|
|
Research on aqueous hydroxyl radical generated from minerals of dust fall in Tianshui |
ZHANG Liu-fei1,2, DONG Fa-qin2, TAN Dao-yong2, SUN Shi-yong2, WANG Bin2 |
1. School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China;
2. Key Laboratory of Solid Waste Treatment and Resource Recycle, Ministry of Education, Mianyang 621010, China |
|
|
Abstract The generation of aqueous hydroxyl radical from the dust fall, collected from Tianshui City, Gansu province, was investigated using the high performance liquid chromatography method. The mineral composition of dust fall was quartz (57.08%), calcite (27.79%), albite (10.29%), and muscovite (4.84%). The amount of generated hydroxyl radical from dust fall, simulated dust fall (including theoretical calculation method and physical mix method), and pure minerals were in the following order:calcite (1.30×10-10 mol)> simulated dust fall (calculation) (5.47×10-11 mol)> dust fall (5.34×10-11 mol)> quartz (2.90×10-11 mol)> muscovite (1.90×10-11 mol)> albite (1.09×10-11 mol)> dust fall (mix) (7.16×10-12 mol). The minerals in dust fall had the major contribution to the formation of hydroxyl radical. The discrepancy in the amount of the generated hydroxyl radical between dust fall and simulated dust fall was caused by mineral composition, the dissolution of metallic ions and organic compounds in water, the surface area of minerals, and the interactions between the mineral and the water media.
|
Received: 16 July 2015
|
|
|
|
|
[1] |
NIH. Genetics home reference[Z]. U.S. National Library of Medicine, 2006.
|
[2] |
Cohn C A. Mineral-generated reactive oxygen species[D]. New York:Stony Brook university, 2006:1-201.
|
[3] |
Fenton H J H. Oxidation of tartaric acid in the presence of iron[J]. Journal of the Chemical Society, Transactions, 1894,(65):899-910.
|
[4] |
Cohn C A, Laffers R, Schoonen M A A. Using Yeast RNA as a Probe for Generation of Hydroxyl Radicals by Earth Materials[J]. Environmental Science & Technology, 2006,40(8):2838-2843.
|
[5] |
Gazzano E, Foresti E, Lesci I G, et al. Different cellular responses evoked by natural and stoichiometric synthetic chrysotile asbestos[J]. Toxicology and Applied Pharmacology, 2005,206(3):356-364.
|
[6] |
刘立柱,董发勤,孙仕勇,等.石英粉/磷酸盐缓冲溶液体系中羟基自由基荧光分光光度法定量检测研究[J]. 光谱学与光谱分析, 2014,34(7):1886-1889.
|
[7] |
Cooper W J, Zika R G. Photochemical formation of hydrogen peroxide in surface and ground Waters[J]. Science, 1983,220(4598):711-712.
|
[8] |
Wilson C L, Hinman N W, Cooper W J, et al. Hydrogen peroxide cycling in surface geothermal waters of Yellowstone National Park[J]. Environmental Science & Technology, 2000,34(13):2655-2662.
|
[9] |
Strli? M, Kolar J, Šelih V-S, et al. A comparative study of several transition metals in Fenton-like reaction systems at circumneutral pH[J]. Acta Chimica Slovenica, 2003,(50):619-632.
|
[10] |
Jacobson M C, Hansson H C, Noone K J, et al. Organic atmospheric aerosols:review and state of the science[J]. Reviews of Geophysics, 2000,38(2):267-294.
|
[11] |
Wilson W E, Chow J C, Claiborn C, et al. Monitoring of particulate matter outdoors[J]. Chemosphere, 2002,49(9):1009-1043.
|
[12] |
Brook R D, Brook J R, Rajagopalan S, Air pollution:the "heart" of the problem[J]. Current Hypertension Reports, 2003,5(1):32-39.
|
[13] |
Knaapen A M, Seiler F, Schilderman P A, et al. Neutrophils cause oxidative DNA damage in alveolar epitheliar cells[J]. Free Radical Biology and Medicine, 1999,27(1/2):234-240.
|
[14] |
Knaapen A M, Borm P J, Albrecht C, et al. Inhaled particles and lung cancer. Part A:Mechanisms[J]. International Journal of Cancer, 2004,109(6):799-809.
