Abstract：Alkali lignin was used as raw material to prepare alkali lignin-based activated carbon (LAC). And then, lignin-based activated carbon-supported with nickel-zinc oxides (NiZn-DO/LAC) was fabricated by hydrothermal synthesis after adding nickel nitrate and zinc nitrate onto LAC. The structure of NiZn-DO/LAC was characterized by BET, SEM and XRD, and the adsorption behavior of sulfathiazole (ST) in aqueous solution was also studied. The results showed that the NiZn-DO/LAC had evident obvious three-dimensional porous structure and stable crystal structure with a large specific surface area of 759.1m2/g. In the process of ST adsorption, the NiZn-Do/Lac showed excellent adsorption performance, with the maximum adsorption capacity up to 328.2mg/g, which was better than other reported adsorbents. Additionally, the ST was easily desorbed from NiZn-DO/LAC with NaOH solution and the analytical rate of NiZn-DO/LAC was still reach up to 79.43% after 4times of recycles. Furthermore, it showed that the adsorption behavior of ST over NiZn-DO/LAC was mainly through the synergistic effect of electrostatic interaction, π-π interaction, complexation, hydrophobic effects and hydrophobicity, resulting in a great improvement of adsorption performance.
Baran W, Adamek E, Ziemianska J, et al. Effects of the presence of sulfonamides in the environment and their influence on human health[J]. Journal of Hazardous Materials, 2011,196:1-15.DOI:10.1016/j.jhazmat.2011.08.082.
[2]
陈哲,吴立明,苏怡.生活饮用水中磺胺类抗生素污染现状及其控制的研究进展[J]. 上海预防医学, 2018,30(5):412-415. Chen Z, Wu L M, Su Y, et al. Research progress on pollution status and control of sulfonamides in drinking water[J]. Shanghai Preventive Medicine, 2018,30(5):412-415.
[3]
王佳豪,许锴,刘康乐,等.水中磺胺类抗生素去除技术的研究进展[J]. 应用化工, 2020,49(7):1813-1818. Wang J H, Xu K, Liu K L, et al. Research progress of removal technology of sulfonamides antibiotics in water[J]. Application of Chemical, 2020,49(7):1813-1818.
[4]
Peiris C, Gunatilake S R, Mlsna T E, et al. Biochar based removal of antibiotic sulfonamides and tetracyclines in aquatic environments:A critical review[J]. Bioresource Technology, 2017.DOI:10.1016/j.biortech.2017.07.150.
[5]
Yu J, Xiang, Zhang Y, et al. Carbon-based materials as adsorbent for antibiotics removal:Mechanisms and influencing factors[J]. Journal of Environmental Management, 2019.DOI:10.1016/j.jenvman.2019. 02.068.
[6]
Meng Q, Zhang Y, D Meng, et al. Removal of sulfadiazine from aqueous solution by in-situ activated biochar derived from cotton shell[J]. Environmental Research, 2020,191(5):110104.
[7]
Wan J, Ding J, Tan W, et al. Magnetic-activated carbon composites derived from iron sludge and biological sludge for sulfonamide antibiotic removal[J]. Environmental Science and Pollution Research, 2020,27(12).DOI:10.1007/s11356-020-07940-z.
[8]
Su X, Yang S, Song Y, et al. Adsorption of sulfathiazole drug on the platinum-decorated zinc oxide nanotubes[J]. Journal of Sulfur Chemistry, 2020,(11):1-12.DOI:10.1080/17415993.2020.1797032.
[9]
Liu S, Wei W, Wu S, et al. Preparation of hierarchical porous activated carbons from different industrial lignin for highly efficient adsorption performance[J]. Journal of Porous Materials, 2020,27(5):1523-1533.
[10]
Raymundo-Pi Ero E, Aza S P, Cacciaguerra T, et al. KOH and NaOH activation mechanisms of multiwalled carbon nanotubes with different structural organization[J]. Carbon, 2005,43(4):786-795.
