二次有机气溶胶相态的研究现状与展望

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Abstract

This review presents an overview of the analytical techniques for detecting the phase state of secondary organic aerosol (SOA), the effects of phase state on mass transport, and the types of SOA being studied. The previous studies showed that SOA could be solid, semi-solid, or liquid. The bulk diffusion coefficients for solid and semi-solid can be much smaller than those for liquid SOA, and therefore lead to limited mass transfer of species and different formation and transformation of SOA compared to liquid systems. However, only several types of SOA precursors have been studied, such as α-pinene, isoprene, and toluene. The phase state of SOA in urban areas as well as the effects of coexisting inorganic species on their phase state is largely unknown. Our analysis shows that the phase state perhaps play an important role in the rapid increase of secondary particle mass concentration during heavily hazed events. Therefore, it is important to study the phase state of SOA and the absorption and transfer of the key active gases at the surface and in the bulk of aerosols in the polluted environments, which will help us to further understand the mechanisms of the formation and evolution of secondary particles in China.

Key words： secondary organic aerosol (SOA) phase state viscosity diffusion coefficients

Received: 21 September 2016

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X513

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	LIU Yue-chen
	WU Zhi-jun
	HU Min

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LIU Yue-chen,WU Zhi-jun,HU Min. Advances in the phase state of secondary organic aerosol[J]. CHINA ENVIRONMENTAL SCIENCECE, 2017, 37(5): 1637-1645.

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http://manu36.magtech.com.cn/Jweb_zghjkx/EN/ OR http://manu36.magtech.com.cn/Jweb_zghjkx/EN/Y2017/V37/I5/1637

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