[1] Zhang S, Li M, Li J, et al. High-ammonia selective metal-organic framework-derived Co-doped Fe/Fe₂O₃catalysts for electrochemical nitrate reduction[J]. Proceedings of the National Academy of Sciences, 2022,119(6):e2115504119.
[2] Chen F Y, Elgazzar A, Pecaut S, et al. Electrochemical nitrate reduction to ammonia with cation shuttling in a solid electrolyte reactor[J]. Nature Catalysis, 2024,7(9):1032-1043.
[3] Fan K, Xie W, Li J, et al. Active hydrogen boosts electrochemical nitrate reduction to ammonia[J]. Nature Communications, 2022,13(1):7958.
[4] Yao Y, Zhu S, Wang H, et al. A spectroscopic study of electrochemical nitrogen and nitrate reduction on rhodium surfaces[J]. Angewandte Chemie, 2020,59(26):10479-10483.
[5] Yao F, Yang Q, Zhong Y, et al. Indirect electrochemical reduction of nitrate in water using zero-valent titanium anode: Factors, kinetics, and mechanism[J]. Water Research, 2019,157:191-200.
[6] Zeng Y, Priest C, Wang G, et al. Restoring the nitrogen cycle by electrochemical reduction of nitrate: progress and prospects[J]. Small Methods, 2020,4(12):2000672.
[7] Zhang J, Huang L, Tjiu W W, et al. Evidence for distinct active sites on oxide-derived cu for electrochemical nitrate reduction[J]. Journal of the American Chemical Society, 2024,146(44):30708-30714.
[8] Du H, Guo H, Wang K, et al. Durable electrocatalytic reduction of nitrate to ammonia over defective pseudobrookite Fe₂TiO₅nanofibers with abundant oxygen vacancies[J]. Angewandte Chemie, 2023, 135(5):202215782.
[9] Fang Z, Jin Z, Tang S, et al. Porous two-dimensional iron-cyano nanosheets for high-rate electrochemical nitrate reduction[J]. ACS Nano, 2021,16(1):1072-1081.
[10] Fu Y, Wang S, Wang Y, et al. Enhancing electrochemical nitrate reduction to ammonia over cu nanosheets via facet tandem catalysis[J]. Angewandte Chemie, 2023,62(26):202303327.
[11] Hua Y, Song N, Wu Z, et al. Cu–Fe synergistic active sites boost kinetics of electrochemical nitrate reduction[J]. Advanced Functional Materials, 2024,34(21):2314461.
[12] Huang H, Peramaiah, Huang K W. Rethinking nitrate reduction: redirecting electrochemical efforts from ammonia to nitrogen for realistic environmental impacts[J]. Energy & Environmental Science, 2024,17(8):2682-2685.
[13] Jiang Y, Kong D, Huang L, et al. Refining the active phases of silver/nickle-based catalysts achieves a highly-selective reduction of nitrate to ammonium at low overpotential[J]. Applied Catalysis B: Environment and Energy, 2024,356:124224.
[14] Gao W, Yan Z, Tian S, et al. Modulate the strength of *H adsorption by changing the spin state over Cu/Co dual-active sites accelerating ammonia electrochemical synthesis kinetics[J]. Applied Catalysis B: Environment and Energy, 2025,377:125495.
[15] Li Y, Lu Z, Zheng L, et al. The synergistic catalysis effect on electrochemical nitrate reduction at the dual-function active sites of the heterostructure[J]. Energy & Environmental Science, 2024,17(13): 4582-4593.
[16] Liu H, Lang X, Zhu C, et al. Efficient electrochemical nitrate reduction to ammonia with copper-supported rhodium cluster and single-atom catalysts[J]. Angewandte Chemie, 2022,61(23):e202202556.
[17] Lu X, Song H, Cai J, et al. Recent development of electrochemical nitrate reduction to ammonia: A mini review[J]. Electrochemistry Communications, 2021,129:107094.
