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Pollution status and health risks of drinking water of the polycyclic aromatic hydrocarbons and phthalate esters in the deep shallow pore water of Hutuo River Pluvial Fan |
GENG Meng-jiao1, CHANG Sheng1, LIU Yan1, WANG Shan-jun1, HAN Xiang-yun1,2 |
1. State Environmental Protection Key Laboratory of Drinking Water Source Protection, Chinese Research Academy of Environmental Sciences, Beijing 100012, China; 2. College of Chemistry and Material Science, Hebei Normal University, Shijiazhang 050024, China |
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Abstract In order to investigate the pollution status of polycyclic aromatic hydrocarbons (PAHs) and phthalate esters (PAEs) in the deep shallow pore water of Hutuo River Pluvial Fan, the US EPA priority control PAHs and PAEs in the groundwater of this region were analyzed by gas chromatography-mass spectrometry. The occurrence, distribution characteristics and their potential probabilistic carcinogenic risk through drinking water were also assessed in this present study. The results showed that both PAHs and PAEs could be detected in all the 7deep shallow pore water samples. The concentration of the ∑PAHs was ranged from 34.4 to 598.5ng/L. The percent of the 2~3ring PAHs was accounted about 50%~83%, which indicated that the 2~3ring PAHs was predominated. While the concentration of the ∑PAEs was ranged from 27.6 to 25236.7ng/L and there were three samples that the concentration were reached 20μg/L, and in addition, the DBP and DEHP were the dominant constitutes. As compared to other surveyed groundwater research regions in China, the PAHs pollution level of this research area was closed to the others, however, the PAEs pollution level of this research area was higher than the others. The health risk of drinking groundwater in the study area was evaluated by the recommended method by US EPA. It showed that the cancer risk of PAHs of all the samples were excessed acceptable level (10-6) except G2 sample point. Besides, the cancer risk of G1, G6 and G7 sample were larger than 10-6 for the health risk assessment of PAEs. The results of this study suggested that the quality of groundwater in this research region should be pay enough attention by government.
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Received: 22 April 2016
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[1] |
赵红梅,赵华,毛洪亮,等.华北平原滹沱河冲洪积扇第四纪地层划分[J].地层学杂志,2014,38(2):137-146.
|
[2] |
李亚松,张兆吉,费宇红,等.河北省滹沱河冲积平原地下水质量及污染特征研究[J].地球学报,2014,35(2):169-176.
|
[3] |
费宇红,张兆吉,杨梅,等.滹沱河平原地下水有机污染健康风险评价[J].上海地质,2010,2:13-19.
|
[4] |
李亚松,张兆吉,费宇红,等.滹沱河冲积平原浅层地下水有机污染研究[J].干旱区资源与环境,2012,26(8):52-56.
|
[5] |
Countway R E,Dickhut R M,Canuel E A,et al.Polycyclic aromatic hydrocarbon (PAH) distributions and associations with organic matter in surface waters of the York River,VA Estuary[J].Organic Geochemistry,2003,34(2):209-224.
|
[6] |
Krupadam R J,Khan M S,Wate S R.Removal of probable human carcinogenic polycyclic aromatic hydrocarbons from contaminated water using molecularly imprinted polymer[J].Water Research,2010,44(3):681-688.
|
[7] |
Baek S O,Field R A,Goldstone M E,et al.A review of atmospheric polycyclic aromatic hydrocarbons:sources,fate and behavior[J].Water Air&Soil Pollution,1991,60(3/4):279-300.
|
[8] |
Liu H,Cui K,Zeng F,et al.Occurrence and distribution of phthalate esters in riverine sediments from the Pearl River Delta region,South China[J].Marine Pollution Bulletin,2014,83(1):358-365.
|
[9] |
Guo X,Wang L,Wang X,et al.Occurrence and environmental risk assessment of PAEs in Weihe River near Xi'an City,China[J].Water Science&Technology,2013,67(5):948-959.
|
[10] |
Adams W J,Biddinger G R,Robillard K A,et al.A summary of the acute toxicity of 14phthalate esters to representative aquatic organisms[J].Environ.Toxicol.Chem.,1995,14(9):1569-1574.
|
[11] |
代俊宁.滹沱河冲洪积扇地下水回灌研究[D].北京:中国地质大学(北京),2014,6
|
[12] |
许宜平,张铁山,黄圣彪,等.某自来水厂水源多环芳烃污染分析[J].安全与环境学报,2004,4(6):14-17.
|
[13] |
Liu X,Shi J,Bo T,et al.Occurrence of phthalic acid esters in source waters:a nationwide survey in China during the period of 2009-2012[J].Environmental Pollution,2013,184(8):262-270.
|
[14] |
邵一先.郭庄泉岩溶水系统中多环芳烃的分布与归趋研究[D].武汉:中国地质大学(武汉),2014,5.
|
[15] |
孙玉川.有机氯农药和多环芳烃在表层岩溶系统中的迁移转化特征研究[D].成都:西南大学,2012,4.
|
[16] |
龚香宜,何炎志,孙云雷.江汉平原四湖流域上区地下水中多环芳烃分布特征与源解析[J].环境科学学报,2015,35(3):789-796.
|
[17] |
罗庆,孙丽娜,张耀华.细河流域地下水中多环芳烃污染健康风险评价[J].农业环境科学学报,2011,30(5):959-964.
|
[18] |
张英,孙继朝,陈玺,等.东莞地下水邻苯二甲酸酯分布特征及来源探讨[J].环境污染与防治,2011,33(8):57-61.
|
[19] |
蒋丽佳,许秋瑾,梁存珍,等.江苏某县地下水邻苯二甲酸酯类的检测与风险评价[J].中国环境监测,2013,29(4):5-10.
|
[20] |
Ma W L,Liu L Y,Qi H,et al.Polycyclic aromatic hydrocarbons in water,sediment and soil of the Songhua River Basin,China[J].Environmental Monitoring and Assessment,2013,185(10):8399-8409.
|
[21] |
中华人民共和国中央政府.2010年国民体质监测公报[EB/OL].(2012-04-19)[2014-12-19].http://www.gov.cn/test/2012-04/19/content_2117320.htm.
|
[22] |
Nisbet C,Lagoy P.Toxic equivalency factors-for polycyclic aromatic hydrocarbons (PAHs)[J].Regulatory Toxicology and Pharmacology,1992,16(3):290-300.
|
[23] |
U S Environmental Protection Agency.The Risk Assessment Guidelines of 1986[M]//EPA/600/18-87/045.Washington DC:Office of Emergency and Remedial Response.U S EPA,1986.
|
[24] |
U S Environmental Protection Agency.Guidelines for exposure assessment[R].Washington DC:Risk Assessment Forum,1992:4-5.
|
[25] |
环境保护部.中国人群暴露参数手册(成人卷)[M].北京:中国环境出版社,2013,12.
|
[26] |
Sun J H,Wang G L,ChaiY,et al.Distribution of polycyclic aromatic hydrocarbons (PAHs) in Henan reach of the Yellow River,Middle China[J].Ecotoxicol.Environ.Safety,2009,72(5):1614-1624.
|
[27] |
US Environmental Protection Agency.Edition of the drinking water standards and health advisories[R].Washington DC:Office of Water US Environmental Protection Agency,2004:1-2.
|
|
|
|