|
|
|
| Adsorption properties of micropollutants amino acids on metallic organic framework HKUST-1 in aqueous system |
| LU Si-jia1, MA Xiao-yan1, LI Qing-song2, SONG Ya-li3, YU Qi1, ZHU Li-dan1 |
1. College of Civil Engineering and Architecture, Zhejiang University of Technology, Hangzhou 310014, China;
2. Fujian Engineering and Research Center of Rural Sewage Treatment and Water Safety, Water Resources and Environmental Institute, Xiamen University of Technology, Xiamen 361005, China;
3. School of Civil Enginneering and Architecture, Zhejiang University of Science and Technology, Hangzhou 310023, China |
|
|
|
|
Abstract The metal organic framework HKUST-1 was prepared by solvothermal method. The tyrosine (Tyr), phenylalanine (phe) and tryptophan (Tyr) which were detected frequently in water source were selected as the targets, and their adsorption on HKUST-1 was investigated. The adsorbent characteristic of HKUST-1was analyzed by XRD and FTIR techniques. The adsorption mechanism of amino acids on HKUST-1 was investigated by adsorption kinetics, isotherms and thermodynamics. HKUST-1 had high crystallinity and good removal effects on tyrosine, phenylalanine and tryptophan, saturated adsorption capacity was up to 248.65,143.67 and 140.09mg/g; the adsorption process was in accordance with the Langmuir adsorption isotherm model and the Lagergren quasi-secondary kinetic model; adsorption thermodynamics results showed that HKUST-1 removed amino acids as an endothermic reaction; high adsorption capacity was mainly attributed to electrostatic interaction, hydrogen bonding and π-π interaction.
|
|
Received: 06 December 2018
|
|
|
|
|
|
| [1] |
Sharma V K, Yang X, Cizmas L, et al. Impact of metal ions, metal oxides, and nanoparticles on the formation of disinfection byproducts during chlorination[J]. Chemical Engineering Journal, 2017,317:777-792.
|
| [2] |
徐倩,徐斌,覃操,等.水中典型含氮有机物氯化生成消毒副产物的潜能研究[J]. 环境科学, 2011,32(7):1967-1973. Xu Q, Xu B, Qin C, et al. Chlorination byproducts formation potentials of typical nitrogenous organic compounds in water[J]. Environmental Science, 2011,32(7):1967-1973.
|
| [3] |
How Z T, Linge K L, Busetti F, et al. Chlorination of amino acids:reaction pathways and reaction rates[J]. Environmental Science & Technology, 2017,51(9):4870-4876.
|
| [4] |
Hagedorn F, Schleppi P, Waldner P, et al. Export of dissolved organic carbon and nitrogen from Gleysol dominated catchments-the significance of water flow paths[J]. Biogeochemistry, 2000,50(2):137-161.
|
| [5] |
Huang G, Jiang P, Li X F. Mass spectrometry identification of N-chlorinated dipeptides in drinking water[J]. Analytical Chemistry, 2017,89(7):4204-4209.
|
| [6] |
Pivokonsky M, Safarikova J, Bubakova P, et al. Coagulation of peptides and proteins produced by Microcystis aeruginosa:interaction mechanisms and the effect of Fe-peptide/protein complexes formation[J]. Water Research, 2012,46(17):5583-5590.
|
| [7] |
Prevost M, Ganthier C, Hureiki L, et al. Removal of amino acids, biodegradable organic carbon and chlorine demand by biological filtration in cold water[J]. Environmental Technology, 1998,19(9):903-911.
|
| [8] |
Dotson A, Westerhoff P. Occurrence and removal of amino acids during drinking water treatment[J]. American Water Works Association, 2009,101(9):101-115.
|
| [9] |
马锋锋,赵保卫,刁静茹,等.磁性生物炭对水体中对硝基苯酚的吸附特性[J]. 中国环境科学, 2019,39(1):170-178. Ma F F, Zhao B W, Diao J R, et al. Adsorption characteristics of p-nitrophenol removal by magnetic biochar[J]. China Enviromental Science, 2019,39(1):170-178.
