The chemical component characteristics of vehicle tire wear particles
WU Lin1, ZHANG Xin-feng2, MEN Zheng-yu1, ZHANG Jing3, CHANG Jun-yu1, ZHANG bao-xi1, MAO Hong-jun1
1. College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China;
2. China Automotive Technologyand Research Center Co., Ltd., Dongli District, Tianjin 300300, China;
3. Tian-bin Rui-cheng Environmental Technology and Engineering Co., Ltd., Tianjin 300190, China
To obtainthe physical and chemical characteristics of particulate matter emitted from the tire wears of on-road vehicles, 17 kinds of selected tire tread were worn away by use of the tire profile simulation abrasion instrument. Tire wear particle samples were obtained, and 18 kinds of elements and 20 kinds of polycyclic aromatic hydrocarbons (PAHs) were extracted and detected. The results showed that the content of elements and PAHs varied significantly with different brand and speed level. The average content of 18 kinds of elements was (99.04±68.43) mg/g, accounting for 9.90% of the samples according to weight percentage, the average content of Si(88.97±67.85) mg/g, Zn(6.77±1.64) mg/g and Na(1.05±0.75) mg/g exceeded 1mg/g, the average content of Cd was (0.43±0.31)μg/g. The total content of 20kinds of PAHs changed from 12.13 to 433.64μg/g, the average content was (94.13±110.18) μg/g. The most abundant component was PY (30.98±31.27) μg/g, followed by CHR, BaP, FA, PHE and BghiP. Among them, AC contributes the lowest share with (0.58±0.2) μg/g on average. In term of the ring number, 4-ring PAHs were the major contents (accounting for 45.03%~67.93%), followed by 3-ring (15.45% on average) and 5-ring (12.62% on average) PAHs. In general, the contents of elements and PAHs in tires of foreign brands were slightly higher than those of domestic brands, while the numbers of PAHs rings were slightly lower than those of domestic brands.
陈多宏,李梅,黄渤,等.区域大气细粒子污染特征及快速来源解析[J]. 中国环境科学, 2016,36(3):651-659. Chen D H, Li M, Huang B, et al. The pollution characteristics and source apportionment of regional atmospheric fine particles[J]. China Environmental Science, 2016,36(3):651-659.
[2]
Zhao P S, Dong F, He D, et al. Characteristics of concentrations and chemical compositions for PM2.5 in the region of Beijing, Tianjin, and Hebei, China[J]. Atmospheric Chemistry and Physics, 2013,13:4631-4644.
[3]
Chem Risk, Inc, DIK Inc. State of knowledge report for tire materials and tire wear particles[EB/OL]. http://www.wbcsd.org/Pages/Adm/Download.aspx?ID=67&ObjectTpeId=7.2008,07.
[4]
Anna W, Goran D.环境中轮胎磨耗颗粒的产生及影响[J]. 轮胎工业, 2014,34(9):528-538. Anna W, Goran D. Occurrence and effects of tire wear particles in the environment[J]. Tire Industry, 2014,34(9):528-538.
[5]
Adachi K, Tainosho Y. Characterization of heavy metal particles embedded in tire dust[J]. Environment International, 2004,30:1009-1017.
[6]
Harrison R M, Jones A M, Gietl J, et al. Estimation of the contributions of brake dust, tire wear, and resuspension to non-exhaust traffic particles derived from atmospheric measurements[J]. Environmental Science & Technology, 2012,46:6523-6529.
[7]
Panko J M, Chu J, Kreider M L, et al. Measurement of airborne concentrations of tire and road wear particles in urban and rural areas of France, Japan, and the United States[J]. Atmospheric Environment, 2013,72:192-199.
[8]
Lee S, Kwak J, Kim H, et al. Properties of roadway particles form interaction between the tire and road pavement[J]. International Journal of Automotive Technology, 2013,14:163-173.
[9]
Ozaki H, Watanabe I, Kuno K. Investigation of the heavy metal sources in relation to automobiles[J]. Water Air Soil Pollution, 2004, 157:209-223.
