我国典型钢铁工业城市夏季臭氧污染来源解析研究

Abstract
Figure/Table
References
Related Citation (15)

Download: PDF (1427 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract Handan was the most seriously ozone polluted city compared with surrounding cities. This paper was analyzed the spatial and temporal distribution characteristics of ozone in Handan by using monitoring data. The analysis showed that ozone pollution was very serious during research period and the standard exceeding rate of days was 86.7% in Handan. Ozone concentration exhibited spatial variations over the research regions. The main causes of ozone pollution were influenced from elevated temperature, low humidity and transmission of southerly air masses. Then comprehensive air quality model extensions CAMx based ozone source apportionment technology (OSAT) was applied to quantify the contributions of different emissions to ozone concentration in different receptors of Handan. The analysis revealed that the ozone pollution in Handan had strong regional contribution. Local emissions to ozone pollution of administrative region had reached 43.9%, while obvious increase of ozone contribution to urban areas came from local emissions (46.5%). Chen’an was the most seriously ozone polluted county in Handan, while ozone pollution in Chen’an resulted from both local emissions (37.4%) and from Henan. Compared with monthly average, local emissions for the typical ozone pollution process tended to have more ozone contribution (54.0%). Divided by source sectors, the largest contributors to ozone of main urban areas were local mobile pollution sources. While for the typical ozone pollution process, the largest contributors turned into local metallurgical. Sensitivity analysis of model photochemical ozone generation showed that under monthly average most of ozone in main urban areas were generated in VOCs sensitive. While for the typical ozone pollution process, the proportion of ozone generated in NO_x sensitive had been increased.

Key words： Handan city steel industrial city ozone CAMx-OSAT model source apportionment sensitivity analysis

Received: 09 June 2020

PACS:

X513

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	YAO Shi-yin
	WEI Wei
	SHEN Ze-ya
	WANG Chuan-da
	NIU Yuan

Cite this article:

YAO Shi-yin,WEI Wei,SHEN Ze-ya等. Source apportionment of ozone pollution in the typical steel industry city of China in summer[J]. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(1): 37-48.

URL:

http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2021/V41/I1/37

[1]	梁从诫.2005年:中国的环境危局与突围[M]. 北京:社会科学文献出版社, 2006:1-20. Liang C J. Crisis and breakthrough of China's environment (2005)[M]. Beijing:Social Sciences Literature Press, 2006:1-20.
[2]	环境保护部.2016中国环境状况公报[R]. 北京:环境保护部, 2017:7-16. Environmental Protection Agency. Bulletin on the state of China's environment 2016[R]. Beijing:Environmental Protection Agency, 2017:7-16.
[3]	生态环境部.2017中国生态环境状况公报[R]. 北京:生态环境部, 2018:7-16. Ministry of Ecology and Environment. Bulletin of China's ecological environment 2017[R]. Beijing:Ministry of Ecology and Environment, 2018:7-16.
[4]	生态环境部.2018中国生态环境状况公报[R]. 北京:生态环境部, 2019:7-16. Ministry of Ecology and Environment. Bulletin of China's ecological environment 2018[R]. Beijing:Ministry of Ecology and Environment, 2019:7-16.
[5]	唐孝炎,张远航,邵敏.大气环境化学(第二版)[M]. 北京:高等教育出版社, 2006:101-113. Tang X Y, Zhang Y H, Shao M. Atmospheric environmental chemistry. 2nd ed.[M]. Beijing:Higher Education Press, 2006:101-113.
[6]	Sun C, Zhao N, Zhuang Z, et al. Mechanisms and reaction pathways for simultaneous oxidation of NOx and SO2 by ozone determined by in situ IR measurements[J]. Journal of Hazardous Materials, 2014,274:376-383.
[7]	Seinfeld J H, Pandis S N. 2006. Atmospheric chemistry and physics:From air pollution to climate change (2nd edition)[M]. John Wiley &Sons, Inc.
[8]	王雪松,李金龙.人为源排放VOC对北京地区臭氧生成的贡献[J]. 中国环境科学, 2002,22(6):22-26. Wang X S, Li J L. The contribution of anthropogenic hydrocarbons to ozone formation in Beijing areas[J]. China Environmental Science, 2002,22(6):22-26.
[9]	王占山,李云婷,陈添,等.北京城区臭氧日变化特征及与前体物的相关性分析[J]. 中国环境科学, 2014,34(12):3001-3008. Wang Z S, Li Y T, Chen T, et al. Analysis on diurnal variation characteristics of ozone and correlations with its precursors in urban atmosphere of Beijing[J]. China Environmental Science, 2014,34(12):3001-3008.
[10]	梁永贤,尹魁浩,胡泳涛,等.深圳地区臭氧污染来源的敏感性分析[J]. 中国环境科学, 2014,34(6):1390-1396. Liang Y X, Yin K H, Hu Y T, et al. Sensitivity analysis of ozone precursor emission in Shenzhen, China[J]. China Environmental Science, 2014,34(6):1390-1396.
[11]	Li Y, Lau K H, Fung C H, et al. Ozone source apportionment (OSAT) to differentiate local regional and super-regional source contributions in the Pearl River Delta region, China[J]. Journal of Geophysical Research Atmospheres, 2012,117,D15305.
[12]	Wolff G T, Lioy P J, Meyers R E, et al. Anatomy of two ozone transport episodes in the Washington, D.C. to Boston, Mass. Corridor[J]. Environmental Science & Technology, 1977,11(5):506-510.
[13]	黄争超,洪礼楠,尹佩玲,等.保定市夏季O3污染来源及大气传输影响研究[J]. 北京大学学报(自然科学版), 2018,54(3):665-672. Huang Z C, Hong L N, Yin P L, et al. Source apportionment and transport characteristics of ozone in Baoding during summer time[J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 2018,54(3):665-672.
[14]	邯郸市统计局.邯郸市统计年鉴[M]. 北京:中国统计出版社, 2018:25-48. Handan Statistics Bureau. Handan statistical yearbook[M]. Beijing:China Statistics Press, 2018:25-48.
[15]	邯郸市生态环境局.邯郸市环境质量公报2016年度[R]. 邯郸:邯郸市生态环境局, 2017:1. Handan Ecology and Environment Bureau. Handan environmental quality bulletin 2016[R]. Handan:Handan Ecology and Environment Bureau, 2017:1.
[16]	邯郸市生态环境局.邯郸市环境质量公报2017年度[R]. 邯郸:邯郸市生态环境局, 2018:1. Handan Ecology and Environment Bureau. Handan environmental quality bulletin 2017[R]. Handan:Handan Ecology and Environment Bureau, 2018:1.
[17]	邯郸市生态环境局.邯郸市环境质量公报2018年度[R]. 邯郸:邯郸市生态环境局, 2019:1. Handan Ecology and Environment Bureau. Handan environmental quality bulletin 2018[R]. Handan:Handan Ecology and Environment Bureau, 2019:1.
[18]	Skamarock W C, Klemp J B, Dudhia J, et al. A description of the advanced research WRF Version 3, Tech. Note, NCAR/TN-475+STR[R]. Boulder:National Center for Atmospheric Research, 2008.
[19]	Dunker A M, Yarwood G, Ortmann J P, et al. Comparison of source apportionment and source sensitivity of ozone in a three-dimensional air quality model[J]. Environmental Science & Technology, 2002, 36(13):2953-2964.
[20]	Sillman S. The use of NOy, H2O2, and HNO3as indicators for ozone-NOx-hydrocarbons sensitivity in urban locations[J]. Journal of Geophysical Research:Atmospheres, 1995,100:14175-14188.
[21]	ENVIRON. User's guide to the Comprehensive Air Quality Model with Extensions (CAMx), Version 4.4[R]. Novato, CA, US:Environ International Corporation, 2002.
[22]	李浩.夏季典型光化学污染过程中长三角地区大气臭氧的污染来源追踪研究[D]. 上海:东华大学, 2015. Li H. Ozone source apportionment during a typical photochemical pollution episode in summer in the Yangtze River Delta[D]. Shanghai:DONGHUA University, 2015.
[23]	安俊琳,王跃思,李昕,等.北京大气O3与NOx的变化特征[J]. 生态环境学报, 2008,(4):1420-1424. An J L, Wang Y S, Li X, et al. Characteristics of atmospheric O3 and NOx concentrations in the urban area[J]. Ecology and Environmental Sciences, 2008,(4):110-114.
[24]	刘树华,刘振鑫,李炬,等.京津冀地区大气局地环流耦合效应的数值模拟[J]. 中国科学:地球科学, 2009,39(1):88-98. Liu S H, Liu Z X, Li J, et al. Numerical simulation of coupling effect of local atmospheric circulation in BTH region[J]. Scientia Sinica (Terrae), 2009,39(1):88-98.
[25]	Martin, Randall V. Space-based diagnosis of surface ozone sensitivity to anthropogenic emissions[J]. Geophysical Research Letters, 2004,31(6):337-357.
[26]	香港天文台.[DB/OL]. http://www.weather.gov.hk/tc/wxinfo/currwx/wxcht.htm.
[27]	刘健,吴兑,范绍佳,等.前体物与气象因子对珠江三角洲O3污染的影响[J]. 中国环境科学, 2017,37(3):813-820. Liu J, Wu D, Fan S J, et al. Impacts of precursors and meteorological factors on ozone pollution in Pearl River Delta[J]. China Environmental Science, 2017,37(3):813-820.
[28]	Wang X S, Li J L, Zhang Y H, et al. Ozone source attribution during a severe photochemical smog episode in Beijing, China[J]. Science in China, 2009,52(8):1270-1280.
[29]	王自发,李丽娜,吴其重,等.区域输送对北京夏季O3浓度影响的数值模拟研究[J]. 自然杂志, 2008,30(4):194-198. Wang Z F, Li L N, Wu Q Z, et al. Simulation of the impacts of regional transport on summer ozone levels over Beijing[J]. Chinese Journal of Nature, 2008,30(4):194-198.
[30]	李源,孔君,徐虹,等.天津市臭氧污染特征及来源解析研究[J]. 环境污染与防治, 2019,41(6):647-651. Li Y, Kong J, Xu H, et al. Analysis of ozone pollution characteristic in Tianjin and its source apportionment[J]. Environmental Pollution & Control, 2019,41(6):647-651.
[31]	陆倩,王国辉,冯一淳,等.气象条件对承德市臭氧重污染天气的影响[J]. 生态与农村环境学报, 2019,35(8),992-999. Lu Q, Wang G H, Feng Y C, et al. The influence of meteorological conditions on a heavy ozone pollution process in Chengde city[J]. Journal of Ecology and Rural Environment, 2019,35(8):992-999.
[32]	沈劲,王自发,黄晓波,等.广东省O3污染特征及其来源解析研究[J]. 环境科学学报, 2017,37(12):4449-4457. Shen J, Wang Z F, Huang X B, et al. Study on ozone pollution characteristics and source apportionment in Guangdong Province[J]. Acta Scientiae Circumstantiae, 2017,37(12):4449-4457.
[33]	Nopmongcol U, Alvarez Y, Jung J, et al. Source contributions to United States ozone and particulate matter over five decades from 1970 to 2020[J]. Atmospheric Environment, 2017,167(oct.):116-128.