Advances in the removal processes of HONO in the atmosphere
WANG Xue-yao1,2,3, HE Xiang1,2,3, LIN Deng1,2,3
1. College of Ecology and Environment, Xinjiang University, Urumqi 830017, China; 2. Key Laboratory of Oasis Ecology, Ministry of Education, Xinjiang University, Urumqi 830017, China; 3. Xinjiang Jinghe Observation and Research Station of Temperate Desert Ecosystem, Ministry of Education, Urumqi 830017, China
Abstract：Nitric acid (HONO) is the key precursor of photochemical oxidant OH in the atmosphere, which has an important influence on the migration, transformation and removal of air pollutants. The removal processes of HONO in the atmosphere are closely related to its fate whose understanding, however, needs to be improved. It can be concluded from field observation, laboratory simulation and theoretical calculation that HONO can react with various pollutants in homogeneous and heterogeneous ways, which can be divided into four ways to remove HONO in the atmosphere:(1) the photolysis; (2) the reaction with inorganic substances, such as ·OH, HO2·, H·, nitrogen-containing substances, halogen-containing substances, sulfur-containing substances, etc., which include both direct reactions with free radicals and reactions with inorganic compounds; (3) the reaction with organic matter, which can directly or indirectly produce nitro derivatives; and (4) the settlement removal (wet settlement, dry settlement). At present, the studies on HONO removal mainly focused on mechanism; especially for heterogeneous removal of HONO, more efforts were put on the self-reaction of HONO with the participation of common catalytic particles. In the future, more experiments or model simulations are needed to deeply explore various factors affecting HONO removal and simulate the removal process of HONO under real atmospheric conditions.
王雪瑶, 何翔, 林登. 大气中HONO去除途径的研究进展[J]. 中国环境科学, 2023, 43(5): 2152-2160.
WANG Xue-yao, HE Xiang, LIN Deng. Advances in the removal processes of HONO in the atmosphere. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(5): 2152-2160.
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