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Treatment of 2,4,5-trichlorobiphenyl in soil with nanometer zero-valent iron and Na2S2O8 coupled with ultrasonic composite method |
LIU Jian-fu1,2, LI Qing-song1,2, GUO Shu-juan1 |
1. Department of Environmental Science and Engineering, Xiamen University of Technology, Xiamen 361024, China;
2. Key Laboratory of Environmental Biotechnology, Fujian Province University, Xiamen 361024, China |
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Abstract Polychlorinated biphenyls (PCBs) are a group of highly toxic and bio-refractory organic compounds. In order to improve the treatment efficiency of PCBs in soil, 2,4,5-trichlorobiphenyl (PCB-29) was chosen as a model pollutant in this study. The degradation experiments of PCB-29 were performed with nanometer zero-valent iron (NZVI) activation sodium persulfate, and coupled with ultrasonic oxidation. The results indicated that the PCB-29 removal rate was 86.37% in one hour by NZVI/Na2S2O8/ultrasonic composite treatment. The optimal degradation conditions of PCB-29with NZVI/Na2S2O8/ultrasonic composite method are soil initial pH 5.0, Na2S2O8 concentration 12mmol/L, the molar ratio of Na2S2O8/NZVI 1:1.
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Received: 13 November 2017
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