[18] Meng X, Tan X, Ma Y, et al. Recent progress in cobalt-based electrocatalysts for efficient electrochemical nitrate reduction reaction[J]. Advanced Functional Materials, 2025,35(14):2418492.
[19] Xie L, Hao Q, Wu Y, et al. Asymmetric coordination engineering accelerates the electrochemical nitrate reduction kinetics on metal- organic frameworks[J]. Applied Catalysis B: Environment and Energy, 2025,375:125428.
[20] Xu M, Dong S, Guo H, et al. Defective perovskite supported palladium-nickel nanocatalyst for effective electrochemical nitrate reduction[J]. Applied Catalysis B: Environment and Energy, 2025, 375:125433.
[21] Murphy E, Liu Y, Matanovic I, et al. Elucidating electrochemical nitrate and nitrite reduction over atomically-dispersed transition metal sites[J]. Nature Communications, 2023,14(1):4554.
[22] Ni J, Yan J, Li F, et al. Atomic Co-P catalytic pair drives efficient electrochemical nitrate reduction to ammonia[J]. Advanced Energy Materials, 2024,14(28):2400065.
[23] Sarkar S, Adalder A, Paul S, et al. Iron phthalocyanine hollow architecture enabled ammonia production via nitrate reduction to achieve 100% faradaic efficiency[J]. Applied Catalysis B: Environment and Energy, 2024,343: 123580.
[24] Su L, Li K, Zhang H, et al. Electrochemical nitrate reduction by using a novel Co₃O₄/Ti cathode[J]. Water Research, 2017,120:1-11.
[25] Sun L, Liu B. Mesoporous PdN alloy nanocubes for efficient electrochemical nitrate reduction to ammonia[J]. Advanced Materials, 2023,35(1):2207305.
[26] Ullah S, Wang S, Ahmad M S, et al. Investigating the role of oxygen vacancies in metal oxide for enhanced electrochemical reduction of NO₃^- to NH₃: mechanistic insights[J]. Inorganic Chemistry Frontiers, 2023,10(22): 6440-6488.
[27] Ke S W, Lv Y, Gu Y, et al. Dual-enzyme-mimicking sites in covalent organic frameworks enable highly efficient relay electrosynthesis of ammonia[J]. JACS Au, 2025,5(6):2523-2532.
[28] 齐鲁,陈思哲,丁素莹,等.NiFe LDHs的制备及其吸附去除废水中硝酸盐的性能和机理分析[J]. 中国环境科学, 2025,45(11):6068-6078. Qi L, Chen S, Ding S, et al. Preparation of NiFe LDHs and its adsorption performance and mechanism analyses of removing nitrate from wastewater[J]. China Environmental Science, 2025,45(11):6068-6078.
[29] Wang J, Wu D, Li M, et al. Bismuth ferrite as an electrocatalyst for the electrochemical nitrate reduction[J]. Nano Letters, 2022,22(13):5600-5606.
[30] Wu Z Y, Karamad M, Yong X, et al. Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst[J]. Nature Communications, 2021,12(1):2870.
[31] Xiong Y, Wang Y, Tsang C C, et al. Metal doped unconventional phase irni nanobranches: tunable electrochemical nitrate reduction performance and pollutants upcycling[J]. Environmental Science & Technology, 2024,58(24):10863-10873.
[32] Xiong Y, Wang Y; Zhou J, et al. Electrochemical nitrate reduction: ammonia synthesis and the beyond[J]. Advanced Materials, 2024, 36(17):2304021.
[33] Yao F, Jia M, Yang Q, et al. Highly selective electrochemical nitrate reduction using copper phosphide self-supported copper foam electrode: Performance, mechanism, and application[J]. Water Research, 2021,193:116881.
[34] Zhang S, Wu J, Zheng M, et al. Fe/Cu diatomic catalysts for electrochemical nitrate reduction to ammonia[J]. Nature Communications, 2023,14(1):3634.
[35] Zhang W D, Dong H, Zhou L, et al. Fe single-atom catalysts with pre-organized coordination structure for efficient electrochemical nitrate reduction to ammonia[J]. Applied Catalysis B: Environment and Energy, 2022,317:121750.
