Pollution characteristics and ozone formation potential of VOCs in the plastic foam shoe manufacturing centre

LI Ting-ting; LIANG Xiao-ming; LU Qing; LIU Ming; CHEN Zhi-hang; WANG Shuo; LU Hai-tao; MU Gui-zhen; GUO Song-jun; HE Qiu-sheng; CHEN Lai-guo

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China Environmental Science ›› 2020, Vol. 40 ›› Issue (8) : 3260-3267.

Air Pollution Control

Pollution characteristics and ozone formation potential of VOCs in the plastic foam shoe manufacturing centre

LI Ting-ting^1,2, LIANG Xiao-ming², LU Qing², LIU Ming², CHEN Zhi-hang², WANG Shuo², LU Hai-tao², MU Gui-zhen^2,3, GUO Song-jun¹, HE Qiu-sheng⁴, CHEN Lai-guo²

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Abstract

Five monitoring sites were set up in and around the plastic foam shoe manufacturing center in Wuchuan, Guangdong to study the pollution characteristics and ozone formation potentials of atmospheric VOCs. The results showed that the composition of atmospheric VOCs was predominantly alkanes (38.4%), oxygen-containing VOCs (33.5%), and aromatic hydrocarbons (19.5%). The total concentration of 80 kinds of VOCs ranged from 137.1μg/m³ to 169.0μg/m³ with an average of 149.1μg/m³. N-pentane, isopentane, n-butane, isobutane, formaldehyde, toluene, m/o-xylene, acetone, methyl ethyl ketone, cyclohexanone, methyl methacrylate, and ethyl acetate were characteristic VOCs of this shoe manufacture industry. The spatial trends of the total VOC concentrations, characteristic VOC types (oxygen-containing volatile organic compounds, aromatic hydrocarbons) and characteristic VOC components (toluene, o-xylene, m-xylene, methyl ethyl ketone, and ethyl acetate) all showed a spatial pattern that the concentration was largest at contaminated area, followed by affected area (downwind) and control area (upwind). Additionally, the ozone formation potential (OFP) of VOCs was estimated with the maximum incremental reactivity (MIR) method. The mean value of OFP was 544.6μg/m³, indicating that the manufacture of plastic foam shoes tended to cause the pollution of ambient VOCs and have a significant impact on ozone formation.

Key words

ozone formation potential / plastic foam shoes / pollution characteristics / VOCs

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LI Ting-ting, LIANG Xiao-ming, LU Qing, LIU Ming, CHEN Zhi-hang, WANG Shuo, LU Hai-tao, MU Gui-zhen, GUO Song-jun, HE Qiu-sheng, CHEN Lai-guo. Pollution characteristics and ozone formation potential of VOCs in the plastic foam shoe manufacturing centre[J]. China Environmental Science. 2020, 40(8): 3260-3267

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