某市再生水灌区水土环境中PPCPs污染特征分析

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Abstract

In order to preliminarily understand the distribution characteristics of pharmaceuticals and personal care products (PPCPs) in soil environment, and then identify the main source of PPCPs in groundwater in the farming area of southeast suburban of a city,drilled profiles in irrigation area, reclaimed water irrigation area, and wetland were investigated in detail. In each profile, samples of surface water, groundwater and soil samples from different depths were collected. The routine indexes and 15target PPCPs of all samples were analyzed. The analytical results indicated that there was an obvious difference in concentration levels of PPCPs in different areas. Generally, the concentrations of PPCPs in the soil profiles in reclaimed water irrigation area were the highest, and those in the wet lands were the lowest. The average total concentration of soil PPCPs was 15.6μg/kg. The detected PPCPs mainly includecarbamazepine, bezafibrate, gemifibrozil, chloramghenicol and indometacin. In the irrigation area, the average total concentrations of PPCPs in surface water and in groundwater were 272.5ng/L and 63.5ng/L, respectively. In surface water, there was a trend that the concentration of PPCPs decreased downwards. By using themixing Multi-cell principle and concept of Push flow, vertical transport process of PPCPs from soil surface to ground water was depicted. The calculated results of 9selected PPCPs (not includingcarbamazepine, mefenamicacidand nalidixic acid) in groundwateraccorded well with the measured values. This preliminarily indicated that the reclaimed water is the main source of PPCPs in groundwater in the irrigation area.

Key words： pharmaceuticals and personal care products (PPCPs) reclaimed irrigationarea reduction factor source identification

Received: 12 January 2016

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	Articles by authors
	HUANG De-liang
	HE Jiang-tao
	YANG Lei
	HE Bao-nan

Cite this article:

HUANG De-liang,HE Jiang-tao,YANG Lei等. Distribution characteristics of pharmaceuticals and personal care products in water and soil environment in reclaimed water irrigation area of a city[J]. CHINA ENVIRONMENTAL SCIENCECE, 2016, 36(9): 2614-2623.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2016/V36/I9/2614

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[12]	Jurado A, Lopez-Serna R, Vazquez-Sune E, et al. Occurrence of carbamazepine and five metabolites in an urban aquifer[J]. Chemosphere, 2014,115:47-53.
[13]	王丹,隋倩,吕树光,等.黄浦江流域典型药物和个人护理品的含量及分布特征[J]. 中国环境科学, 2014,34(7):1897-904.
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[15]	Seiler R L, Zaugg S D, Thomas J M, et al. Caffeine and pharmaceuticals as indicators of waste water contamination in wells[J]. Ground Water, 1999,37(3):405-10.
[16]	Del Rosario K L, Mitra S, Humphrey C P, et al. Detection of pharmaceuticals and other personal care products in groundwater beneath and adjacent to onsite wastewater treatment systems in a coastal plain shallow aquifer[J]. Science of the Total Environment, 2014,487:216-23.
[17]	Fram M S, Belitz K. Occurrence and concentrations of pharmaceutical compounds in groundwater used for public drinking-water supply in California[J]. The Science of the Total Environment, 2011,409(18):3409-17.
[18]	Loos R, Locoro G, Comero S, et al. Pan-European survey on the occurrence of selected polar organic persistent pollutants in ground water[J]. Water Research, 2010,44(14):4115-26.
[19]	Wiegel S, Aulinger A, Brockmeyer R, et al. Pharmaceuticals in the river Elbe and its tributaries[J]. Chemosphere, 2004,57(2):107-26.
[20]	Kim S D, Cho J, Kim I S, et al. Occurrence and removal of pharmaceuticals and endocrine disruptors in South Korean surface, drinking, and waste waters[J]. Water Research, 2007, 41(5):1013-21.
[21]	Teijon G, Candela L, Tamoh K, et al. Occurrence of emerging contaminants, priority substances (2008/105/CE) and heavy metals in treated wastewater and groundwater at Depurbaix facility (Barcelona, Spain)[J]. The Science of the Total Environment, 2010.
[22]	周海东,王奉飞,李涵.PhACs在城市污水中迁移机理的研究[J]. 水资源与水工程学报, 2011(2):87-90.
[23]	Clara M, Strenn B, Kreuzinger N. Carbamazepine as a possible anthropogenic marker in the aquatic environment: investigations on the behaviour of Carbamazepine in wastewater treatment and during groundwater infiltration[J]. Water Research, 2004,38(4): 947-54.
[24]	Pan M, Chu L M. Adsorption and degradation of five selected antibiotics in agricultural soil[J]. Science of the Total Environment, 2016,545/546:48-56.
[25]	Corada-Fernández C, Jiménez-Martínez J, Candela L, et al. Occurrence and spatial distribution of emerging contaminants in the unsaturated zone. Case study: Guadalete River basin (Cadiz, Spain)[J]. Chemosphere, 2015,119:S131-S7.
[26]	Karickhoff S W, Brown D S, Scott T A. Sorption of hydrophobic pollutants on natural sediments[J]. Water Research, 1979,13(3): 241-8.
[27]	Huntscha S, Rodriguez Velosa D M, Schroth M H, et al. Degradation of polar organic micropollutants during riverbank filtration: complementary results from spatiotemporal sampling and push-pull tests[J]. Environ. Sci. Technol., 2013,47(20): 11512-21.
[28]	Jurado A, Vàzquez-Suñé E, Carrera J, et al. Emerging organic contaminants in groundwater in Spain: A review of sources, recent occurrence and fate in a European context[J]. Science of the Total Environment, 2012,440:82-94.