[36] Huang Y, Liang Y, Jiang H, et al. Enrichment of active hydrogen on nanoporous Ru/Co₂P for enhanced electrocatalytic nitrate to ammonia[J]. Chemical Engineering Journal, 2025,516:164046.
[37] Liu M, Yang F, Zhao H, et al. Enabling kinetics matching in electrocatalytic ammonia synthesis by leveraging spatially-confined Cu/Fe₂O₃ heterointerfaces to maximize *H supply and utilization[J]. Chemical Engineering Journal, 2025,516:164148.
[38] Ma C, Zhang H, Yang Y, et al. Computation-guided design of Ru-based intermetallic catalysts enabling nearly 100% selectivity for electrocatalytic ammonia synthesis at ultra-low potential[J]. Advanced Functional Materials, 2025,35(42):2506817.
[39] Wang Y, Wang C, Li M, et al. Nitrate electroreduction: mechanism insight, in situ characterization, performance evaluation, and challenges[J]. Chemical Society Reviews, 2021,50(12):6720-6733.
[40] Ba J, Dong H, Odziomek M, et al. Red carbon mediated formation of Cu₂O clusters dispersed on the oxocarbon framework by fehling's route and their use for the nitrate electroreduction in acidic conditions[J]. Advanced Materials, 2024,36(25):2400396.
[41] Feng C, Bo K, Wan J, et al. Triple synergy engineering via metal-free dual-atom incorporation for self-sustaining acidic ammonia electrosynthesis[J]. Angewandte Chemie, 2025,64(27):202505211.
[42] Zhou J, Zhu Y, Wen K, et al. Efficient and selective electrochemical nitrate reduction to N₂using a flow-through zero-gap electrochemical reactor with a reconstructed Cu(OH)₂ cathode: insights into the importance of inter-electrode distance[J]. Environmental Science & Technology, 2024,58(10):4824-4836.
[43] Xie F, Wu Z, Yang J. Valorizing nitrate in electrochemical nitrogen cycling: copper-based catalysts from reduction to C-N coupling[J]. Small, 2025,21(20):2500833.
[44] Zhang J, Xing C, An S, et al. NaBH₄-assisted reconstruction of binary micro-domains on Cu electrode for the selective production of green ammonia[J]. Green Chemistry, 2025,27:7129-7136.
[45] Thani E S, Yang Y T, Du Q Y, et al. Porous Cu nanosheets for efficient ammonia production via nitrate electroreduction[J]. Materials Chemistry Frontiers, 2025,9:2243-2249.
[46] He Z, Zhou Q, Zi X, et al. Unlocking ampere-level nitrate electroreduction to ammonia via the built-in electric field in monometallic catalysts[J]. Nano Letters, 2025,25(23):9221–9228.
[47] Jin T, Wang J, Gong Y, et al. Mechanochemical-tuning size dependence of iridium single atom and nanocluster toward highly selective ammonium production[J]. Chem Catalysis, 2023,3(1):100477.
[48] Zhang N, Zhang G, Shen P, et al. Lewis acid Fe-V pairs promote nitrate electroreduction to ammonia[J]. Advanced Functional Materials, 2023, 33(13):2211537.
[49] Zhang F, Luo J, Chen J, et al. Interfacial assembly of nanocrystals on nanofibers with strong interaction for electrocatalytic nitrate reduction[J]. Angewandte Chemie, 2023,135(38):202310383.
[50] Huang Y, He C, Cheng C, et al. Pulsed electroreduction of low- concentration nitrate to ammonia[J]. Nature Communications, 2023,14(1):7368.
[51] Li J, Li M, An N, et al. Atomically dispersed Fe atoms anchored on S and N-codoped carbon for efficient electrochemical denitrification[J]. Proceedings of the National Academy of Sciences, 2021,118(33): e2105628118.
[52] Liang X, Fu N, Yao S, et al. The progress and outlook of metal single-atom-site catalysis[J]. Journal of the American Chemical Society, 2022,144(40):18155-18174.
