Characteristics analysis of dissolved organic matter in the acid mine drainage
ZHANG Si-yu1,3, YUE Zheng-bo1,3, SHE Zhi-xiang1,3, PAN Xin1,3, SHAO Rui1,3, SHI Quan2, HE Chen2, LI Yun-yun2, WANG Jin1,3
1. School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, China; 2. The Heavy Oil Key Laboratory, China University of Petroleum, Beijing 102200, China; 3. Laboratory of Nanominerals and Pollution Control of Anhui Higher Education Institutes, Hefei 230009, China
Abstract：Surface water samples with different offshore distances from AMD in Anhui province were collected, and the sources and component characteristics of DOM in water samples were studied with Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) and Excitation-Emission Matrix spectroscopy (EEMs). The EEMs results showed that the fluorescence peak intensity of autochthonous tryptophan in the DOM sample correlated positively with the distance. The EEMs characteristic indexes values of FI, HIX and BIX indicated that DOM was mainly from internal sources. FT-ICR MS analysis results further indicated endogenous components (lipids, aliphatic/proteins, carbohydrates) in the DOM sample near the shoreside had a relatively low proportion of 66% at the molecular level. The main components were composed of CHO, CHON and CHOS containing substances. The high fraction of CHOS compounds was mainly related to the high sulfate concentration in AMD.
张思宇, 岳正波, 佘智祥, 潘鑫, 邵锐, 史权, 何晨, 李运运, 王进. 某酸性矿山排水中溶解性有机物的特征分析[J]. 中国环境科学, 2020, 40(8): 3401-3407.
ZHANG Si-yu, YUE Zheng-bo, SHE Zhi-xiang, PAN Xin, SHAO Rui, SHI Quan, HE Chen, LI Yun-yun, WANG Jin. Characteristics analysis of dissolved organic matter in the acid mine drainage. CHINA ENVIRONMENTAL SCIENCECE, 2020, 40(8): 3401-3407.
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