山谷型填埋场溢流式PRB净化地下水氨氮研究

赵莉, 詹良通, 游雨晴, 潘倩, 陈成

中国环境科学 ›› 2025, Vol. 45 ›› Issue (11) : 6230-6240.

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中国环境科学 ›› 2025, Vol. 45 ›› Issue (11) : 6230-6240.
环境生态

山谷型填埋场溢流式PRB净化地下水氨氮研究

  • 赵莉1,2, 詹良通2, 游雨晴3, 潘倩1, 陈成4
作者信息 +

Investigation on groundwater NH4+-N purification by passive overflow-PRB at valley-type landfill sites

  • ZHAO Li1,2, ZHAN Liang-tong2, YOU Yu-qing3, PAN Qian1, CHEN Cheng4
Author information +
文章历史 +

摘要

山谷型生活垃圾填埋场通常具有水力梯度大、地下水流速高和污染迁移快等特点,传统结构的可渗透反应墙(PRB)难以高效捕获地下水污染羽.针对山谷型填埋场地下水污染迁移特征,提出了溢流式PRB新型结构.溢流式PRB由低渗透性阻隔墙和高渗透性PRB组成,PRB位于阻隔墙中间区段的上部.阻隔墙可汇聚上游地下水并雍高水位,迫使污染地下水通过PRB区段进行净化.溢流式PRB适于修建在山谷的下游出流口处,可防止污染羽进一步向场区外运移,并解决所需PRB建造深度过大的问题.为验证溢流式PRB的有效性,以广东省和浙江省两处山谷型填埋场下游地下水氨氮为净化对象,采用NaCl改性沸石作为PRB填料,应用MODFLOW和MT3DMS模型预测布设溢流式PRB后的集流和净化效果.模拟结果显示:在山谷型填埋场下游布设溢流式PRB可有效阻滞污染羽进一步向下游迁移,5年内两处溢流式沸石PRB下游氨氮浓度低于20.0mg/L或1.5mg/L.

Abstract

Valley-type municipal solid waste (MSW) landfill sites were characterized by a large hydraulic gradient, high groundwater flow velocity and rapid contamination migration. It was challenging for traditional permeable reactive barriers (PRBs) to efficiently capture contamination plumes under these conditions. According to the contamination migration characteristics of valley-type landfill sites, a novel passive overflow-PRB was proposed in this paper. The passive overflow-PRB was composed of a low-permeability cutoff wall and a high-permeability PRB, with the PRB situated in the upper-middle section of the cutoff wall. Upstream groundwater would be captured by the cutoff wall, then the groundwater level would be elevated and the contaminated groundwater would be forced through the PRB for remediation. This design was suitable for installation at the downstream outflow of a valley, effectively preventing further migration of the contamination plume off-site, and solving the problem of excessive construction depth required for the PRB. To validate the effectiveness of the passive overflow-PRB, the groundwater ammonium nitrogen (NH4+-N) from two valley-type landfill sites in Guangdong Province and Zhejiang Province was taken as the remediation target. NaCl-modified zeolite was applied as the reactive material of the PRB, and MODFLOW and MT3DMS models were employed to simulate the collection and remediation effects after construction of passive overflow-PRB. The simulation results indicated that the passive overflow-zeolite PRB could effectively prevent the further migration of NH4+-N contamination plume to the downstream, maintaining concentrations below 20.0mg/L or 1.5mg/L for 5years.

关键词

生活垃圾填埋场 / 山谷型 / 污染地下水 / 可渗透反应墙 / 氨氮 / 溢流

Key words

municipal solid waste landfill / valley-type / contaminated groundwater / permeable reactive barrier / ammonium nitrogen / overflow

引用本文

导出引用
赵莉, 詹良通, 游雨晴, 潘倩, 陈成. 山谷型填埋场溢流式PRB净化地下水氨氮研究[J]. 中国环境科学. 2025, 45(11): 6230-6240
ZHAO Li, ZHAN Liang-tong, YOU Yu-qing, PAN Qian, CHEN Cheng. Investigation on groundwater NH4+-N purification by passive overflow-PRB at valley-type landfill sites[J]. China Environmental Science. 2025, 45(11): 6230-6240
中图分类号: X523   