[53] Liu C, Sheng B, Zhou Q, et al. Manipulating d-band center of nickel by single-iodine-atom strategy for boosted alkaline hydrogen evolution reaction[J]. Journal of the American Chemical Society, 2024,146(39):26844-26854.
[54] Jin J, Wicks J, Min Q, et al. Constrained C₂adsorbate orientation enables CO-to-acetate electroreduction[J]. Nature, 2023,617(7962): 724-729.
[55] Osorio-Tejada J, Escriba-Gelonch M, Vertongen R, et al. CO₂ conversion to CO via plasma and electrolysis: a techno-economic and energy cost analysis[J]. Energy & Environmental Science, 2024,17(16):5833-5853.
[56] Wang X, Wang J J, Hu H, et al. Harnessing spin-lattice interplay in metal nitrides for efficient ammonia electrosynthesis[J]. Advanced Materials, 2025,37(29):2504505.
[57] Wu Y, Zhuang Z, Chen C, et al. Atomic-level regulation strategies of single-atom catalysts: Nonmetal heteroatom doping and polymetallic active site construction[J]. Chem Catalysis, 2023,3(7):100586.
[58] Yu J, Gao R T, Guo X, et al. Electrochemical nitrate reduction to ammonia on AuCu single-atom alloy aerogels under wide potential window[J]. Angewandte Chemie, 2025,64(4):202415975.
[59] Zhang X, Liu X, Huang Z F, et al. Regulating intermediate adsorption and H₂O dissociation on a diatomic catalyst to promote electrocatalytic nitrate reduction to ammonia[J]. Energy & Environmental Science, 2024,17(18):6717-6727.
[60] Tschitschko B, Esti M, Philippi M, et al. Rhizobia-diatom symbiosis fixes missing nitrogen in the ocean[J]. Nature, 2024,630(8018):899-904.
[61] Yadav D K, Latiyan S, Devan R S, et al. Breaking barriers: synergistic interactions between pt single atoms and nitrogen-rich g-C₃N₄ for maximized photocatalytic hydrogen production[J]. Small, 2025,21(30):2503843.
[62] Lu X, Wu J, He X, et al. Ordered single active sites for cascade hydrogenation and hydroformylation reactions[J]. Nature Catalysis, 2025,8:536–547.
[63] Zhang Q, Guan J. Single-atom catalysts for electrocatalytic applications[J]. Advanced Functional Materials, 2020,30(31):2000768.
[64] Li L, Chang X, Lin X, et al. Theoretical insights into single-atom catalysts[J]. Chemical Society Reviews, 2020,49:8156-8178.
[65] Li Y, Sun Q. Recent advances in breaking scaling relations for effective electrochemical conversion of CO₂[J]. Advanced Energy Materials, 2016,6(17):1600463.
[66] Zhang J, Guo S, Li T, et al. Unravelling the high-valence iridium single-atoms on MnCoO_x clusters for proton exchange membrane water electrolyzer[J]. Applied Catalysis B: Environment and Energy, 2025,377:125518.
[67] Huang C, Wang Q, Wei X, et al. Microenvironment-coordinated P₁CoN₃ single-atom sites for selective photocatalytic CO₂ reduction to C₂ products[J]. Journal of Catalysis, 2025,450:116245.
[68] Wang T, Wang J, Lu C, et al. Single-atom anchored curved carbon surface for efficient CO₂ electro-reduction with nearly 100% co selectivity and industrially-relevant current density[J]. Advanced Materials, 2023,35(35):2205553.
[69] Jin Z, Yang M, Dong Y, et al. Atomic dispersed hetero-pairs for enhanced electrocatalytic CO₂ reduction[J]. Nano-Micro Letters, 2023,16(4):1-13.
[70] Hu Q, Qi S, Huo Q, et al. Designing efficient nitrate reduction electrocatalysts by identifying and optimizing active sites of Co-based spinels[J]. Journal of the American Chemical Society, 2024,146(5): 2967-2976.
