多核yolk?shell型Co3O4@mSiO2纳米反应器降解双酚A

Abstract
Figure/Table
References
Related Citation (10)

Download: PDF (1219 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract In this study, a kind of multi yolk-shell Co₃O₄@mSiO₂ (mesoporous SiO₂) nanoreactor was synthesized. Cationic surfactant assisted self-template method was used to synthesize hollow mesoporous SiO₂ microspheres (HMSS). Then cobalt acetate and ammonia solution were introduced into the cavity through mesoporous to form Co₃O₄ core. XRD, XPS, SEM, STEM, BET analysis were combined to characterize the structure, element valences, specific surface area and morphology of the synthesized nanoreactor, which showed the nanoreactor was evenly dispersed with about 300nm particle diameter. The surface of the nanoreactor was full of mesoporous, and a large number of Co₃O₄ particles distributed in its hollow space. Large specific surface area of 161m²/g was demonstrated, which was apparently higher than Co₃O₄ nanoparticle with 35m²/g specific surface area. The adsorption capacity of BPA by multi yolk-shell Co₃O₄@mSiO₂ nanoreactor was 12.7mg/g within 1h. Peroxymonosulfate (PMS) was catalyzed to degrade 81.8% of BPA within 2h, which was apparently higher than Co₃O₄ nanoparticle with 51.3% degradation rate. Dosage of PMS was saved by using the nanoreactor, and it could avoid high salinity in water. Furthermore, the nanoreactor was well recyclable, as well as performed to be highly efficient and stable in the pH range of 3~9.

Key words： nanoreactor sulfate radical yolk-shell Co₃O₄ hollow mesoporous SiO₂ microspheres

Received: 03 November 2017

X505

Corresponding Authors: 陈晴空,副教授,chenqingkong@cqjtu.edu.cn E-mail: chenqingkong@cqjtu.edu.cn

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	JI Fang-ying
	WANG Pan-qiao
	CHEN Qing-kong

Cite this article:

JI Fang-ying,WANG Pan-qiao,CHEN Qing-kong. Mesoporous multi yolk-shell@mSiO₂ nanoreactor for BPA degradation[J]. CHINA ENVIRONMENTAL SCIENCECE, 2018, 38(6): 2124-2134.

URL:

http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2018/V38/I6/2124

[1]	陈晓旸.基于硫酸自由基的高级氧化技术降解水中典型有机污染物研究[D]. 大连:大连理工大学, 2007.
[2]	Antoniou M G, de la Cruz A A, Dionysiou D D. Degradation of microcystin-LR using sulfate radicals generated through photolysis, thermolysis and e(-) transfer mechanisms[J]. Applied Catalysis B-environmental, 2010,96(3/4):290-298.
[3]	Guo W, Su S, Yi C, et al. Degradation of antibiotics amoxicillin by Co3O4-catalyzed peroxymonosulfate system[J]. Environmental Progress & Sustainable Energy, 2013,32(2):193-197.
[4]	Shukla P, Wang S, Singh K, et al. Cobalt exchanged zeolites for heterogeneous catalytic oxidation of phenol in the presence of peroxymonosulphate[J]. Applied Catalysis B:Environmental, 2010,99(1):163-169.
[5]	Hu P, Long M. Cobalt-catalyzed sulfate radical-based advanced oxidation:A review on heterogeneous catalysts and applications[J]. Applied Catalysis B:Environmental, 2016,181(Supplement C):103-117.
[6]	Perez-Lorenzo M, Vaz B, Salgueirino V, et al. Hollow-shelled nanoreactors endowed with high catalytic activity[J]. Chemistry-A European Journal, 2013,19(37):12196-12211.
[7]	Anipsitakis G P, Stathatos E, Dionysiou D D. Heterogeneous activation of oxone using Co3O4[J]. Journal of Physical Chemistry B, 2005,109(27):13052-13055.
[8]	Xu X R, Li H B, Wang W H, et al. Degradation of dyes in aqueous solutions by the Fenton process[J]. Chemosphere, 2004,57(7):595-600.
[9]	Hartmann M. Ordered mesoporous materials for bioadsorption and biocatalysis[J]. Chemistry of Materials, 2005,17(18):4577-4593.
[10]	Deng Y, Qi D, Deng C, et al. Superparamagnetic high-magnetization microspheres with an Fe3O4@SiO2 core and perpendicularly aligned mesoporous SiO2 shell for removal of microcystins[J]. Journal of the American Chemical Society, 2008,130(1):28-29.
[11]	Liu Z, Yang H, Zhang H, et al. Oil-field wastewater purification by magnetic separation technique using a novel magnetic nanoparticle[J]. Cryogenics, 2012,52(12SI):699-703.
[12]	Latini G, Knipp G, Mantovani A, et al. Endocrine disruptors and human health[J]. Mini-Reviews in Medicinal Chemistry, 2010,10(9):846-855.
[13]	Bromer J G, Zhou Y, Taylor M B, et al. Bisphenol-A exposure in utero leads to epigenetic alterations in the developmental programming of uterine estrogen response[J]. Faseb Journal, 2010,24(7):2273-2280.
[14]	Staples C A, Dorn P B, Klecka G M, et al. A review of the environmental fate, effects, and exposures of bisphenol A[J]. Chemosphere, 1998,36(10):2149-2173.
[15]	Huling S G, Kan E, Wingo C. Fenton-driven regeneration of MTBE-spent granular activated carbon-Effects of particle size and iron amendment procedures[J]. Applied Catalysis B-Environmental, 2009,89(3/4):651-658.
[16]	Kan E, Huling S G. Effects of Temperature and acidic pre-treatment on fenton-driven oxidation of MTBE-spent granular activated carbon[J]. Environmental Science & Technology, 2009,43(5):1493-1499.
[17]	Liu C, Li J, Qi J, et al. Yolk-Shell Fe0@SiO2 Nanoparticles as nanoreactors for fenton-like catalytic reaction[J]. ACS Applied Materials & Interfaces, 2014,6(15):13167-13173.
[18]	陈晴空.基于SO4•-的非均相类Fenton-光催化协同氧化体系研究[D]. 重庆:重庆大学, 2014.
[19]	Ganesh I, Gupta A K, Kumar P P, et al. Preparation and characterization of Co-doped TiO2 materials for solar light induced current and photocatalytic applications[J]. Materials Chemistry and Physics, 2012,135(1):220-234.
[20]	Lu Y, Lin Y, Wang D, et al. A high performance cobalt-doped ZnO visible light photocatalyst and its photogenerated charge transfer properties[J]. Nano Research, 2011,4(11):1144-1152.
[21]	Shi P, Su R, Wan F, et al. Co3O4 nanocrystals on graphene oxide as a synergistic catalyst for degradation of Orange Ⅱ in water by advanced oxidation technology based on sulfate radicals[J]. Applied Catalysis B-Environmental, 2012,123:265-272.
[22]	Saputra E, Muhammad S, Sun H, et al. alpha-MnO2 activation of peroxymonosulfate for catalytic phenol degradation in aqueous solutions[J]. Catalysis Communications, 2012,26:144-148.
[23]	Zeng T, Zhang X, Wang S, et al. Spatial Confinement of a Co3O4 Catalyst in Hollow Metal-Organic Frameworks as a Nanoreactor for Improved Degradation of Organic Pollutants[J]. Environmental Science & Technology, 2015,49(4):2350-2357.
[24]	Du D, Shi W, Wang L, et al. Yolk-shell structured Fe3O4@void@TiO2 as a photo-Fenton-like catalyst for the extremely efficient elimination of tetracycline[J]. Applied Catalysis B-Environmental, 2017,200:484-492.
[25]	Chen L, Li L, Wang T, et al. A novel strategy to fabricate multifunctional Fe3O4@C@TiO2 yolk-shell structures as magnetically recyclable photocatalysts[J]. Nanoscale, 2014,6(12):6603-6608.
[26]	Cleveland V, Bingham J, Kan E. Heterogeneous Fenton degradation of bisphenol A by carbon nanotube-supported Fe3O4[J]. Separation and Purification Technology, 2014,133(Supplement C):388-395.
[27]	Yu L, Wang C, Ren X, et al. Catalytic oxidative degradation of bisphenol A using an ultrasonic-assisted tourmaline-based system:Influence factors and mechanism study[J]. Chemical Engineering Journal, 2014,252(Supplement C):346-354.
[28]	Zhao M, Zheng L, Li N, et al. Fabrication of hollow silica spheres in an ionic liquid microemulsion[J]. Materials Letters, 2008, 62(30):4591-4593.
[29]	Yang Q, Choi H, Dionysiou D D. Nanocrystalline cobalt oxide immobilized on titanium dioxide nanoparticles for the heterogeneous activation of peroxymonosulfate[J]. Applied Catalysis B-Environmental, 2007,74(1/2):170-178.
[30]	Rivas F J, Gimeno O, Borallho T. Aqueous pharmaceutical compounds removal by potassium monopersulfate. Uncatalyzed and catalyzed semicontinuous experiments[J]. Chemical Engineering Journal, 2012,192(Supplement C):326-333.
[31]	Su S, Guo W, Yi C, et al. Degradation of amoxicillin in aqueous solution using sulphate radicals under ultrasound irradiation[J]. Ultrasonics Sonochemistry, 2012,19(3):469-474.
[32]	Hu P, Long M. Cobalt-catalyzed sulfate radical-based advanced oxidation:A review on heterogeneous catalysts and applications[J]. Applied Catalysis B:Environmental, 2016,181(Supplement C):103-117.
[33]	Chen Q, Ji F, Liu T, et al. Synergistic effect of bifunctional Co-TiO2 catalyst on degradation of Rhodamine B:Fenton-photo hybrid process[J]. Chemical Engineering Journal, 2013,229(Supplement C):57-65.
[34]	GB/T19923-2005城市污水再生利用-工业用水水质[S].
[35]	Ding Y, Zhu L, Wang N, et al. Sulfate radicals induced degradation of tetrabromobisphenol A with nanoscaled magnetic CuFe2O4 as a heterogeneous catalyst of peroxymonosulfate[J]. Applied Catalysis B:Environmental, 2013,129(Supplement C):153-162.
[36]	Muhammad S, Shukla P R, Tadé M O, et al. Heterogeneous activation of peroxymonosulphate by supported ruthenium catalysts for phenol degradation in water[J]. Journal of Hazardous Materials, 2012,215(Supplement C):183-190.
[37]	Yuan Z, Sui M, Yuan B, et al. Degradation of ibuprofen using ozone combined with peroxymonosulfate[J]. Environmental Science-Water Research & Technology, 2017,3(5):960-969.
[38]	Li Y, Zhang F. Catalytic oxidation of Methyl Orange by an amorphous FeOOH catalyst developed from a high iron-containing fly ash[J]. Chemical Engineering Journal, 2010, 158(2):148-153.
[39]	Ji F, Li C, Deng L. Performance of CuO/Oxone system:Heterogeneous catalytic oxidation of phenol at ambient conditions[J]. Chemical Engineering Journal, 2011,178:239-243.
[40]	GB3838-2002地表水环境质量标准[S].