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Digestion performance of roasted sample produced by co-treatment of spent pot-lining and red mud |
LU Fang-hai1, ZHENG Kai1,2, SU Xiang-dong1,2, CHEN Xiao-hu1, HUANG Fang1, WANG Zhi-cheng1, GU Xiao-fei1, YAN Qing-song3 |
1. School of Materials Science and Metallurgical Engineering, Guizhou Institute of Technology, Guiyang 550003, China; 2. Key Laboratory of Light Metal Materials Processing of Guizhou Province, Guizhou Institute of Technology, Guiyang 550003, China; 3. Guizhou Yi Wei De Environmental Protection Technology Development Co., Ltd, Qingzhen 551400, China |
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Abstract The digestion performance of roasted sample produced by co-treatment of spent pot-lining and red mud at high temperature were studied using XRF, ICP-MS, XRD and SEM-EDS. The experimental results showed that the influences of alkali concentration (Na2CO3), temperature, digestion duration and liquid-solid ratio on the digestion rates of Al2O3 and Na2O and the enrichment of TFe2O3 were consistent. The optimal digestion conditions were below:Na2CO3 30g/L, temperature 50℃, time 30min, liquid-solid ratio 8. Under these conditions, the digestion rates of Al2O3 and Na2O in the roasted sample were 87.41% and 92.51% respectively; while only 3.02% of SiO2 and 0.36% of CaO were digested, and iron minerals were almost indissoluble in alkaline solution. The content of TFe2O3 increased to 39.89% in the digested residue from 23.64% in the roasted sample. The results showed that the efficiently recovery of aluminum, sodium and the enrichment of iron from the roasted sample were achieved simultaneously by the digestion process. Moreover, compared with the roasted sample, the amount of digested residue was reduced by nearly 16% (evaluated based on the digestion rates of Al2O3 and Na2O), and it was non-hazardous.
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Received: 11 November 2019
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[1] |
Andrade-Vieira L F, Gedraite L S, Campos J M S, et al. Effects of spent pot liner on mitotic activity and nuclear DNA content in meristematic cells of Allium cepa[J]. Journal of Environmental Management, 2012,107(9):140-146.
|
[2] |
Lisbona D F, Somerfield C, Steel K M. Leaching of spent pot-lining with aluminium nitrate and nitric acid:Effect of reaction conditions and thermodynamic modelling of solution speciation[J]. Hydrometallurgy, 2013,134-135(5):132-143.
|
[3] |
Lu F H, Xiao T F, Lin J, et al. Recovery of gallium from Bayer red mud through acidic-leaching-ion-exchange process under normal atmospheric pressure[J]. Hydrometallurgy, 175(2018):124-132
|
[4] |
Qu Y, Li H, Tian W, et al. Leaching of valuable metals from red mud via batch and continuous processes by using fungi[J]. Minerals Engineering, 2015,81:1-4.
|
[5] |
Liu Z, Li H. Metallurgical process for valuable elements recovery from red mud-A review[J]. Hydrometallurgy, 2015,155:29-43.
|
[6] |
Personnet P B. Treatment and reuse of spent pot lining, an industrial application in a cement kiln[M]//Essential Readings in Light Metals. Springer International Publishing, 2016:1049-1056.
|
[7] |
Flores I V, Fraiz F, Junior R A L, et al. Evaluation of spent pot lining (SPL) as an alternative carbonaceous material in ironmaking processes[J]. Journal of Materials Research & Technology, 2017. https://doi.org/10.1016/j.jmrt.2017.11.004)
|
[8] |
陈喜平.铝电解废槽衬火法处理工艺研究与热工分析[D]. 长沙:中南大学, 2009. Chen X P. Studying on pyro-process for spent potlining and its heat transfer analyzing[D]. Changsha:Central South University, 2009.
|
[9] |
Birry L, Leclerc S, Poirier S. The LCL&L Process:A Sustainable Solution for the Treatment and Recycling of Spent Potlining[M]//Light Metals 2016. John Wiley & Sons, Inc. 2016.
|
[10] |
Xiao J, Yuan J, Tian Z, et al. Comparison of ultrasound-assisted and traditional caustic leaching of spent cathode carbon (SCC) from aluminum electrolysis.[J]. Ultrasonics Sonochemistry, 2018,40:21-29.
|
[11] |
田忠良,杨凯,肖劲,等.一种从铝电解槽废旧的阴极炭块中回收炭和电解质的方法, CN105821445A[P]. 2016. Tian Z L, Yang K, Xiao J, et al. A method of recovering carbon and electrolyte from waste cathode carbon block of aluminum electrolytic cell. CN105821445A[P]. 2016.