[71] Dai P, Lang J, Huang W, et al. Spin state modulation via magnetic fields in fe single atom catalysts for high-performance aqueous zinc- sulfur batteries[J]. ACS Nano, 2025,19(22):21083–21094.
[72] Yuan J, Chen F, Feng W, et al. Dynamic switching spin state of Fe single atoms for piezoelectric-mediated overall nitrogen fixation photosynthesis[J]. Advanced Materials, 2025,37(32):e2504015.
[73] Li Q, Luo L, Guo X, et al. Modulation of the second-beyond coordination structure in single-atom electrocatalysts for confirmed promotion of ammonia synthesis[J]. Journal of the American Chemical Society, 2025,147(2):1884-1892.
[74] Wu X, Nazemi M, Gupta S, et al. Contrasting capability of single atom palladium for thermocatalytic versus electrocatalytic nitrate reduction reaction[J]. ACS Catalysis, 2023,13(10):6804-6812.
[75] 杨鑫,韩春秋,曹玥晗,等.金属氧化物电催化硝酸盐还原合成氨研究进展[J]. 无机材料学报, 2024,39(9):1-13. Yang X, Han C, Cao Y, et al. Recent advances in electrocatalytic nitrate reduction to ammonia using metal oxides[J]. Journal of Inorganic Materials, 2024,39(9):1-13.
[76] 韩晶,廖润华,邓文强,等.铜掺杂氮化碳电催化硝酸盐产氨性能研究[J]. 化学学报, 2024,82:295-302. Han J, Liao R, Deng W, et al. Study on performance of copper doped carbon nitride electrocatalyzing nitrate to produce ammonia[J]. Acta Chim. Sinica, 2024,82:295-302.
[77] 梁彩凤,赵港,吴琪.铜基催化剂在电催化硝酸根还原制氨中的应用[J]. 材料导报, 2025,39(15):205-212. Liang C, Zhao G, Wu Q. Application of copper-based catalysts in electrocatalytic nitrate reduction to ammonia[J]. Materials Reports, 2025,39(15):205-212.
[78] 董亚男,赵长盛,陈庆锋,等.铜基材料电催化还原硝酸盐制氨研究进展[J]. 精细化工, 2024,41:762. Dong Y, Zhao C, Chen Q, et al. Advances in electrocatalytic reduction of nitrate to ammonia over copper-based catalysts[J]. Fine Chemicals, 2024,41:762.
[79] Du H L, Chatti M, Hodgetts R Y, et al. Electroreduction of nitrogen with almost 100% current-to-ammonia efficiency[J]. Nature, 2022, 609(7928):722-727.
[80] Foster S L, Bakovic S I P, Duda R D, et al. Catalysts for nitrogen reduction to ammonia[J]. Nature Catalysis, 2018,1(7):490-500.
[81] Cheng N, Zhang L, Doyle-Davis K, et al. Single-atom catalysts: from design to application[J]. Electrochemical Energy Reviews, 2019, 2(4):539-573.
[82] Wang A, Li J, Zhang T. Heterogeneous single-atom catalysis[J]. Nature Reviews Chemistry, 2018,2(6):65-81.
[83] Yang J, Qi H, Li A, et al. Potential-driven restructuring of Cu single atoms to nanoparticles for boosting the electrochemical reduction of nitrate to ammonia[J]. Journal of the American Chemical Society, 2022,144(27):12062-12071.
[84] Sun P, Liu S, Zheng X, et al. Challenges and opportunities of atomic-scales reactive sites in thriving electrochemical CO₂ reduction reaction[J]. Nano Today, 2024,55:102152.
[85] You X, Guo Z, Jiang Q, et al. Magnetic-field-induced spin transition in single-atom catalysts for nitrate electrolysis to ammonia[J]. Nano Letters, 2025,25(21):8704-8712.
[86] Sun P, Gracia-Espino E, Tan F, et al. Treasure-bowl style bifunctional site in cerium–tungsten hetero-clusters for superior solar-driven hydrogen production[J]. Materials Horizons, 2024,11(16):3892-3902.
