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| Simulations of the atmospheric benzo[a]pyrene in China using CMAQ model |
| YAN Wen-jun1,2, LIU Min1, LIU Shi-jie2, HE You-jiang2, TANG Wei2, WANG Qing1, LI Ye1, MENG Fan2 |
1. Key Laboratory of Geographic Information Science, Ministry of Education, College of Geographic Sciences, East China Normal University, Shanghai 200241, China;
2. Atmospheric Environment Institute, Chinese Research Academy of Environmental Sciences, Beijing 100012, China |
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Abstract The modules for simulating transport, transformation and deposition processes, as well as gas/particle partitioning (KOA absorption mechanism) processes of atmospheric BaP was implemented into the CMAQ, a regional air quality model developed by U.S. E.P.A. The spatial distributions of BaP concentrations, dry and wet deposition rates are simulated for January, April, July and October 2014 in China. The comparison between modeled and observed BaP concentrations shows the predicted values were in an acceptable range. The predicted deposition results show that the wet deposition is the dominant deposition pathway. The spatial distributions of the BaP depositions are closely related to that of the anthropogenic emissions and present obvious long-distance transportation characteristics.
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Received: 06 November 2015
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| [1] |
唐孝炎,张远航,邵 敏.大气环境化学 [M]. 北京:高等教育出版社, 2006:91-101.
|
| [2] |
Wania F, Mackay D. Tracking the distribution of persistent organic pollutants [J]. Environ. Sci. Technol., 1996,30(9):390-396.
|
| [3] |
Jang C J C, Chang N B. Development and application of U.S. EPA's Models-3: An integrated ""one-atmosphere"" third-generation air quality modeling system [J]. Journal of the Chinese Institute of Environmental Engineering, 2000,10(1):19-34.
|
| [4] |
Byun D W, Ching J K S. Science Algorithms of the EPA Models-3Community Multiscale Air Quality (CMAQ) Modeling System [Z]. EPA-600/R-99/030, US Environmental Protection Agency. US Government Printing Office, Washington, DC.See also /http://www.epa.gov/asmdnerl/models3/doc/science/science. html.
|
| [5] |
San José R, Pérez J L, Callén M S, et al. BaP (PAH) air quality modelling exercise over Zaragoza (Spain) using an adapted version of WRF-CMAQ model [J]. Environmental Pollution, 2013,183:151-158.
|
| [6] |
Zhang H, Ying Q. Secondary organic aerosol from polycyclic aromatic hydrocarbons in Southeast Texas [J]. Atmospheric Environment, 2012,55:279-287.
|
| [7] |
Matthias V, Aulinger A, Quante M. CMAQ simulations of the Benzo(a)pyrene distribution over Europe for 2000and 2001 [J]. Atmospheric Environment, 2009,43(26):4078-4086.
|
| [8] |
Simcik M F, Franz T P, Zhang H, et al. Gas-particle partitioning of PCBs and PAHs in the Chicago urban and adjacent coastal atmosphere: states of equilibrium [J]. Environmental Science & Technology, 1998,32(2):251-257.
|
| [9] |
Matthias V, Aulinger A, Quante M. Adapting CMAQ to investigate air pollution in North Sea coastal regions [J]. Environmental Modelling & Software, 2008,23(3):356-368.
|
| [10] |
Meng F, Zhang B, Gbor P, et al. Models for gas/particle partitioning, transformation and air/water surface exchange of PCBs and PCDD/Fs in CMAQ [J]. Atmospheric Environment, 2007,41(39):9111-9127.
|
| [11] |
Zhang B, Meng F, Shi C, et al. Modeling the atmospheric transport and deposition of polychlorinated dibenzo-p-dioxins and dibenzofurans in North America [J]. Atmospheric Environment, 2009,43(13):2204-2212.
|
| [12] |
Bewersdorff I, Aulinger A, Volker M, et al. Modeling of benzo(a)pyrene concentrations in north sea coastal areas: contribution of ship emissions [J]. Hrvatski Meteorološki ?asopis, 2008,43(43/2):586-590.
|
| [13] |
Wang W, Simonich S L M, Wang W, et al. Atmospheric polycyclic aromatic hydrocarbon concentrations and gas/particle partitioning at background, rural village and urban sites in the North China Plain [J]. Atmospheric Research, 2011,99(2):197-206.
|
| [14] |
汪祖丞,刘 敏,杨 毅,等.上海城区多环芳烃的多介质归趋模拟研究 [J]. 中国环境科学, 2011,31(6):984-990.
|
| [15] |
刘 敏,王兰辉.城市地表系统POPs多介质循环过程与模拟研究进展 [J]. 中国环境科学, 2013,33(11):2018-2026.
|
| [16] |
Tao S, Li X, Yang Y, et al. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China [J]. Environmental Science & Technology, 2006,40(15):4586-4591.
|
| [17] |
Liu S, Lu Y, Wang T, et al. Using gridded multimedia model to simulate spatial fate of Benzo[α]pyrene on regional scale [J]. Environment international, 2014,63:53-63.
