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Preparation of photocatalytic composite ultrafiltration membrane and its properties under simulated solar irradiation |
YANG Chun-yan, WANG Qiao, ZHANG Guang-shan, WANG Peng |
State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China |
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Abstract The visible-light responsive photocatalytic composite ultrafiltration membranes were prepared by L-S phase inversion method, where polysulfone (PSF) was used as membrane material and the hydrophilic Fe-doped TiO2 nanoparticles were additive. In addition, surface morphology, surface functional groups, hydrophilicity, ultrafiltration performance, mechanical property, thermal stability and photocatalytic performance were separately analyzed to explore the influences of Fe-TiO2 on the composite membrane. The results showed that when the mass ratio of Fe-TiO2 and PSF was 0.20, the RhB removal rate of Fe-TiO2/PSF composite membrane (61%) was evidently higher than that of pure PSF membrane (33%). By adding photocatalyst, the composite membrane could possess response under simulated solar irradiation. Meanwhile, a certain amount of catalyst could improve the physical and chemical properties of PSF membrane, which broadens its application field.
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Received: 09 May 2017
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[1] |
Gao Y, Li B, Zhong L, et al. Effect of nano-amphiphilic cellulose as a modifier to PSf composite membranes[J]. Vacuum, 2014, 107:199-203.
|
[2] |
Tang Y, Xu J, Gao C. Ultrafiltration membranes with ultrafast water transport tuned via different substrates[J]. Chemical Engineering Journal, 2016,303:322-330
|
[3] |
Yang Y, Wang P. Preparation and characterizations of a new PS/TiO2 hybrid membranes by sol-gel process[J]. Polymer, 2006, 47(8):2683-2688.
|
[4] |
Jyothi M S, Nayak V, Padaki M, et al. The effect of UV irradiation on PSf/TiO2 mixed matrix membrane for chromium rejection[J]. Desalination, 2014,354:189-199.
|
[5] |
Yang Y, Zhang H, Wang P, et al. The influence of nano-sized TiO2 fillers on the morphologies and properties of PSF UF membrane[J]. Journal of Membrane Science, 2007,288(1/2):231-238.
|
[6] |
Fischer K, Grimm M, Meyers J, et al. Photoactive microfiltration membranes via directed synthesis of TiO2 nanoparticles on the polymer surface for removal of drugs from water[J]. Journal of Membrane Science, 2015,478:49-57.
|
[7] |
Leong S, Razmjou A, Wang K, et al. TiO2 based photocatalytic membranes:A review[J]. Journal of Membrane Science, 2014, 472:167-184.
|
[8] |
刘秀华.金属离子掺杂二氧化钛光催化剂的改性研究[D]. 绵阳:中国工程物理研究院, 2007.
|
[9] |
Dolat D, Mozia S, Ohtani B, et al. Nitrogen, iron-single modified (N-TiO2, Fe-TiO2) and co-modified (Fe, N-TiO2) rutile titanium dioxide as visible-light active photocatalysts[J]. Chemical Engineering Journal, 2013,225:358-364.
|
[10] |
Wang Q, Zhang G, Li Z, et al. Preparation and properties of polyamide/titania composite nanofiltration membrane by interfacial polymerization[J]. Desalination, 2014,352:38-44.
|
[11] |
杨亚楠,王鹏,郑庆柱.聚砜/纳米TiO2有机-无机复合超滤膜的制备与表征[J]. 高校化学工程学报, 2007,(5):766-772.
|
[12] |
胡春,王怡中,汤鸿霄.表面键联型TiO2/SiO2固定化催化剂的结构及催化性能[J]. 催化学报, 2001,(2):185-188.
|
[13] |
何杨.掺杂纳米ZnO改性PVDF超滤膜的制备及特性研究[D]. 厦门:华侨大学, 2013.
|
[14] |
田共有.红外、碳硫分析联用判别聚砜类材料[J]. 分析试验室, 2008,(S1):309-310.
|
[15] |
郑虹,介兴明,于海军,等.新型a-纤维素/聚砜共混超滤膜的制备与性能研究[J]. 膜科学与技术, 2015,(6):1-8.
|
[16] |
Kumar R, Isloor A. M, Ismail A. F, et al. Permeation, antifouling and desalination performance of TiO2 nanotube incorporated PSf/CS blend membranes[J]. Desalination, 2013,316:76-84.
|
[17] |
杨亚楠,张明耀,金晶,等.聚砜/纳米TiO2有机-无机复合超滤膜及其性能[J]. 化工进展, 2009,28(z1):145-148.
|
[18] |
Gao Y, Li B, Zhong L, et al. Effect of nano-amphiphilic cellulose as a modifier to PSf composite membranes[J]. Vacuum, 2014,107:199-203.
|
[19] |
刁静人.热重分析结果的影响因素分析[J]. 磁性材料及器件, 2012,(6):49-52.
|
[20] |
严秋玲,龚玉娇,殷先泽,等.季铵化聚砜/改性蒙脱土阴离子交换膜的制备与表征[J]. 高分子材料科学与工程, 2016,(4):168-172.
|
[21] |
王雪,徐佳,蒋钰烨,等.新型抑菌聚砜超滤膜的制备及性能[J]. 高等学校化学学报, 2012,(9):2129-2134.
|
[22] |
王明霞,姬宇,张玉忠,等.聚乙烯吡啶接枝聚砜膜的制备及pH敏感性能[J]. 高分子材料科学与工程, 2016,(3):64-69.
|
[23] |
Rajabi H R, Khani O, Shamsipur M, et al. High-performance pure and Fe3+-ion doped ZnS quantum dots as green nanophotocatalysts for the removal of malachite green under UV-light irradiation[J]. Journal of Hazardous Materials, 2013, 250-251:370-378.
|
[24] |
Mohamed M A, W Salleh W N, Jaafar J, et al. Physicochemical characteristic of regenerated cellulose/N-doped TiO2 nanocomposite membrane fabricated from recycled newspaper with photocatalytic activity under UV and visible light irradiation[J]. Chemical Engineering Journal, 2016,284:202-215.
|
|
|
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