[87] Ajmal S, Kumar A, Mushtaq M A, et al. Uniting synergistic effect of single-Ni site and electric field of B-bridged-N for boosted electrocatalytic nitrate reduction to ammonia[J]. Small, 2024,20(32):2310082.
[88] Xu J, Zhang S, Liu H, et al. Breaking local charge symmetry of iron single atoms for efficient electrocatalytic nitrate reduction to ammonia[J]. Angewandte Chemie, 2023,135(39):e202308044.
[89] Xiang T, Liu X, Wang Z, et al. Boosting active hydrogen generation via ruthenium single atoms for efficient electrocatalytic nitrate reduction to ammonia[J]. Applied Catalysis B: Environment and Energy, 2025,365:124943.
[90] Li J, Li M, An N, et al. Boosted ammonium production by single cobalt atom catalysts with high faradic efficiencies[J]. Proceedings of the National Academy of Sciences, 2022,119(29):e2123450119.
[91] Zhang Y, Chen X, Wang W, et al. Electrocatalytic nitrate reduction to ammonia on defective Au₁Cu (111) single-atom alloys[J]. Applied Catalysis B: Environment and Energy, 2022,310:121346.
[92] Chen G F, Yuan Y, Jiang H, et al. Electrochemical reduction of nitrate to ammonia via direct eight-electron transfer using a copper– molecular solid catalyst[J]. Nature Energy, 2020,5(8):605-613.
[93] Lim J, Liu C Y, Park J, et al. Structure sensitivity of Pd facets for enhanced electrochemical nitrate reduction to ammonia[J]. ACS Catalysis, 2021,11(12):7568-7577.
[94] Gao W, Xie K, Xie J, et al. Alloying of Cu with Ru enabling the relay catalysis for reduction of nitrate to ammonia[J]. Advanced Materials, 2023,35(19):2202952.
[95] Zhang B, Yang C, Jia Y, et al. Spin modulation of single Fe atoms with thiolate-poisoned Pd nanoclusters for highly efficient ammonia synthesis[J]. AIChE Journal, 2024,70(7):e18449.
[96] Dou F, Guo F, Li B, et al. Pulsed electro-catalysis enables effective conversion of low-concentration nitrate to ammonia over Cu₂O@Pd tandem catalyst[J]. Journal of Hazardous Materials, 2024,472:134522.
[97] Zhang M, Song K, Liu C, et al. Electron-rich Au nanocrystals/Co₃O₄ interface for enhanced electrochemical nitrate reduction into ammonia[J]. Journal of Colloid and Interface Science, 2023,650:193-202.
[98] Zhou B, Zhan G, Yao Y, et al. Renewable energy driven electroreduction nitrate to ammonia and in-situ ammonia recovery via a flow-through coupled device[J]. Water Research, 2023,242:120256.
[99] Huang T, Liang T, You J, et al. Coordination environment-tailored electronic structure of single atomic copper sites for efficient electrochemical nitrate reduction toward ammonia[J]. Energy & Environmental Science, 2024,17(21):8360-8367.
[100]Cao H, Liang B, Ye S, et al. Constructing Ru single-atomic sites through potential-induced self-reconstruction to accelerate electrocatalytic nitrate reduction for ammonia production[J]. Chemical Engineering Journal, 2024,490:151883.
[101]Yang W, Chang Z, Yu X, et al. Triple regulations via Fe redox boosting nitrate reduction to ammonia at industrial current densities[J]. Angewandte Chemie, 2025,137(3):e202415300.
[102]Wu S, Yan J, Zhao D, et al. Three-dimensional RuCo alloy nanosheets arrays integrated pinewood-derived porous carbon for high-efficiency electrocatalytic nitrate reduction to ammonia[J]. Journal of Colloid and Interface Science, 2024,668:264-271.