|
| [18] |
张 珏,孟 凡,何友江,等.长江三角洲地区大气二噁英类污染物输送—沉降模拟研究 [J]. 环境科学研究, 2011,24(12): 1393-1402.
|
| [19] |
Carter W P L. Documentation of the SAPRC-99chemical mechanism for VOC reactivity assessment [J]. Contract, 2000, 92(329):95-308.
|
| [20] |
Jiménez P, Parra R, Baldasano J M. Influence of initial and boundary conditions for ozone modeling in very complex terrains: A case study in the northeastern Iberian Peninsula [J]. Environmental Modelling & Software, 2007,22(9):1294-1306.
|
| [21] |
Shen H, Huang Y, Wang R, et al. Global atmospheric emissions of polycyclic aromatic hydrocarbons from 1960 to 2008 and future predictions [J]. Environmental Science & Technology, 2013, 47(12):6415-6424.
|
| [22] |
Halsall C J. Investigating the occurrence of persistent organic pollutants (POPs) in the arctic: Their atmospheric behaviour and interaction with the seasonal snow pack [J]. Environmental Pollution, 2004,128(1):163-175.
|
| [23] |
Baek S O, Goldstone M E, Kirk P W W, et al. Phase distribution and particle size dependency of polycyclic aromatic hydrocarbons in the urban atmosphere [J]. Chemosphere, 1991,22(5):503-520.
|
| [24] |
毕新慧,盛国英,谭吉华,等.多环芳烃(PAHs)在大气中的相分布 [J]. 环境科学学报, 2004,24(1):101-106.
|
| [25] |
Yamasaki H, Kuwata K, Miyamoto H. Effects of ambient temperature on aspects of airborne polycyclic aromatic hydrocarbons [J]. Environmental Science & Technology, 1982, 16(4):189-194.
|
| [26] |
Odum H T. Ecological and general systems: an introduction to systems ecology [M]. University Press of Colorado, 1994.
|
| [27] |
Pankow J F. An absorption model of gas/particle partitioning of organic compounds in the atmosphere [J]. Atmospheric Environment, 1994a,28(2):185-188.
|
| [28] |
Junge C E. Basic considerations about trace constituents in the atmosphere as related to the fate of global pollutants [J]. Advances in Environmental Science and Technology 8 (Pt. 1), 1977:7-25.
|
| [29] |
Pankow J F. Review and comparative analysis of the theories on partitioning between the gas and aerosol particulate phases in the atmosphere [J]. Atmospheric Environment (1967), 1987,21(11): 2275-2283.
|
| [30] |
Finizio A, Mackay D, Bidleman T, et al. Octanol-air partition coefficient as a predictor of partitioning of semi-volatile organic chemicals to aerosols [J]. Atmospheric Environment, 1997,31(15): 2289-2296.
|
| [31] |
Harner T, Bidleman T F. Measurements of octanol-air partition coefficients for polychlorinated biphenyls [J]. Journal of Chemical & Engineering Data, 1996,41(4):895-899.
|
| [32] |
Harner T, Bidleman T F. Octanol-air partition coefficient for describing particle/gas partitioning of aromatic compounds in urban air [J]. Environmental Science & Technology, 1998,32(10): 1494-1502.
|
| [33] |
Odabasi M, Cetin E, Sofuoglu A. Determination of octanol-air partition coefficients and supercooled liquid vapor pressures of PAHs as a function of temperature: application to gas-particle partitioning in an urban atmosphere [J]. Atmospheric Environment, 2006,40(34):6615-6625.
|
| [34] |
The Staffs of the California Air Resources Board and the Office of Environmental Health Hazard-Assessment. Benzo[a]pyrene as a toxic air contaminant [R]. The California Air Resources Board and the Environmental Health Hazard-Assessment, 1994,(4): 39650-39662.
|
| [35] |
Elena Mantseva, Alexander Malanichev, Nadezhda Vulykh. Poly aromatic hydrocarbons in the environment [R]. MSC-E Technical Note 9/2002.
|
| [36] |
Keyte I J, Harrison R M, Lammel G. Chemical reactivity and long-range transport potential of polycyclic aromatic hydrocarbons-a review [J]. Chemical Society Reviews, 2013, 42(24):9333-9391.
|
| [37] |
Bewersdorff I, Aulinger A, Matthias V, et al. The effect of temporal resolution of PAH emission data on transport and deposition patterns simulated with the Community Multiscale Air Quality modelling system (CMAQ) [J]. Meteorologische Zeitschrift, 2009,18(1):41-53.
|
| [38] |
Berdowski J J M, Baas J, Bloos J P J, et al. The European emission inventory of heavy metals and persistent organic pollutants. Umweltforschungsplan des Bundesministers fur Umwelt, naturschutz und Reaktorsicherheit. Forschungsbericht 104 02 672/03, 1997.
|
| [39] |
Aulinger A, Matthias V, Quante M. Introducing a partitioning mechanism for PAHs into the community multiscale air quality modeling system and its application to simulating the transport of benzo (a) pyrene over Europe [J]. Journal of Applied Meteorology and Climatology, 2007,46(11):1718-1730.
|
|
|
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