北京森林BVOCs排放特征及对区域空气质量的影响

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Abstract Emission characteristics of BVOCs from forests and its impact on regional air quality in Beijing were studied by analyzing the volume data of second-class forest resources survey in Beijing and investigating the BVOCs emission factors from relevant literatures. The results showed that the average BVOCs emissions from forest in Beijing were 27.97×10⁹g C/a, with a range of 9.46~76.45×10⁹g C/a. The contribution of isoprene, monoterpene and other VOCs (OVOCs) to total BVOCs emissions were 75.09%, 15.62% and 9.29%, respectively. The BVOCs emissions had significant species variation:poplar and quercus were the main species responsible for isoprene emission, contributing 63.16% and 25.92% to the total, respectively; Pinus tabulaeformis was the main species responsible for monoterpene emission, contributing 40.90% to the total. Forests of different age-class had different contributions to BVOCs emissions. Half-mature forest was the main emission source and contributed 39.14% to the total BVOCs emission from forests. The seasonal variations of BVOCs emissions were significant, and the emissions in spring, summer, autumn and winter accounted for 12.55%, 77.48%, 9.76% and 0.21% of the annual emissions, respectively. The ozone formation potential of BVOCs was 240.51×10⁹g, of which isoprene was the main contributor accounting for 92.66%. The secondary organic aerosol formation potential of BVOCs was 1.73×10⁹g, and the contributions of isoprene and monoterpene were 24.26% and 75.73%, respectively. This study indicated that BVOCs emissions form forest caused the annual atmospheric ozone concentrations to rise by 9.01μg/m³ and an increase of the annual atmospheric SOA concentrations by 0.94μg/m³. Especially, BVOCs emissions had relatively high contribution to ozone formation in summer. Therefore, the VOCs emissions capacity of species should be fully considered in urban greening, which would be conductive to improve air quality.

Key words： the volume of tree species emission inventory isoprene ozone formation potential secondary organic aerosol

Received: 30 June 2020

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X511

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	ZHANG Qiang
	LI Ling-jun
	ZHAO Wen-hui
	WANG Xin-hui
	JIANG Lei
	LIU Bao-xian
	LI Xiang
	LU Hai-feng

Cite this article:

ZHANG Qiang,LI Ling-jun,ZHAO Wen-hui等. Emission characteristics of VOCs from forests and its impact on regional air quality in Beijing[J]. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(2): 622-632.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2021/V41/I2/622