|
[15] |
周林,邵龙义,刘君霞,等.宣威肺癌高发区室内PM10对肺泡上皮细胞凋亡的影响[J]. 中国环境科学, 2010,30(7):1004-1008.
|
[16] |
Halliwell B. Role of free radicals in the neurodegenerative diseases-Therapeutic implications for antioxidant treatment[J]. Drugs and Aging, 2001,18(9):685-716.
|
[17] |
Iuga C, Sainzdíaz C I, Vivierbunge A. Hydroxyl radical initiated oxidation of formic acid on mineral aerosols surface:a mechanistic, kinetic and spectroscopic study[J]. Environmental Chemistry, 2015,12(2):236-244.
|
[18] |
Hellack B, Quass U, Beuck H, et al. Elemental composition and radical formation potency of PM10 at an urban background station in Germany in relation to origin of air masses[J]. Atmospheric Environment, 2015,105:1-6.
|
[19] |
Aruguete D M, Hochella J M F. l.Bacteria-nanoparticle interactions and their environmental implications[J]. Environmental Chemistry, 2010,(7):3-9.
|
[20] |
Ana C B. Almeida L, Tiago S. P, et al. Lead Exposure and Oxidative Stress:A Systematic Review[J]. Reviews of Environmental Contamination and Toxicology, 2016,236,193-238.
|
[21] |
Raúl O Q B, Ernesto A M, Claudia M G C, et al.Evaluation of the oxidative potential of urban PM and its relation to in vitro induced DNA damage:a spatial and temporal comparison[J]. Rev. Int. Contam. Ambie, 2015,31(2):145-154.
|
[22] |
唐建军,陈益清,李文龙,TiO2及负载Fe(Ⅲ)可见光催化H2O2降解扑草净的协同效应[J]. 中国环境科学, 2015,35(3):777-782.
|
[23] |
董发勤,贺小春,李国武,我国北方部分地区大气粉尘的特征研究[J]. 岩石矿物, 2005,25(3):114-117.
|
[24] |
陈武,董发勤,代群威,等.天水市大气降尘组成特征及表面电性模拟研究[J]. 环境科学学报, 2013,33(12):3386-3390.
|
[25] |
张彭义,余刚,蒋展鹏,苯甲酸类光催化降解和羟基自由基反应的关系[J]. 中国环境科学, 1999,19(3):193-196.
|
[26] |
Medina A, Gamero P, Almanza J M. Fly ash from a Mexican mineral coal. II. Source of W zeolite and its effectiveness in arsenic (V) adsorption[J]. Journal of hazardous materials, 2010, 181(1):91-104.
|
[27] |
胡颖,邵龙义,沈蓉蓉,等.北京市PM2.5对DNA的氧化性损伤规律分析[J]. 中国环境科学, 2013,33(10):1863-1868.
|
[28] |
Balaz P. Mechanical activation in hydrometallurgy[J]. International Journal of Mineral Processing, 2003,72(1-4):341-354.
|
[29] |
Fubini B, Hubbard A. Reactive oxygen species (ROS) and Reactive nitrogen species (RNS) generation by silica in inflammation and fibrosis[J]. Free Radical Biology and Medicine, 2003,34(12):1507-1516.
|
[30] |
Saruwatari K, Kameda J, Tanaka H. Generation of hydrogen ions and hydrogen gas in quartz-water crushing experiments:an example of chemical processes in active faults[J]. Physis and Chemistry of Minerals, 2004,31(3):176-182.
|
[31] |
Narayanasamy J, Kubicki J D. Mechanism of hydroxyl radical generation from a silica surface:molecular crbital calculations[J]. Journal of Physical Chemistry B, 2005,109(46):21796-21807.
|
[32] |
Gao Z Y, Sun W, Hu Y H, et al. Anisotropic surface broken bond properties and wettability of calcite and fluorite crystals[J]. Transactions of Nonferrous Metals Society of China, 2012,(22):1203-1208.
|
[33] |
Karagüzel C, Can M F, Sönmez E, et al. Effect of electrolyte on surface free energy components of feldspar minerals using thin-layer wicking method[J]. Journal of Colloid and Interface Science, 2005,285(1):192-200.
|
[34] |
Gumpu M B, Sethuraman S, Krishnan U M, et al. A review on detection of heavy metal ions in water-An electrochemical approach[J]. Sensors and Actuators B:Chemical, 2015,213:515-533.
|
|
|
|