生物质多孔炭特征构建及对N2O吸附可行性分析

王佳颖; 刘峥; 张晶; 梁柳玲

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中国环境科学 ›› 2024, Vol. 44 ›› Issue (6) : 3502-3516.

碳排放控制

生物质多孔炭特征构建及对N₂O吸附可行性分析

王佳颖¹, 刘峥¹, 张晶², 梁柳玲³

作者信息 +

Characteristics construction of biomass porous carbon and feasibility analysis of N₂O adsorption

WANG Jia-ying¹, LIU Zheng¹, ZHANG Jin², LIANG Liu-ling³

Author information +

文章历史 +

摘要

针对N₂O的排放现状和原因,在生物炭对农业土壤中N₂O的排放控制的应用研究进行了总结.分析了多孔炭的物理化学性质对N₂O吸附的关键作用,重点论述不同制备条件对生物质多孔炭理化性质的影响.其中含木质素较高的生物质原料在高温热解后更容易形成微孔结构,在不同温度(400℃~ 1000℃)和生物质前驱体的条件下,多孔炭的比表面积和微孔容积最高分别可达2979m²/g和1.130cm³/g.此外,使用活化剂及杂原子掺杂剂的方式可以改变生物质多孔炭的表面极性、酸碱性、亲疏水性等的化学性质,并增加表面官能团种类,从而通过增强化学吸附作用进一步提高生物质多孔炭的吸附容量.最后,根据生物质多孔炭的特点,从吸附容量、可再生性和选择性等三个方面分析了生物质多孔炭吸附富集N₂O的可行性.最后,根据生物质多孔炭的特点,从吸附容量、可再生性和选择性等三个方面分析了生物质多孔炭吸附富集N₂O的可行性,为生物质多孔炭对N₂O气体吸附控制应用提供了科学依据.

Abstract

This article aimed at the current situation and causes of N₂O emission, the research on the application of N₂O emission purification on the biochar from agricultural soil were summarized, and the crucial role of physicochemical properties of biomass porous carbon on N₂O adsorption was further analyzed. Importantly, the effects of different preparation conditions on the physicochemical properties of biomass porous carbon were emphatically discussed. Among them, the microporous structure was easily formed by using biomass raw materials with greater lignin content during the high temperature pyrolysis. Under different temperatures (400℃-1000℃) and biomass precursors, the specific surface area and the micropore volume of porous carbon were maximally achieved to 2979m²/g and 1.130cm³/g, respectively. In addition, the chemical properties of biomass porous carbon, such as surface polarity, acid-base properties, hydrophilicity and hydrophobicity, were modified via the method of activator and heteroatom doping, and then the surface functional groups were also increased, thereby improving the adsorption capacity of biomass porous carbon by the enhancement of chemical adsorption. Furthermore, according to the characteristics of biomass porous carbon, the feasibility of N₂O adsorption and enrichment was further illustrated from three aspects, such as adsorption capacity, renewability and selectivity. It provides a scientific basis for the application of N₂O adsorption by biomass porous carbon.

导出引用

王佳颖, 刘峥, 张晶, 梁柳玲. 生物质多孔炭特征构建及对N₂O吸附可行性分析[J]. 中国环境科学. 2024, 44(6): 3502-3516

WANG Jia-ying, LIU Zheng, ZHANG Jin, LIANG Liu-ling. Characteristics construction of biomass porous carbon and feasibility analysis of N₂O adsorption[J]. China Environmental Science. 2024, 44(6): 3502-3516

中图分类号： X703

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