|
|
Emission characteristics and chemical reactivity of volatile organic compounds from light-duty gasoline vehicles |
YAO Sen, WEI Wei, CHENG Shui-yuan, WANG Gang, ZHANG Hang-yu, CHEN Guo-lei |
Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing 100124, China |
|
|
Abstract The VOCs samples emitted from light-duty gasoline vehicles ranging from China II to China IV was collected by portableemission measurement system (PEMS). Alkanes, alkenes and aromatics in the exhaust were analyzed using GC-MS and GC-FID. Results demonstrated that the emission reductions of VOCs from light-duty gasoline vehicles had been achieved as the control technology become more rigorous, China II, China III and China IV vehicles were 49.62, 21.65 and 6.72mg/km, respectively. Aromatics were the dominant VOCs with weight percentages of 47.43%~60.52%. The ozone formation potentials and SOA formation potential for different emission standards were 24.64 ~ 234.14mg/km and 13.24 ~125.32mg/km. Driving speeds also influenced the VOCs emissions from the tested China III vehicles, the VOCs emission factors, ozone formation potential (OFP) and SOA formation potential from light-duty gasoline vehicles were dropped with the increase of the speed.
|
Received: 24 February 2016
|
|
|
|
|
[1] |
Sartelet K N, Couvidat F, Seigneur C, et al. Impact of biogenic emissions on air quality over Europe and North America [J]. Atmospheric Environment, 2012,53(SI):131-141.
|
[2] |
Huang Y, Ho S S H, Ho K F, et al. Characteristics and health impacts of VOCs and carbonyls associated with residential cooking activities in Hong Kong [J]. Journalof Hazardous Materials, 2011,186(1):344-351.
|
[3] |
Toro M V, Cremades L V, Calbo J. Relationship between VOC and NOx emissions and chemical production of tropospheric ozone in the Aburra Valley/(Colombia) [J]. Chemosphere, 2006, 65(5):881-888.
|
[4] |
Derwent R G, Jenkin M E, Utembe S R, et al. Secondary organic aerosol formation from a large number of reactive man-made organic compounds [J]. Scienceof The Total Environment, 2010,408(16):3374-3381.
|
[5] |
王扶潘,朱乔,冯凝,等.深圳大气中VOCs的二次有机气溶胶生成潜势 [J]. 中国环境科学, 2014,34(10):2449-2457.
|
[6] |
Zheng J, Shao M, Che W, et al. Speciated VOC Emission Inventory and Spatial Patterns of Ozone Formation Potential in the Pearl River Delta, China [J]. Environmental Science& Technology, 2009,43(22):8580-8586.
|
[7] |
Huang C, Chen C H, Li L, et al. Emission inventory of anthropogenic air pollutants and VOC species in the Yangtze River Delta region, China [J]. Atmospheric Chemistryand Physics, 2011,11(9):4105-4120.
|
[8] |
区家敏,冯小琼,刘郁葱,等.珠江三角洲机动车挥发性有机物排放化学成分谱研究 [J]. 环境科学学报, 2014,34(4):826-834.
|
[9] |
Wang J, Jin L, Gao J, et al. Investigation of speciated VOC in gasoline vehicular exhaust under ECE and EUDC test cycles [J]. Scienceof The Total Environment, 2013,445:110-116.
|
[10] |
于艳,王秀艳,杨文.天津市机动车二次有机气溶胶生成潜势的估算 [J]. 中国环境科学, 2015,35(2):381-386.
|
[11] |
Huang C, Lou D, Hu Z, et al. A PEMS study of the emissions of gaseous pollutants and ultrafine particles from gasoline- and diesel-fueled vehicles [J]. Atmospheric Environment, 2013,77: 703-710.
|
[12] |
Yao Z, Wu B, Shen X, et al. On-road emission characteristics of VOCs from rural vehicles and their ozone formation potential in Beijing, China [J]. Atmospheric Environment, 2015,105:91-96.
|
[13] |
Huo H, Yao Z, Zhang Y, et al. On-board measurements of emissions from light-duty gasoline vehicles in three mega-cities of China [J]. Atmospheric Environment, 2012,49:371-377.
|
[14] |
Yao Z, Shen X, Ye Y, et al. On-road emission characteristics of VOCs from diesel trucks in Beijing, China [J]. Atmospheric Environment, 2015,103:87-93.
|
[15] |
史纯珍,张明辉,姚志良.机动车尾气排放羰基化合物研究进展 [J]. 环境科学与技术, 2014,(S2):266-272.
|
[16] |
Cao X, Yao Z, Shen X, et al. On-road emission characteristics of VOCs from light-duty gasoline vehicles in Beijing, China [J]. Atmospheric Environment, 2016,124:146-155.
|
[17] |
傅晓钦,翁燕波,钱飞中,等.行驶机动车尾气排放vocs成分谱及苯系物排放特征 [J]. 环境科学学报, 2008,28(6):1056-1062.
|
[18] |
Carter W. Development of ozone reactivity scales for volatile organic-compounds [J]. Journal OF The Air &Waste Management Association, 1994,44(7):881-899.
|
[19] |
Grosjean D. Insitu organic aerosol formation during a smog episode - estimated production and chemical functionality [J]. Atmospheric Environment Part A-General Topics, 1992,26(6):953-963.
|
[20] |
Grosjean D, Seinfeld J H. Parameterization of the formation potential of secondary organic aerosols [J]. Atmospheric Environment, 1989,23(8):1733-1747.
|
[21] |
Platt S M, El Haddad I, Zardini A A, et al. Secondary organic aerosol formation from gasoline vehicle emissions in a new mobile environmental reaction chamber [J]. Atmospheric Chemistry and Physics, 2013,13(18):9141-9158.
|
[22] |
Chirico R, Decarlo P F, Heringa M F, et al. Impact of aftertreatment devices on primary emissions and secondary organic aerosol formation potential from in-use diesel vehicles: results from smog chamber experiments [J]. Atmospheric Chemistryand Physics, 2010,10(23):11545-11563.
|
[23] |
吕子峰,郝吉明,段菁春,等.北京市夏季二次有机气溶胶生成潜势的估算 [J]. 环境科学, 2009,30(4):969-975.
|
[24] |
郑玫,闫才青,李小滢,等.二次有机气溶胶估算方法研究进展 [J]. 中国环境科学, 2014,34(3):555-564.
|
[25] |
Plaza J, Gomez-Moreno F J, Nunez L, et al. Estimation of secondary organic aerosol formation from semicontinuous OC-EC measurements in a Madrid suburban area [J]. Atmospheric Environment, 2006,40(6):1134-1147.
|
[26] |
Nordin E Z, Eriksson A C, Roldin P, et al. Secondary organic aerosol formation from idling gasoline passenger vehicle emissions investigated in a smog chamber [J]. Atmospheric Chemistry and Physics, 2013,13(12):6101-6116.
|
|
|
|