[11]
Otowa T, Tanibata R, Itoh M, et al. Production and adsorption characteristics of MAXSORB:High-surface-area active carbon[J]. Gas Separation & Purification, 1993,7(4):241-245.
[12]
Li R, Wang J J, Gaston L A, et al. An overview of carbothermal synthesis of metal-biochar composites for the removal of oxyanion contaminants from aqueous solution[J]. Carbon, 2018,129:674-687.
[13]
Yaseen M, Ullah S, Ahmad W, et al. Fabrication of Zn and Mn loaded activated carbon derived from corn cobs for the adsorptive desulfurization of model and real fuel oils[J]. Fuel, 2021,284:119102.
[14]
Rahman, Muttakin, Pal, et al. A statistical approach to determine optimal models for IUPAC-classified adsorption isotherms[J]. Energies (Basel), 2019,12(23):4565.
[15]
Zebastian B M, Petter L K. Preparation of chabazite with mesopores templated from a cationic polymer[J]. Microporous and Mesoporous Materials, 2018,271:S1170975593.
[16]
Wu Z, Xue Y, Gao Z, et al. Synthesis of Ni-doped anatase TiO2 single crystals loaded on wood-based activated carbon for enhanced photodegradation of triphenylmethane dyes[J]. Environmental Science and Pollution Research, 2021,28(6):6491-6503.
[17]
Aswini, Panneerselvam, Vijayalakshmi, et al. Removal of nickel from aqueous solution using synthesized IL/ZnO NPs.[J]. Environmental science and pollution research international, 2020,27(7).DOI:10.1007/s11356-019-07425-8.
[18]
Kim J D, Choi H C. Carbon nanotube-supported Pd/Ni(OH)2 nanoparticles:Magnetically recoverable and reusable catalyst for the reduction of nitroarenes[J]. Bulletin of the Korean Chemical Society, 2017,38(11).DOI:10.1002/bkcs.11291.
[19]
Skala L. Electron transfer in chemisorption[J]. Physica Status Solidi, 2010,130(2):K157-K162.
[20]
Mohammadi R, Azadmehr A, Maghsoudi A, et al. Fabrication of the alginate-combusted coal gangue composite for simultaneous and effective adsorption of Zn(II) and Mn(II)[J]. Journal of Environmental Chemical Engineering, 2019,7(6):103494.
[21]
张书源.颗粒活性炭和改性凹凸棒土对水中磺胺类抗生素的吸附去除研究[D]. 兰州:兰州交通大学, 2019. Zhang S Y. Study on adsorption removal of sulfonamides antibiotics in water by granular activated carbon and modified attapulgite[D]. Lanzhou:Lanzhou Jiaotong University, 2019.
[22]
李蕊宁.改性马铃薯秸秆生物炭对水体中典型抗生素的吸附性能研究[D]. 兰州:兰州大学, 2018. Li R N. Study on the adsorption capacity of modified potato straw biochar for typical antibiotics in water[D]. Lanzhou:Lanzhou University, 2018.
[23]
Ahmed M B, Zhou J L, Ngo H H, et al. Single and competitive sorption properties and mechanism of functionalized biochar for removing sulfonamide antibiotics from water[J]. Chemical Engineering Journal, 2017,311.DOI:10.1016/j.cej.2016.11.106.
[24]
B Y F A, B L H, A L W, et al. Adsorption of sulfonamides on biochars derived from waste residues and its mechanism[J]. Journal of Hazardous Materials, DOI:2020.10.1016/j.jhazmat.2020.124291.
[25]
Almajed A, Ahmad M, Usman A, et al. Fabrication of sand-based novel adsorbents embedded with biochar or binding agents via calcite precipitation for sulfathiazole scavenging-ScienceDirect[J]. Journal of Hazardous Materials, 2020,405(10):124249.
[26]
沈秀娥.多壁碳纳米管对硝基化合物和抗生素的吸附特性研究[D]. 长春:吉林大学, 2009. Shen X E. Adsorption characteristics of multi-walled carbon nanotubes for nitro compounds and antibiotics[D]. Changchun:Jilin University, 2009.