[103]Li P, Jin Z, Fang Z, et al. Single-site iron catalyst with preoccupied active centers that achieves selective ammonia electrosynthesis from nitrate[J]. Energy & Environmental Science, 2021,14(6):3522-3531.
[104]Zhao Z L, Yang S, Wang S, et al. Isolated rhodium atoms activate porous TiO₂ for enhanced electrocatalytic conversion of nitrate to ammonia[J]. Advanced Science, 2024,12(2):2411705.
[105]Wan J, Yang J, Yang N, et al. Axial chlorine-induced symmetry- breaking iron single-atom catalyst for electrochemical ammonia synthesis[J]. ACS Catalysis, 2025,15(6):4507-4518.
[106]Li L X, Sun W J, Zhang H Y, et al. Highly efficient and selective nitrate electroreduction to ammonia catalyzed by molecular copper catalyst@Ti₃C₂T_x Mxene[J]. Journal of Materials Chemistry A, 2021,9(38):21771-21778.
[107]Zhang S, Zha Y, Ye Y, et al. Oxygen-coordinated single Mn sites for efficient electrocatalytic nitrate reduction to ammonia[J]. Nano-Micro Letters, 2023,16(9):1-13.
[108] Li H, Gan K, Li R, et al. Highly dispersed NiO clusters induced electron delocalization of Ni-N-C catalysts for enhanced CO₂ electroreduction[J]. Advanced Functional Materials, 2023,33(1):2208622.
[109]Li Y, Pei Z, Luan D, et al. Superhydrophobic and conductive wire membrane for enhanced CO₂ electroreduction to multicarbon products[J]. Angewandte Chemie, 2023,62(19):e202302128.
[110]Gawande M B, Fornasiero P, Zbořil R. Carbon-based single-atom catalysts for advanced applications[J]. ACS Catalysis, 2020,10(3): 2231-2259.
[111]Cui Y, Ren C, Li Q, et al. Hybridization state transition under working conditions: activity origin of single-atom catalysts[J]. Journal of the American Chemical Society, 2024,146(22):15640-15647.
[112]Dong C, Gao Z, Li Y, et al. Fully exposed palladium cluster catalysts enable hydrogen production from nitrogen heterocycles[J]. Nature Catalysis, 2022,5(6):485-493.
[113]Gu Z, Zhang Y, Fu Y, et al. Coordination desymmetrization of copper single-atom catalyst for efficient nitrate reduction[J]. Angewandte Chemie, 2024,136(38):e202409125.
[114]Liu Y, Qiu W, Wang P, et al. Pyridine-N-rich Cu single-atom catalyst boosts nitrate electroreduction to ammonia[J]. Applied Catalysis B: Environment and Energy, 2024,340:123228.
[115]Long X, Huang F, Zhong T, et al. One-step strategy to maximize single-atom catalyst utilization in nitrate reduction via bidirectional optimization of mass transfer and electron supply[J]. Environmental Science & Technology, 2025,59(17):8555-8567.
[116]Sun P, Li C, Xu J, et al. Effect of Sn element on optimizing thermoelectric performance of Te nanowires[J]. Sustainable Energy & Fuels, 2018,2(12):2636-2643.
[117]Sun P, Zhou Y, Li H, et al. Round-the-clock bifunctional honeycomb- like nitrogen-doped carbon-decorated Co₂P/Mo₂ C-heterojunction electrocatalyst for direct water splitting with 18.1% STH efficiency[J]. Applied Catalysis B: Environment, 2022,310:121354.
[118]Yu S, Kang H, Jee S, et al. MOF-based single-atom and metal cluster catalysts by room-temperature synthesis for tumor therapy[J]. Advanced Healthcare Materials, 2025,14(18):2501058.
[119]Jiang S, Xue J, Liu T, et al. Visualization of the distance-dependent synergistic interaction in heterogeneous dual-site catalysis[J]. Journal of the American Chemical Society, 2024,146(42):29084-29093.
[120]Sun P, Zheng X, Chen A, et al. Constructing amorphous-crystalline interfacial bifunctional site island-sea synergy by morphology engineering boosts alkaline seawater hydrogen evolution[J]. Advanced Science, 2024,11(24):2309927.