[10]
Sadiktsis I, Bergvall C, Johansson C, et al. Automobile tires-a potential source of highly carcinogenic dibenzopyrenes to the environment[J]. Environmental Science & Technology, 2012,46:3326-3334.
[11]
Hewitt C N, Rashed M B. An integrated budget for selected pollutants for a major rural highway[J]. Science of the Total Environment, 1990, 93(93):375-384.
[12]
Hildemann L M, Markowski G R, Cass G R. Chemical composition of emissions from urban sources of fine organic aerosol[J]. Environmental Science & Technology, 1991,25(4):744-759.
[13]
Brewer P. Vehicles as a source of heavy metal contamination in the environment[D] Berkshire:University of Reading, 1997.
[14]
Oostergo H. Emission of metals and PACs by traffic[R]. Ministry of VROM, 1997.
[15]
Legret M, Pagotto C. Evaluation of pollutant loadings in the runoff waters from a major rural highway[J]. Science of the Total Environment, 1999,235(1-3):143-150.
[16]
Limited K M, Kennedy P, Gadd J, et al. Preliminary examination of trace elements in tires, brake pads and road bitumen in New Zealand[EB/OL]. Revised October 2003. http://transport.govt.nz/assets/Import/Documents/stormwater-inorganic3.pdf.
[17]
Adachi K, Tainosho Y. Characterization of heavy metal particles embedded in tire dust[J]. Environment International, 2004,30(8):1009-1017.
[18]
Councell T B, Duckenfield K U, Landa E R, et al. Tire-wear particles as a source of zinc to the environment[J]. Environmental Science & Technology, 2004,38(15):4206-4214.
[19]
Kreider M L, Panko J M, McAtee B L, et al. Physical and chemical characterization of tire-related particles:Comparison of particles generated using different methodologies[J]. Science of the Total Environment, 2010,408(3):652-659.
[20]
Smolders E, Degryse F. Fate and effect of zinc from tire debris in soil[J]. Environmental Science & Technology, 2002,36(17):3706-3710.
[21]
Ahagon A, Kida M, Kaidou H. Aging of tire parts during service. I. Types of aging in heavy-duty tires[J]. Rubber Chemistry and Technology, 1990,63(5):683-697.
[22]
Fauser P. Particulate air pollution with emphasis on traffic generated aerosols[R]. Ed. Riso national laboratory, 1999.
[23]
Rogge W F, Hildemann L M, Mazurek M A, et al. Sources of fine organic aerosol. 3. Road dust, tire debris, and organometallic brake lining dust:roads as sources and sinks[J]. Environ. sci.technol, 1993, 27(9):1892-1904.
[24]
Demarini D M, Lemieux P M, Ryan J V, et al. Mutagenicity and chemical analysis of emissions from the open burning of scrap rubber tires[J]. Environmental Science & Technology, 1994,28(1):136-141.
[25]
Reddy C M, Quinn J G. Environmental chemistry of benzothiazoles derived from rubber[J]. Environmental Science & Technology, 1997,31(10):2847-2853.
[26]
Boonyatumanond R, Murakami M,Wattayakorn G, et al. Sources of polycyclic aromatic hydrocarbons (PAHs) in street dust in a tropical Asian mega-city, Bangkok, Thailand[J]. Science of the Total Environment, 2007,384(1):420-432.
[27]
Aatmeeyata, Sharma M. Polycyclic aromatic hydrocarbons, elemental and organic carbon emissions from tire-wear[J]. Science of the Total Environment, 2010,408(20):4563-4568.
[28]
Aatmeeyata, Sharma M. Contribution of traffic-generated nonexhaust PAHs, elemental carbon, and organic carbon emission to air and urban runoff pollution[J]. Journal of Environmental Engineering, 2010, 136(12):1447-1450.
[29]
董彩玉,苍飞飞. GC/MS内标法测定全钢载重子午线轮胎中的多环芳烃含量[J]. 轮胎工业, 2013,33(2):119-123. Dong C Y, Cang F F. Determination of PAHs in Truck and Bus Radial Tire by GC/MS and Internal Standard Method[J]. Tire Industry, 2013,33(2):119-123.