参考文献

[1] 周 睿,吴 玲,簿 丝,等.深圳简易垃圾填埋场水土环境污染指标识别 [J]. 中国环境科学, 2022,42(3):1287-1294. Zhou R, Wu L, Bu S, et al. Pollutant identification of water and soil of uncontrolled landfills in Shenzhen [J]. China Environmental Science, 2022,42(3):1287-1294.
[2] 刘一民,汪 洋,王 济,等.山谷型填埋场地下水污染特征分析及健康风险评价 [J]. 环境化学, 2022,41(8):2540-2550. Liu Y M, Wang Y, Wang J, et al. Pollution characteristics and health risk assessment of groundwater in a valley type landfill [J]. Huanjing Huaxue-Environmental Chemistry, 2022,41(8):2540-2550.
[3] Xiang S, He X, Yang Q, et al. Migration and natural attenuation of leachate pollutants in bedrock fissure aquifer at a valley landfill site [J]. Environmental Pollution, 2024,362:124963.
[4] Zhan L T, Wu L B, Han H, et al. Hydrogeological classification of municipal solid waste landfill sites in China and correlation with groundwater contaminant migration [J]. Hydrogeology Journal, 2023, 31(3):771-787.
[5] Hudak P F. Evaluation of non-pumped wells with slurry cutoff walls for containing and removing contaminated groundwater [J]. Environmental Earth Sciences, 2016,75(1):67.
[6] USEPA (United States Environmental Protection Agency). A citizen’s guide to pump and treat [R]. 2012:United States.
[7] Kontos Y N. A simulation-optimization model for optimal aquifer remediation, using genetic algorithms and MODFLOW [J]. Hydrology, 2024,11(5):60.
[8] 潘 倩.土—膨润土竖向隔离墙力学行为及其对防污性能影响 [D]. 杭州:浙江大学, 2016. Pan Q. Mechanical behavior of soil-bentonite cutoff walls and its impact on contaminant control [D]. Hangzhou: Zhejiang University, 2016.
[9] 杨孔立.建筑渣土-膨润土回填料防渗性能的试验研究 [D]. 杭州:浙江大学, 2019. Yang K L. Experimental study on water permeability of waste soil-bentonite backfill [D]. Hangzhou: Zhejiang University, 2019.
[10] USEPA (United States Environmental Protection Agency). Permeable reactive barrier technologies of contaminant remediation: EPA/600/R- 98/125 [R]. 1998: United States.
[11] 陈仲如,张澄博,李洪艺,等.可渗透反应墙的结构与设计研究 [J]. 安全与环境学报, 2012,12(4):56-61. Chen Z R, Zhang C B, Li H Y, et al. On the structure and design of permeable reactive barrier [J]. Journal of Safety and Environment, 2012,12(4):56-61.
[12] ITRC (Interstate Technology & Regulatory Council). Permeable reactive barrier: Technology update. PRB-5 [R]. Washington, D.C.: Interstate Technology & Regulatory Council, PRB: Technology Update Team, 2011.
[13] Obiri-Nyarko F, Grajales-Mesa S J, Malina G. An overview of permeable reactive barriers for in situ sustainable groundwater remediation [J]. Chemosphere, 2014,111:243-259.
[14] Zhan L T, Zhao L, Wu L B, et al. A passive sink-zeolite permeable reactive barrier to control NH4+-N pollution plume within groundwater: Conceptual design and numerical modeling [J]. Chemosphere, 2023,334:138965.
[15] Guan Q H, Li F L, Chen X Q, et al. Assessment of the use of a zero-valent iron permeable reactive barrier for nitrate removal from groundwater in the alluvial plain of the Dagu River, China [J]. Environmental Earth Sciences, 2019,78(7):244.
[16] Bortone I, Chianese S, Erto A, et al. An optimized configuration of adsorptive wells for the remediation of an aquifer contaminated by multiple aromatic hydrocarbon pollutants [J]. Science of the Total Environment, 2019,696:133731.
[17] Bortone I, Santonastaso G, Erto A, et al. An innovative in-situ DRAINage system for advanced groundwater reactive TREATment (in-DRAIN-TREAT) [J]. Chemosphere, 2021,270:129412.
[18] 罗兴申,郑凯旋,许芳铭,等.数值模拟减压集流式可渗透反应墙技术修复地下水 [J]. 中国环境科学, 2021,41(12):5728-5735. Luo X S, Zheng K X, Xu F M, et al. Numerical simulation for remediation of polluted ground water by a novel convergent flow permeable reactive barrier [J]. China Environmental Science, 2021, 41(12):5728-5735.