|
[12] |
鲍龙飞.铝电解槽废旧阴极材料的综合利用研究[D]. 西安:西安建筑科技大学, 2014. Bao L F. Research on comprehensive utilization of the spen cathode of aluminium cell[D]. Xi'an:Xi'an University of architecture and technology, 2014.
|
[13] |
李楠.浮选法综合回收利用低碳品位废旧阴极工艺研究[D]. 昆明:昆明理工大学, 2015. Li N. Study on the technology of comprehensive recovery and utilization of low carbon grade waste cathode by flotation[D]. Kunming:Kunming University of Science and Technology, 2015.
|
[14] |
Palmieri M J, Luber J, Andrade-Vieira L F, Davide L C. Cytotoxic and phytotoxic effects of the main chemical components of spent pot-liner:A comparative approach[J]. Mutation Research/Genetic Toxicology and Environmental Mutagenesis, 2014,763(3):30-35.
|
[15] |
Cyril S, Walid M, Mahfoud B, et al. A laboratory-scale experimental investigation on the reuse of a modified red mud in ceramic materials production, Construction and Building Materials[J]. 2018,163:21-31
|
[16] |
史京转,魏红,周孝德,等.酸化赤泥吸附环丙沙星的特征、机理及过程优化[J]. 中国环境学, 2019,39(11):4689-4696. Shi J Z, Wei H, Zhou X D, et al. Adsorption of ciprofloxacin by acidified red mud:characteristic, mechanism and process optimization[J]. Chinese Environmental Science, 2019,39(11):4689-4696
|
[17] |
Deihimi N, Irannajad M, Rezai B. Characterization studies of red mud modification processes as adsorbent for enhancing ferricyanide removal[J]. Journal of Environmental Management, 2017,206:266-275.
|
[18] |
Samouhos M, Taxiarchou M, Pilatos G, et al. Controlled reduction of red mud by H2, followed by magnetic separation[J]. Minerals Engineering, 2017,105:36-43.
|
[19] |
Abdulvaliyev R A, Akcil A, Gladyshev S V, et al. Gallium and vanadium extraction from red mud of Turkish alumina refinery plant:Hydrogarnet process[J]. Hydrometallurgy, 2015,157:72-77.
|
[20] |
Lu F H, Xiao T F, Lin J, et al. Resources and extraction of gallium:A review[J]. Hydrometallurgy, 2017,174:105-115.
|
[21] |
Jayasankar K, Ray P K, Chaubey A K, et al. Production of pig iron from red mud waste fines using thermal plasma technology[J]. Int. J. Miner. Metall. Mater, 2012,19(8):679-684.
|
[22] |
Xenidis A, Zografidis C, Kotsis I, et al. Reductive Smelting of Greek Bauxite Residues for Iron Production[M]//Light Metals 2011. Springer International Publishing, 2011:113-117.
|
[23] |
Man Y, Feng J. Effect of gas composition on reduction behavior in red mud and iron ore pellets[J]. Powder Technology, 2016,301:674-678.
|
[24] |
Zhao Z, Yang Y, Xiao Y, et al. Recovery of gallium from Bayer liquor:A review[J]. Hydrometallurgy, 2012,s125-126(8):115-124.
|
[25] |
Xu Z, Hwang J, Greenlund R, et al. Quantitative Determination of Metallic Iron Content in Steel-Making Slag[J]. Journal of Minerals & Materials Characterization & Engineering, 2003,02(1):2557-2564.
|
[26] |
Samouhos M, Taxiarchou M, Tsakiridis P E, et al. Greek "red mud" residue:a study of microwave reductive roasting followed by magnetic separation for a metallic iron recovery process.[J]. Journal of Hazardous Materials, 2013,254-255:193.
|
[27] |
毕诗文.氧化铝生产工艺[M]. 北京:化学工业出版社, 2006. Bi SW. Alumina production process[M]. Beijing:Chemical Industry Press, 2006.
|
[28] |
Sun H, Wang B, Zhang J, et al. Characterization and alumina leachability of 12CaO·Al2O3 with different holding times[J]. Advances in Materials Science & Engineering, 2014,(2):1-6.
|
[29] |
Sun H, Wang B, Zhang J, et al. Secondary reaction mechanism of leaching process of calcium aluminate slag[J]. Transactions of Nonferrous Metals Society of China, 2015,25(4):1334-1340.
|
[30] |
Li X, Xiao W, Liu W, et al. Recovery of alumina and ferric oxide from Bayer red mud rich in iron by reduction sintering[J]. Transactions of Nonferrous Metals Society of China, 2009,19(5):1342-1347
|
[31] |
Liu W, Sun S, Zhang L, et al. Experimental and simulative study on phase transformation in Bayer red mud soda-lime roasting system and recovery of Al, Na and Fe[J]. Minerals Engineering, 2012,39(12):213-218.
|
|
|
|