[27]
Cecen F. Activated Carbon for Water and Wastewater Treatment:Integration of Adsorption and Biological Treatment[M]. Wiley-VCH, 2011.
[28]
Iriel A, Bruneel S P, Schenone N, et al. The removal of fluoride from aqueous solution by a lateritic soil adsorption:Kinetic and equilibrium studies[J]. Ecotoxicology & Environmental Safety, 2018,149(mar.):166-172.
[29]
薛向东,杨宸豪,于荐麟,等.圩区河道底泥腐殖酸对重金属和抗生素的共吸附[J]. 环境科学, 2020:1-15. Xue X D, Yang C H, Yu J L, et al. Co-adsorption of heavy metals and antibiotics by humic acid from river sediment in polder area[J]. Environmental Sciences, 2020:1-15.
[30]
Gogolishvili O S, Reshetova E N. Chromatographic enantioseparation and adsorption thermodynamics of hydroxy acids and their derivatives on antibiotic-based chiral stationary phases as affected by eluent pH[J]. Chromatographia, 2021,84(1):1-21.
[31]
Larasati A, Fowler G D, Graham N J D. Chemical regeneration of granular activated carbon:preliminary evaluation of alternative regenerant solutions[J]. Environmental Science:Water Research & Technology, 2020,6.DOI:10.1039/D0EW00328J.
[32]
Li B, Zhu X, Hu K, et al. Defect creation in metal-organic frameworks for rapid and controllable decontamination of roxarsone from aqueous solution[J]. Journal of Hazardous Materials, 2016,302:57-64.
[33]
Ruining L I, Zhaowei W, Jialei G, et al. Adsorption characteristics of sulfathiazole in aqueous solution by acid/alkali modified biochars[J]. Acta Scientiae Circumstantiae, 2017.DOI:10.13671/j.hjkxxb.2017. 0155.
[34]
Chen K L, Liu L C, Chen W R, et al. Adsorption of sulfamethoxazole and sulfapyridine antibiotics in high organic content soils[J]. Environmental Pollution, 2017,231(1):1163-1171.
[35]
Liu F F, Zhao J, Wang S, et al. Adsorption of sulfonamides on reduced graphene oxides as affected by pH and dissolved organic matter[J]. Environmental Pollution, 2016,210:85-93.
[36]
Sun, Zhonghai, Zhansheng, et al. Microwave-assisted modification of activated carbon with cationic surfactants for enhancement of naphthalene adsorption[J]. The Korean Journal of Chemical Engineering, 2018.
[37]
Zhang D, Pan B, Wu M, et al. Cosorption of organic chemicals with different properties:Their shared and different sorption sites[J]. Environmental Pollution (Barking, Essex:1987), 2012,160(1):178-184.
[38]
Tong, Yue, Wei, et al. Mechanism of goethite precipitation on magnetite and maghemite nanoparticles studied by surface complexation/precipitation modeling[J]. Langmuir, 2018,34.
[39]
童非,顾雪元.重金属离子与典型离子型有机污染物的络合效应研究[J]. 中国环境科学, 2014,34(7):1776-1784. Tong F, Gu X Y. Study on complexation effect of heavy metal ions with typical ionic organic pollutants[J]. China Environmental Science, 2014,34(7):1776-1784.
[40]
Sekimoto T, Nishihama S, Yoshizuka K, et al. Adsorptive removal of sulfamethoxazole with shell-core chitosan immobilized metal ion[J]. Separation Science & Technology, 2017:1492017-1496395.
[41]
刘鹏磊.磁性生物质活性炭的制备及其对水体中抗生素的吸附研究[D]. 郑州:郑州大学, 2019. Liu P L. Preparation of magnetic biomass activated carbon and its adsorption for antibiotics in water[D]. Zhengzhou:Zhengzhou University, 2019.
