对硝基苯酚和重金属在高炉水淬渣上的竞争吸附研究

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Abstract

Single component and competitive adsorption of p-nitrophenol (p-NP) and heavy metals on water-quenched blast furnace slag (WBFS) were investigated in this study. The adsorption isotherms, kinetics and thermodynamics were studied to explore adsorption characteristics and mechanisms. The results showed that heavy metals played a dominant role in controlling the competitive adsorption with p-NP in a sequence of Cu²⁺ > Cd²⁺ > Zn²⁺. The equilibrium data for adsorption of p-NP by WBFS could be well described by Freundlich isotherm model, while Langmuir isotherm could better fit the data for the adsorption of heavy metal ions on WBFS. The adsorption energy of p-NP calculated by D-R model in each system was -7.53, -7.07, -7.96 and -7.86kJ/mol, respectively. The results showed that WBFS adsorbed p-NP via physical adsorption, while adsorbed metal ions via chemical adsorption and ion exchange. The kinetic results demonstrated that the adsorption rate of p-NP decreased in the presence of heavy metal ions. And the corresponding time to reach adsorption equilibrium was prolonged. However, the patterns for the adsorption of heavy metal ions were not significantly influenced in the presence of p-NP. In the binary system, WBFS exhibited relative higher affinity and selectivity for Cu²⁺, Cd²⁺ and Zn²⁺ than p-NP. The adsorption data of p-NP and heavy metal ions were fitted well by the pseudo-second-order model in both single and binary systems. The values of △G decreased with increasing temperature, indicating the spontaneous nature for the adsorption of p-NP and Cu²⁺、Cd²⁺、Zn²⁺ was proportional to the temperature.The thermodynamics results also indicated the adsorption were an endothermic and entropy-increasing process.

Key words： Water-quenched blast furnace slag p-nitrophenol heavy metals isotherms thermodynamics kinetics competitive adsorption

Received: 18 March 2016

PACS:

X753

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	WANG Zhe
	XU Yi
	HUANG Guo-he
	AN Chun-jiang
	CHEN Li-rong
	ZHANG Si-si

Cite this article:

WANG Zhe,XU Yi,HUANG Guo-he等. Competitive adsorption of p-nitrophenol and heavy metals on water-quenched blast furnace slag[J]. CHINA ENVIRONMENTAL SCIENCECE, 2016, 36(12): 3686-3695.

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http://manu36.magtech.com.cn/Jweb_zghjkx/EN/ OR http://manu36.magtech.com.cn/Jweb_zghjkx/EN/Y2016/V36/I12/3686

