|
|
Treatment of residual water from heavy metals contaminated sediment dredging by electro-coagulation-flotation based on real-time control strategy |
XU Hai-yin1,2, YANG Zhao-hui1,2, ZENG Guang-ming1,2, LUO Yuan-ling3, HUANG Jing1,2, WANG Li-ke1,2, SONG Pei-pei1,2 |
1. College of Environmental Science and Engineering, Hunan University, Changsha 410082, China;
2. Key Laboratory of Environmental Biology and Pollution Control, Ministry of Education, Hunan University, Changsha 410082, China;
3. Changsha Environmental Protection College, Changsha 410004, China |
|
|
Abstract Residual water from heavy metals contaminated sediment dredging had high concentrations of heavy metals, fluctuant water-quality and poor sedimentation. Electro-coagulation-flotation with aluminium anode (Al-ECF) was applied to treat residual water. First, pH and turbidity were selected as monitoring factors of real-time control. Then, a real-time control response model of ratio current and residual cadmium (Cd) was established by the tools of precipitation simulation and data fitting. Experiment results showed that Al-ECF could neutralize pH and improve separation performance and lead (Pb), Cd and zinc (Zn) of effluent met the discharge standards. Additionally, the real-time control strategy could save 35.8% of anode material and 43.4% of electricity power and reduce 47.9% of sludge production.
|
Received: 20 August 2015
|
|
|
|
|
[1] |
王 川,杨朝晖,曾光明,等.DTCR协同水泥固化/稳定化重金属污染底泥的研究[J]. 中国环境科学, 2012,32(11):2060-2066.
|
[2] |
黄丹莲,罗湘颖,许 飘,等.可用于处理底泥清淤尾水中重金属的构筑物及其施工方法, CN103539266A[P]. 2013-10-31.
|
[3] |
童 非,顾雪元.重金属离子与典型离子型有机污染物的络合效应研究[J]. 中国环境科学, 2014,34(7):1776-1784.
|
[4] |
刘 成,邵世光,范成新,等.巢湖重污染汇流湾区沉积物重金属污染特征及风险评价[J]. 中国环境科学, 2014,34(4):1031-1037.
|
[5] |
Yenilmez F, Aksoy A. Comparison of phosphorus reduction alternatives in control of nutrient concentrations in Lake Uluabat: Partial versus full sediment dredging[J]. Limnologica-Ecology and Management of Inland Waters, 2013,43(1):1-9.
|
[6] |
Chiang Y W, Ghyselbrecht K, Santos R M, et al. Adsorption of multi-heavy metals onto water treatment residuals: Sorption capacities and applications[J]. Chem Eng J, 2012,200-202:405-415.
|
[7] |
Xu H Y, Yang Z H, Zeng G M, et al. Investigation of pH evolution with Cr (VI) removal in electrocoagulation process: Proposing a real-time control strategy[J]. Chem. Eng. J., 2014,239:132-140.
|
[8] |
郑志勇,徐海音,宋佩佩,等.电絮凝在水处理中的研究进展[J]. 现代化工, 2015,35(4):29-32,34.
|
[9] |
虞少嵚,熊道文,陈湘斌,等.周期换向电絮凝法用于处理含铬废水研究[J]. 中国环境科学, 2014,34(1):118-122.
|
[10] |
Yang Z H, Xu H Y, Zeng G M, et al. The behavior of dissolution/passivation and the transformation of passive films during electrocoagulation: Influences of initial pH, Cr (VI) concentration, and alternating pulsed current[J]. Electrochim Acta, 2015,153:149-158.
|
[11] |
Gustafsson J. Visual MINTEQ version 3.0[M]. KTH Royal Inst of Technol, Stockholm, Sweden, 2010.
|
[12] |
Heidmann I, Calmano W. Removal of Ni, Cu and Cr from a galvanic wastewater in an electrocoagulation system with Fe-and Al-electrodes[J]. Sep. Purif. Technol., 2010,71(3):308-314.
|
[13] |
Song P P, Yang Z H, Xu H Y, et al. Investigation of Influencing Factors and Mechanism of Antimony and Arsenic Removal by Electrocoagulation Using Fe-Al Electrodes[J]. Ind. Eng. Chem. Res., 2014,53(33):12911-12919.
|
[14] |
Xu H Y, Yang Z H, Luo Y L, et al. A novel approach to sustain Fe0-electrocoagulation for Cr (VI) removal by optimizing chloride ions[J]. Sep. Purif. Technol., 2015,156:200-206.
|
[15] |
HJ 2007-2010 污水气浮处理工程技术规范[S].
|
[16] |
Gao P, Chen X M, Shen F, et al. Removal of chromium (VI) from wastewater by combined electrocoagulation-electroflotation without a filter[J]. Sep. Purif. Technol., 2005,43(2):117-123.
|
[17] |
谭 竹,杨朝晖,徐海音,等.铝铁电极联用电絮凝法处理Cu-EDTA络合废水[J]. 环境工程学报, 2014,8(8):3167-3173.
|
[18] |
Huang J, Yang Z H, Zeng G M, et al. Influence of composite flocculant of PAC and MBFGA1on residual aluminum species distribution[J]. Chem. Eng. J., 2012,191:269-277.
|
|
|
|