[1]	中国环境监测总站.全国城市空气质量报告, 2013~2019[EB/OL]. http://www.cnemc.cn/jcbg/kqzlzkbg/index.shtml.
[2]	Guenther A, Hewitt C, Erickson D, et al. A global-model of natural volatile organic-compound emission[J]. Journal of Geophysical Research Atmospheres, 1995,100(5):8873-8892.
[3]	Shao M, Lu S H, Liu Y, et al. Volatile organic compounds measured in summer in Beijing and their role in ground-level ozone formation[J]. Journal of Geophysical Research:Atmospheres, 2009,114(D2):13.
[4]	Mochizuki T, Miyazaki Y, Ono K, et al. Emissions of biogenic volatile organic compounds and subsequent formation of secondary organic aerosols in a Larix kaempferi forest[J]. Atmospheric Chemistry and Physics, 2015,15(20):12029-12041.
[5]	Wang M, Shao M, Chen W, et al. Trends of non-methane hydrocarbons (NMHC) emissions in Beijing during 2002~2013[J]. Atmospheric Chemistry and Physics, 2015,15(3):1489-1502.
[6]	Li J, Wu R, Li Y, et al. Effects of rigorous emission controls on reducing ambient volatile organic compounds in Beijing, China[J]. Science of the Total Environment, 2016,557(1):531-541.
[7]	北京市统计局,国家统计局北京调查总队.北京统计年鉴2019[EB/OL]. http://nj.tjj.beijing.gov.cn/nj/main/2019-tjnj/zk/indexch.htm. Beijing Municipal Bureau Statistics, Survey Office of the National Bureau of Statistics in Beijing. Beijing Statistical Yearbook 2019[EB/OL]. http://nj.tjj.beijing.gov.cn/nj/main/2019-tjnj/zk/indexch.htm.
[8]	Fu Y, Liao H. Impacts of land use and land cover changes on biogenic emissions of volatile organic compounds in China from the late 1980s to the mid-2000s:implications for tropospheric ozone and secondary organic aerosol[J]. Tellus:Series B, 2014,66:24987.doi:10.3402/tellusb.v66.24987.
[9]	Ghirardo A, Xie J, Zheng X, et al. Urban stress-induced biogenic VOC emissions and SOA-forming potentials in Beijing[J]. Atmospheric Chemistry and Physics, 2016,16(5):2901-2920.
[10]	Pierce T E, Waldruf P S. PC-BEIS:a personal-computer version of the biogenic emissions inventory system[J]. Journal of the Air and Waste Management Association, 1991,41(7):937-941.
[11]	Pierce T, Geroh C, Bender L, et al. Influence of increased isoprene emissions on regional ozone modeling[J]. Journal of Geophysical Research, 1998,103(D19):25611-25629.
[12]	Guenther A, Karl T, Harley P, et al. Estimates of global terrestrial isoprene emissions using MEGAN (model of emissions of gases and aerosols from nature)[J]. Atmospheric Chemistry and Physics, 2006, 6(11):3181-3210.
[13]	谢军飞,李延明.植物源挥发性有机化合物排放清单的研究进展[J]. 环境科学, 2013,34(12):4779-4786.Xie J F, Li Y M. Research advances on volatile organic compounds emission inventory of plants[J]. Environmental Science, 2013,34(12):4779-4786.
[14]	李玲玉, Alex B G,顾达萨,等.典型树种挥发性有机物(VOCs)排放成分谱及排放特征[J]. 中国环境科学, 2019,39(12):4966-4973.Li L Y, Alex B G, Gu DS, et al. Biogenic emission profile of volatile organic compounds from poplar, sweetgum, and pine trees[J]. China Environmental Science, 2019,39(12):4966-4973.
[15]	闫雁,王志辉,白郁华,等.中国植被VOC排放清单的建立[J]. 中国环境科学, 2005,25(1):111-115.Yan Y, Wang Z H, Bai Y H, et al. Establishment of vegetation VOC emission inventory in China[J]. China Environmental Science, 2005, 25(1):111-115.
[16]	毛红梅,张凯山,第宝锋.四川省天然源VOCs排放量的估算和时空分布[J]. 中国环境科学, 2016,36(5):1289-1296.Mao H M, Zhang K S, Di B F. Studies on estimates of biogenic VOC emission and its temporal and spatial distribution in Sichuan[J]. China Environmental Science, 2016,36(5):1289-1296.
[17]	王志辉,张树宇,陆思华,等.北京地区植物VOCs排放速率的测定[J]. 环境科学, 2003,24(2):7-12.Wang Z H, Zhang S Y, Lu S H, et al. Screenings of 23 plant species in Beijing for volatile organic compound emissions[J]. Environmental Science, 2003,24(2):7-12.
[18]	赵静,白郁华,王志辉,等.我国植物VOCs排放速率的研究[J]. 中国环境科学, 2004,24(6):654-657.Zhao J, Bai Y H, Wang Z H, et al. Studies on the emission rates of plants VOCs in China[J]. China Environmental Science, 2004,24(6):654-657.
[19]	谢扬飏,邵敏,陆思华,等.北京市园林绿地植被挥发性有机物排放的估算[J]. 中国环境科学, 2007,27(4):498-502.Xie Y Y, Shao M, Lu S H, et al. The estimation of volatile organic compounds emission from landscape plants in Beijing[J]. China Environmental Science, 2007,27(4):498-502.
[20]	Wang Z H, Bai Y H, Zhang S Y. A biogenic volatile organic compounds emission inventory for Beijing[J]. Atmospheric Environment, 2003,37(27):3771-3782.
[21]	Ren Y, Qu Z, Du Y, et al. Air quality and health effects of biogenic volatile organic compounds emissions from urban green spaces and the mitigation strategies[J]. Environmental Pollution, 2017,230:849-861.
[22]	Mo Z, Shao M, Wang W, et al. Evaluation of biogenic isoprene emissions and their contribution to ozone formation by ground-based measurements in Beijing, China[J]. Science of the Total Environment, 2018,627:1485-1494.