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[2]	Yang P, Xu A D, Xia J, et al. Facile synthesis of highly catalytic activity Ni-Co-Pd-P composite for reduction of the p-nitrophenol[J]. Applied catalysis a-general, 2014,470:89-96.
[3]	岳钦艳,杨晶,高宝玉,等.活性炭纤维对水中酚类化合物的吸附特性[J]. 环境科学, 2008,29(10):2862-2867.
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[7]	Bhatnagar A, Kaczala F, Hogland W, et al. Valorization of solid waste products from olive oil industry as potential adsorbents for water pollution control-a review[J]. Environmental Science & Pollution Research, 2014,21(1):268-298.
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[12]	胡克伟,贾冬艳,颜丽,等.膨润土对重金属离子的竞争性吸附研究[J]. 土壤通报, 2011,42(2):467-470.
[13]	Park J H, Yong S O, Kim S H, et al. Competitive adsorption of heavy metals onto sesame straw biochar in aqueous solutions[J]. Chemosphere, 2016,142:77-83.
[14]	Yang J X, Wei W, Pi S S, et al. Competitive adsorption of heavy metals by extracellular polymeric substances extracted from Klebsiella sp. J1[J]. Bioresource Technology, 2015,196:533-539.
[15]	Andini S, Montagnaro F, Santoro L, et al. Mechanochemical processing of blast furnace slag for its reuse as adsorbent[J]. Chemical Engineering Transactions, 2013,32:2299-2304.
[16]	Xue Y J, Wu S P, Zhou M. Adsorption characterization of Cu (Ⅱ) from aqueous solution onto basic oxygen furnace slag[J]. Chemical Engineering Journal, 2013,231:355-364.
[17]	Boparai H K, Joseph M, O'Carroll D M. Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles[J]. Journal of Hazardous Materials, 2011,186(1):458-465.
[18]	Cai P, Zheng H, Wang C, et al. Competitive adsorption characteristics of fluoride and phosphate on calcined Mg-Al-CO3 layered double hydroxides[J]. Journal of Hazardous Materials, 2012,213:100-108.
[19]	Zhang H, Zhao D, Chen L, Yu X J. Investigation of Cu (Ⅱ) adsorption from aqueous solutions by NKF-6 zeolite[J]. Water Science and Technology, 2011,63:395-402.
[20]	Sljivic M, Smiciklas I, Pejanovic S, et al. Comparative study of Cu2+ adsorption on a zeolite, a clay and a diatomite from Serbia[J]. Applied Clay Science, 2009,43:33-40.
[21]	Mishra P C, Patel R K. Removal of lead and zinc ions from water by low cost adsorbents[J]. Journal of Hazardous Materials, 2009,168:319-325.
[22]	Ghaedia M, Mosallanejad N. Study of competitive adsorption of malachite green and sunset yellow dyes on cadmium hydroxide nanowires loaded on activated carbon[J]. Journal of Industrial and Engineering Chemistry, 2014,20:1085-1096.
[23]	Wang Y, Tang X W, Chen Y M, et al. Adsorption behavior and mechanism of Cd(Ⅱ) on loess soil from China[J]. Journal of Hazardous Materials, 2009,172:30-37.
[24]	刘盛余,马少健,高谨,等.钢渣吸附剂吸附机理的研究[J]. 环境工程学报, 2008,2(1):115-119.
[25]	Wang X H, Liu F F, Lu L, et al. Individual and competitive adsorption of Cr(VI) and phosphate onto synthetic Fe-Al hydroxides[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2013,423:42-49.
[26]	吴光前,张鑫,惠慧,等.氧等离子体改性竹活性炭对苯胺的吸附特性[J]. 中国环境科学, 2012,32(7):1188-1195.
[27]	孙小莉,曾庆轩,冯长根.多胺型阴离子交换纤维吸附铬(Ⅵ)的动力学[J]. 物理化学学报, 2009,25(10):1951-1957.
[28]	张忠.多孔纳米金属氧化物与镍铝水滑石的制备及吸附性能研究[M]. 武汉:武汉理工大学, 2013.
[29]	Shi L, Wei D, Ngo H H, et al. Application of anaerobic granular sludge for competitive biosorption of methylene blue and Pb(Ⅱ):Fluorescence and response surface methodology[J]. Bioresource Technology, 2015,194:297-304.
[30]	周岩梅,张琼,刁晓华,等.硝基苯和西维因在活性炭上的吸附效果及动力学研究[J]. 中国环境科学, 2010,30(9):1177-1182.
[31]	Wang S B, Ariyanto E. Competitive adsorption of malachite green and Pb ions on natural zeolite[J]. Journal of Colloid and Interface Science, 2007,314:25-31.
[32]	张婧怡,袁宏林,石宝友,等.活性炭对天然水体中甲基对硫磷和三氯乙烯的吸附特性研究[J]. 环境科学学报, 2010,30(9):1778-1786.
[33]	Abdus-Salam N, Bello M O. Kinetics, thermodynamics and competitive adsorption of lead and zinc ions onto termite mound[J]. International Journal of Environmental Science, 2015,12(11):1-10.
[34]	Depci T, Kul A R, Onal Y. Competitive adsorption of lead and zinc from aqueous solution on activated carbon prepared from Van pulp:study in single- and multi- solute systems[J]. Chemical Engineering Journal, 2012,200:224-236.
[1]	Körbahti B K, Artut K, Geçgel C, et al. Electrochemical decolorization of textile dyes and removal of metal ions from textile dye and metal ion binary mixtures[J]. Chemical Engineering Journal, 2011,173(3):677-688.
[2]	Yang P, Xu A D, Xia J, et al. Facile synthesis of highly catalytic activity Ni-Co-Pd-P composite for reduction of the p-nitrophenol[J]. Applied catalysis a-general, 2014,470:89-96.
[3]	岳钦艳,杨晶,高宝玉,等.活性炭纤维对水中酚类化合物的吸附特性[J]. 环境科学, 2008,29(10):2862-2867.
[4]	Mohan D, Singh K P. Single- and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse-an agricultural waste[J]. Water Research, 2002,36:2304-2318.