[19] Bekele D N, Du J h, de Freitas L G, et al. Actively facilitated permeable reactive barrier for remediation of TCE from a low permeability aquifer: Field application [J]. Journal of Hydrology, 2019,572:592-602.
[20] Wang X Y. Field test investigation of the pile jacking performance for prefabricated square rigid-drainage piles in saturated silt sandy soils [J]. Advances in Civil Engineering, 2019,2019:4587929.
[21] Wu L B, Zhan L T, Lan J W, et al. Leachate migration investigation at an unlined landfill located in granite region using borehole groundwater TDS profiles [J]. Engineering Geology, 2021,292: 106259.
[22] GB/T14848-2017 地下水质量标准 [S]. GB/T14848-2017 Standard for Groundwater Quality [S].
[23] Zhao L, Zhan L T, Zhang H H, et al. Tracking groundwater pollution plumes at landfill sites using borehole hydrochemical and hydrodynamic profile (BHHP) method [J]. Journal of Environmental Management, 2023,345:118860.
[24] 詹良通,赵 莉,游雨晴,等.适用于深层地下水净化的阻隔墙-可渗透反应墙组合结构:中国, CN202310858832.6 [P]. 2023-11-10. Zhan L T, Zhao L, You Y Q, et al. Cutoff wall-permeable reactive barrier combination structure for deep groundwater purification: China, CN202310858832.6 [P]. 2023-11-10.
[25] Harbaugh A W. MODFLOW-2005, The U.S. Geological Survey modular ground-water model—the ground-water flow process [R]. Washington: U.S. Geological Survey, 2005.
[26] Anderson M P, Woessner, W W, Hunt, R J. Applied groundwater modeling: Simulation of flow and advective transport. [M]. 2nd ed. Amsterdam: Academic Press, 2015:71-77.
[27] Zheng C M, Wang P P. MT3DMS: A modular three-dimensional multispecies transport model for simulation of advection, dispersion, and chemical reactions of contaminants in groundwater systems [M]. Vicksburg:U.S. Army Engineer Research and Development Center, 1999.
[28] Pollock D W. Extending the MODPATH algorithm to rectangular unstructured grids [J]. Groundwater, 2016,54(1):121-125.
[29] Gelhar L W, Welty C, Rehfeldt K R. A critical-review of data on field-scale dispersion in aquifers [J]. Water Resources Research, 1992,28(7):1955-1974.
[30] 龚 锐,叶长文,程 蓉,等.改性土-膨润土阻隔墙阻控离子型稀土矿氨氮污染 [J]. 环境工程学报, 2020,14(5):1394-1403. Gong R, Ye C W, Chen R, et al. Resistance and control of ammonia nitrogen pollution of ionic rare earth ores with modified soil-bentonite barrier [J]. Chinese Journal of Environmental Engineering, 2020,14(5): 1394-1403.
[31] Dong Y, Yuan H, Zhang R, Zhu N. Removal of ammonia nitrogen from wastewater: a review [J]. Transactions of the Asabe, 2019,62(6): 1767-1778.
[32] Zhan L T, You Y Q, Zhao L, et al. A study on the competitive adsorption process of NH4+ and Zn2+ on activated carbon and zeolite [J]. International Journal of Environmental Science and Technology, 2023,20(6):6039-6052.
[33] 游雨晴.地下水复合污染物的多层可渗透性反应墙净化方法及应用 [D]. 杭州:浙江大学, 2023. You Y Q. Study and application of multi-layered permeable reactive barrier in remediating groundwater contaminated by landfills [D]. Hangzhou: Zhejiang University, 2023.
[34] Park E, Zhan H B. One-dimensional solute transport in a permeable reactive barrier-aquifer system [J]. Water Resources Research, 2009, 45:W07502.
[35] Mizan S A, Sonkamble S, Sharadha A, et al. Decision support system for sustainable groundwater management in crystalline hard rocks: Implications for sugarcane agriculture, Southern India [J]. Environmental Monitoring and Assessment, 2022, 194(12):918.
[36] Yihdego Y, Drury L. Mine water supply assessment and evaluation of the system response to the designed demand in a desert region, central Saudi Arabia [J]. Environmental Monitoring and Assessment, 2016, 188(11):619.

基金

四川省区域创新合作项目(2024YFHZ0172);浙江省自然科学基金资助项目(LHY22E080002);国家自然科学基金资助项目(42307210);浙江省自然科学基金资助项目(LQ24E080016)

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