|
| [10] |
Kim H K, Yun W S, Kim M, et al. A chemical route to activation of open metal sites in the copper-based metal-organic framework materials HKUST-1and Cu-MOF-2[J]. Journal of the American Chemical Society, 2015,137(31):10009-10015.
|
| [11] |
Chen Y P, Mu X L, Lester E, et al. High efficiency synthesis of HKUST-1under mild conditions with high BET surface area and CO2 uptake capacity[J]. Progress in Natural Science:Materials International, 2018,28(5):584-589.
|
| [12] |
Ramezanalizadeh H, Manteghi F. Synthesis of a novel MOF/CuWO4 heterostructure for efficient photocatalytic degradation and removal of water pollutants[J]. Journal of Cleaner Production, 2018,172:2655-2666.
|
| [13] |
Lin K A, Hsieh Y. Copper-based metal organic framework (MOF), HKUST-1, as an efficient adsorbent to remove p-nitrophenol from water[J]. Journal of the Taiwan Institute of Chemical Engineers, 2015,50:223-228.
|
| [14] |
Azhar M R, Abid H R, Sun H, et al. Excellent performance of copper based metal organic framework in adsorptive removal of toxic sulfonamide antibiotics from wastewater[J]. Journal of Colloid and Interface Science, 2016,478:344-352.
|
| [15] |
Ke F, Qiu L G, Yuan Y P, et al. Thiol-functionalization of metal-organic framework by a facile coordination-based postsynthetic strategy and enhanced removal of Hg2+ from water[J]. Journal of Hazardous Materials, 2011,196:36-43.
|
| [16] |
马叶,刘斌,孙楠,等.改性活性炭对水中铬离子(VI)的吸附性能[J]. 环境工程学报, 2014,8(7):2672-2676. Ma Y, Liu B, Sun N, et al. Adsorption of Cr ions (VI) by modified activated carbon[J]. Chinese Journal of Environmental Engineering, 2014,8(7):2672-2676.
|
| [17] |
Sun Y, Ding C, Cheng W, et al. Simultaneous adsorption and reduction of U (VI) on reduced graphene oxide-supported nanoscale zerovalent iron[J]. Journal of Hazardous Materials, 2014,280:399-408.
|
| [18] |
Lim Y S, Kim K H. Isotherm,kinetic and thermodynamic studies on the adsorption of 13-dehydroxybaccatin Ⅲ from Taxus chinen? sis onto Sylopute[J]. The Journal of Chemical Thermodynamics, 2017, 39(7):1027-1037.
|
| [19] |
王彩云,刘恋,李创,等. MWCNTs改性凹凸棒土对水中Cr(VI)的吸附研究[J]. 中国环境科学, 2017,37(6):2179-2186. Wang C Y, Liu L, Li C, et al. Adsorption of Cr (VI) on the MWCNTs/attapulgite composites[J]. China Enviromental Science, 2017,37(6):2179-2186.
|
| [20] |
Haque E, Lee J E, Jang I T, et al. Adsorptive removal of methyl orange from aqueous solution with metal-organic frameworks, porous chromium-benzenedicarboxylates[J]. Journal of Hazardous Materials, 2010,181(1-3):535-542.
|
| [21] |
Andrew Lin K-Y, Hsieh Y-T. Copper-based metal organic framework (MOF), HKUST-1, as an efficient adsorbent to remove p-nitrophenol from water[J]. Journal of the Taiwan Institute of Chemical Engineers, 2015,50:223-228.
|
| [22] |
Asadi T, Ehsani M R, Ribeiro A M, et al. CO2/CH4 separation by adsorption using nanoporous metal organic framework copper-benzene-1,3,5-tricarboxylate tablet[J]. Chemical Engineering & Technology, 2013,36(7):1231-1239.
|
| [23] |
Huo S H, Yan X P. Metal-organic framework MIL-100(Fe) for the adsorption of malachite green from aqueous solution[J]. Journal of Materials Chemistry, 2012,22(15):7449-7455.
|
| [24] |
Takara E A, Vega-Hissi E G, Garro-Martinez J C, et al. About endothermic sorption of tyrosine chitosan films[J]. Carbohydrate Polymers, 2019,206:57-64.
|
|
|
|