[121]Tan F, Zhou Y, Zhang H, et al. Improving the hydrogen evolution reaction activity of molybdenum-based heterojunction nanocluster capsules via electronic modulation by erbium-nitrogen-phosphorus ternary doping[J]. Chemical Engineering Journal, 2023,454:140079.
[122]Wang S, Wang L, Wang D, et al. Recent advances of single-atom catalysts in CO₂ conversion[J]. Energy & Environmental Science, 2023,16(7):2759-2803.
[123]Zhou B, Tong Y, Yao Y, et al. Reversed I₁Cu₄single-atom sites for superior neutral ammonia electrosynthesis with nitrate[J]. Proceedings of the National Academy of Sciences, 2024,121(37):e2405236121.
[124]Xu J, Zhang S, Liu H, et al. Breaking local charge symmetry of iron single atoms for efficient electrocatalytic nitrate reduction to ammonia[J]. Angewandte Chemie, 2023,135(39):e202308044.
[125] Sun L, Reddu V, Wang X. Multi-atom cluster catalysts for efficient electrocatalysis[J]. Chemical Society Reviews, 2022,51(21):8923-8956.
[126] Yue C, Yang X, Zhang X, et al. Secondary coordination sphere engineering of single-Sn-atom catalyst via P doping for efficient CO₂ electroreduction[J]. Advanced Energy Materials, 2024,14(38):2401448.
[127]Yin L, Zhang S, Sun M, et al. Heteroatom-driven coordination fields altering single cerium atom sites for efficient oxygen reduction reaction[J]. Advanced Materials, 2023,35:e2302485.
[128]H Wu, B Tian, W Xu, et al. Pressure-dependent CO₂ electroreduction to methane over asymmetric Cu–N₂ single-atom sites[J]. Journal of the American Chemical Society, 2024,146:22266-22275.
[129] C.D. Koolen J K, Pedersen B, Zijlstra, et al. Scalable synthesis of Cu-cluster catalysts via spark ablation for the electrochemical conversion of CO₂ to acetaldehyde[J]. Nature Synthesis, 2025,4(3):336-346.
[130]Shim J, Sung Y E. Unlocking iron spin states for oxygen reduction[J]. Nature Catalysis, 2025,8(5):417-419.
[131]Xu Z, Gao M, Wei Y, et al. Pt migration-lockup in zeolite for stable propane dehydrogenation catalyst[J]. Nature, 2025,643:691–698.
[132]Yang L, Wang C, Li Y, et al. Frustrated lewis pairs on Zr single atoms supported N-doped TiO_2-x catalysts for electrochemical nitrate reduction to ammonia[J]. Advanced Functional Materials, 2024,34(36):2401094.
[133]Xie T, Chen S, Yue Y, et al. Biomimetic phthalocyanine-based covalent organic frameworks with tunable pendant groups for electrocatalytic CO₂ reduction[J]. Angewandte Chemie, 2024,63, e202411188.
[134]Dai T Y, Wang T H, Wen Z, et al. Recent progress on computation- guided catalyst design for highly efficient nitrogen reduction reaction[J]. Advanced Functional Materials, 2024,34(34):2400773.
[135]Lv L, Shen Y, Liu J, et al. Computational screening of high activity and selectivity TM/g-C₃N₄ single-atom catalysts for electrocatalytic reduction of nitrates to ammonia[J]. Journal of Physical Chemistry Letters, 2021, 12(45):11143-11150.
[136]Wen X, Geng X, Su G, et al. Machine learning-driven design of single-atom catalysts for carbon dioxide valorization to high-value chemicals: a review of photocatalysis, electrocatalysis, and thermocatalysis[J]. Green Chemistry, 2025,27(18):4898-4925.
[137]Yu Q, Ma N, Leung C, et al. AI in single-atom catalysts: a review of design and applications[J]. Journal of Materials Informatics, 2025, 5(1):9.