[5]	Futalan C M, Kan C C, Dalida M L, et al. Comparative and competitive adsorption of copper, lead, and nickel using chitosan immobilized on bentonite[J]. Carbohydrate Polymers, 2011,83(2):528-536.
[6]	Mishra P C, Patel R K. Removal of lead and zinc ions from water by low cost adsorbents[J]. Journal of Hazardous Materials, 2009,168:319-325.
[7]	Bhatnagar A, Kaczala F, Hogland W, et al. Valorization of solid waste products from olive oil industry as potential adsorbents for water pollution control-a review[J]. Environmental Science & Pollution Research, 2014,21(1):268-298.
[8]	Yagub M T, Sen T K, Afroze S, et al. Dye and its removal from aqueous solution by adsorption:A review[J]. Advances in Colloid & Interface Science, 2014,209(7):172-184.
[9]	Andini S, Cioffi R, Colangelo F, et al. Effect of mechanochemical processing on adsorptive properties of blast furnace slag[J]. Journal of Environmental Engineering, 2013,139(12):1446-1453.
[10]	Oguz E. Thermodynamic and kinetic investigations of PO43- adsorption on blast furnace slag[J]. Journal of Colloid and Interface Science, 2005,281:62-67.
[11]	Nehrenheim E, Gustafsson J P. Kinetic sorption modeling of Cu, Ni, Zn, Pb and Cr ions to pine bark and blast furnace slag by using batch experiments[J]. Bioresource Technology, 2008,99:1571-1577.
[12]	胡克伟,贾冬艳,颜丽,等.膨润土对重金属离子的竞争性吸附研究[J]. 土壤通报, 2011,42(2):467-470.
[13]	Park J H, Yong S O, Kim S H, et al. Competitive adsorption of heavy metals onto sesame straw biochar in aqueous solutions[J]. Chemosphere, 2016,142:77-83.
[14]	Yang J X, Wei W, Pi S S, et al. Competitive adsorption of heavy metals by extracellular polymeric substances extracted from Klebsiella sp. J1[J]. Bioresource Technology, 2015,196:533-539.
[15]	Andini S, Montagnaro F, Santoro L, et al. Mechanochemical processing of blast furnace slag for its reuse as adsorbent[J]. Chemical Engineering Transactions, 2013,32:2299-2304.
[16]	Xue Y J, Wu S P, Zhou M. Adsorption characterization of Cu (Ⅱ) from aqueous solution onto basic oxygen furnace slag[J]. Chemical Engineering Journal, 2013,231:355-364.
[17]	Boparai H K, Joseph M, O'Carroll D M. Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles[J]. Journal of Hazardous Materials, 2011,186(1):458-465.
[18]	Cai P, Zheng H, Wang C, et al. Competitive adsorption characteristics of fluoride and phosphate on calcined Mg-Al-CO3 layered double hydroxides[J]. Journal of Hazardous Materials, 2012,213:100-108.
[19]	Zhang H, Zhao D, Chen L, Yu X J. Investigation of Cu (Ⅱ) adsorption from aqueous solutions by NKF-6 zeolite[J]. Water Science and Technology, 2011,63:395-402.
[20]	Sljivic M, Smiciklas I, Pejanovic S, et al. Comparative study of Cu2+ adsorption on a zeolite, a clay and a diatomite from Serbia[J]. Applied Clay Science, 2009,43:33-40.
[21]	Mishra P C, Patel R K. Removal of lead and zinc ions from water by low cost adsorbents[J]. Journal of Hazardous Materials, 2009,168:319-325.
[22]	Ghaedia M, Mosallanejad N. Study of competitive adsorption of malachite green and sunset yellow dyes on cadmium hydroxide nanowires loaded on activated carbon[J]. Journal of Industrial and Engineering Chemistry, 2014,20:1085-1096.
[23]	Wang Y, Tang X W, Chen Y M, et al. Adsorption behavior and mechanism of Cd(Ⅱ) on loess soil from China[J]. Journal of Hazardous Materials, 2009,172:30-37.
[24]	刘盛余,马少健,高谨,等.钢渣吸附剂吸附机理的研究[J]. 环境工程学报, 2008,2(1):115-119.
[25]	Wang X H, Liu F F, Lu L, et al. Individual and competitive adsorption of Cr(VI) and phosphate onto synthetic Fe-Al hydroxides[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2013,423:42-49.
[26]	吴光前,张鑫,惠慧,等.氧等离子体改性竹活性炭对苯胺的吸附特性[J]. 中国环境科学, 2012,32(7):1188-1195.
[27]	孙小莉,曾庆轩,冯长根.多胺型阴离子交换纤维吸附铬(Ⅵ)的动力学[J]. 物理化学学报, 2009,25(10):1951-1957.
[28]	张忠.多孔纳米金属氧化物与镍铝水滑石的制备及吸附性能研究[M]. 武汉:武汉理工大学, 2013.
[29]	Shi L, Wei D, Ngo H H, et al. Application of anaerobic granular sludge for competitive biosorption of methylene blue and Pb(Ⅱ):Fluorescence and response surface methodology[J]. Bioresource Technology, 2015,194:297-304.
[30]	周岩梅,张琼,刁晓华,等.硝基苯和西维因在活性炭上的吸附效果及动力学研究[J]. 中国环境科学, 2010,30(9):1177-1182.
[31]	Wang S B, Ariyanto E. Competitive adsorption of malachite green and Pb ions on natural zeolite[J]. Journal of Colloid and Interface Science, 2007,314:25-31.
[32]	张婧怡,袁宏林,石宝友,等.活性炭对天然水体中甲基对硫磷和三氯乙烯的吸附特性研究[J]. 环境科学学报, 2010,30(9):1778-1786.
[33]	Abdus-Salam N, Bello M O. Kinetics, thermodynamics and competitive adsorption of lead and zinc ions onto termite mound[J]. International Journal of Environmental Science, 2015,12(11):1-10.
[34]	Depci T, Kul A R, Onal Y. Competitive adsorption of lead and zinc from aqueous solution on activated carbon prepared from Van pulp:study in single- and multi- solute systems[J]. Chemical Engineering Journal, 2012,200:224-236.