NaOH改性鱼骨粉材料对Cd(II)的吸附

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Abstract

Higher performance function of fish bone meal (FBM_T) treated by NaOH was obtained, and then BET, XRD, FTIR, SEM-EDS, and TEM were used to investigate the structure characteristics of samples and the properties and mechanisms of Cd removal. The results showed that compared with FBM a certain number of medium-and macro-porous appeared in FBM_T, and higher volume and average width of pore were got in FBM_T, being 68.57% and 24.69%, respectively, higher than that of FBM. After treated with NaOH, the amount function groups such as -OH, C=O and PO₄^3- in FBM_T was increased. The adsorption of Cd (Ⅱ) on FBM and FBM_T included an initial fast sorption phase and a second slow sorption phase, and the process of adsorption kinetics was well fitted by Pseudo-second-order, with correlation coefficients R² 0.8635 and 0.9480, respectively. The isothermal adsorption process could be well fitted with Langmuir isotherms, and the maximum adsorption capacity of Cd increased from 9.28mg/g on FBM to 22.47mg/g on FBM_T, and the adsorption intensity (the values of K_F) was correspondingly increased. The value of separation factor (0 < R_L < 1) indicated that the adsorption process of Cd (Ⅱ) was favorable. The interaction mechanisms of function materials and Cd (Ⅱ) involved special cation adsorption, electrostatic adsorption, ion exchange, surface complexation and precipitation. Therefore, the research above supports an economic and effective method for the remediation of Cd contamination using fish bone meal.

Key words： fish bone meal Cd contamination modification absorption mechanism

Received: 09 February 2019

PACS:

X703.5

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	Articles by authors
	LUO Wen-wen
	XU Ying-ming
	WANG Nong
	SUN Yue-bing

Cite this article:

LUO Wen-wen,XU Ying-ming,WANG Nong等. The absorption of Cd(II) on NaOH modified fish bone meal function materials[J]. CHINA ENVIRONMENTAL SCIENCECE, 2019, 39(9): 3824-3831.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2019/V39/I9/3824

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