[23]	Guenther A, Baugh B, Brasseur G, et al. Isoprene emission estimates and uncertainties for the central African EXPRESSO study domain[J]. Journal of Geophysical Research:Atmospheres, 1999,104(D23):30625-30639.
[24]	Benjamin M T, Winer A M. Estimating the ozone-forming potential of urban trees and shrubs[J]. Atmospheric Environment, 1998,32:53-68.
[25]	Staudt M, Bertin N, Frenzel B, et al. Seasonal variation in amount and composition of monoterpenes emitted by young Pinus pinea trees -Implications for emission modeling[J]. Journal of Atmospheric Chemistry, 2000,35(1):77-99.
[26]	张莉,王效科,欧阳志云,等.中国森林生态系统的异戊二烯排放研究[J]. 环境科学, 2003,24(1):8-15.Zhang L, Wang X K, Ooyang Z Y, et al. Estimation of isoprene emission from forest ecosystems in China[J]. Environmental Science, 2003,24(1):8-15.
[27]	Carter W P L. Development of ozone reactivity scales for volatile organic compounds[J]. Journal of the Air and Waste Management Association, 1994,44(7):881-899.
[28]	Zheng J Y, Shao M, Che W W, et al. Speciated VOC emission inventory and spatial patterns of ozone formation potential in the Pearl River Delta, China[J]. Environmental Science and Technology, 2009, 43(22):8580-8586.
[29]	Mentel T F, Kleist E, Andres S, et al. Secondary aerosol formation from stress-induced biogenic emissions and possible climate feedbacks[J]. Atmospheric Chemistry and Physics, 2013,13(17):8755-8770.
[30]	Carter W P L. Reactivity estimates for selected consumer product compounds[R]. California:Center for Environmental Research and Technology, College of Engineering, University of California, February 19,2008.
[31]	Grosjean D. In situ organic aerosol formation during a smog episode:Estimated production and chemical functionality[J]. Atmospheric Environment, Part A, General Topics, 1992,26(6):953-963.
[32]	Guenther A, Zimmerman P, Wildermuth M. Natural volatile organic compound emission rate estimates for U.S. woodland and landscapes[J]. Atmospheric Environment, 1994,28(6):1197-1210.
[33]	赵美萍,邵敏,白郁华,等.我国几种典型树种非甲烷烃类的排放特征[J]. 环境化学, 1996,15(1):69-75.Zhao M P, Shao M, Bai Y H, et al. Study on NMHC emission characteristics of several typical trees in China[J]. Environmental Chemistry, 1996,15(1):69-75.
[34]	Klinger L F, Li Q J, Guenther A B, et al. Assessment of volatile organic compound emissions from ecosystems of China[J]. Journal of Geophysical Research, 2002,107(D21):1-21.
[35]	陈颖,李德文,史奕,等.沈阳地区典型绿化树种生物源挥发性有机物的排放速率[J]. 东北林业大学学报, 2009,(3):49-51.Chen Y, Li D W, Shi Y, et al. Emission rate of biogenic volatile organic compounds from urban trees in Shenyang, China[J]. Journal of Northeast Forestry University, 2009,(3):49-51.
[36]	吕迪.陕西森林植被BVOCs排放特征研究[D]. 杨凌:西北农林科技大学, 2016.Yang D. Estimation of BVOCs emission from forests in Shaanxi[D]. Yangling:Northwest A&F University, 2016.
[37]	樊冲.河北省森林植物源挥发性有机物排放量研究[D]. 北京:北京林业大学, 2019.Fan C. Study on biogenic volatile organic compounds emission from forest plants in Hebei province[D]. Beijing:Beijing Forestry University, 2019.
[38]	桂丽.西安市挥发性有机物排放量估算及其臭氧生成潜势研究[D]. 西安:西北大学, 2019.Gui L. Estimation of volatile organic organic compounds emissions and ozone formation potential in Xi'an city[D]. Xi'an:Northwest University, 2019.
[39]	Tani A, Kawawata Y. Isoprene emission from the major native Quercus spp. in Japan[J]. Atmospheric Environment, 2008,42(19):4540-4550.
[40]	Yaman B, Aydin Y M, Koca H, et al. Biogenic volatile organic compound (BVOC) emissions from various endemic tree species in Turkey[J]. Aerosol and Air Quality Research, 2015,15(1):341-356.
[41]	张福珠,苗鸿,鲁纯.落叶阔叶林释放异戊二烯的研究[J]. 环境科学, 1994,1:1-5.Zhang F Z, Miao H, Lu C. Emission of isoprene from deciduous forest[J]. Environmental Science, 1994,01:1-5.
[42]	Tiwary A, Namdeo A, Fuentes J, et al. Systems scale assessment of the sustainability implications of emerging green initiatives[J]. Environmental Pollution, 2013,183:213-223.
[43]	王效科,牟玉静,欧阳志云,等.太湖流域主要植物异戊二烯排放研究[J]. 植物学通报, 2002,2:224-230.Wang X K, Mu Y J, Ouyang Z Y, et al. Study on emission of isoprene from major plants living in Taihu basin[J]. Chinese Bulletin of Botany, 2002,2:224-230.
[44]	Aydin Y M, Yaman B, Koca H, et al. Biogenic volatile organic compound (BVOC) emissions from forested areas in Turkey:Determination of specific emission rates for thirty-one tree species[J]. Science of the Total Environment, 2014,490:239-253.
[45]	Prendez M, Carvajal V, Corada K, et al. Biogenic volatile organic compounds from the urban forest of the Metropolitan Region, Chile[J]. Environmental pollution, 2013,183:143-150.
[46]	Noe S M, Penuelas J, Niinemets U. Monoterpene emissions from ornamental trees in urban areas:a case study of Barcelona, Spain[J]. Plant Biology, 2008,10(1):163-169.
[47]	牟玉静,宋文质,张晓山,等.落叶阔叶树异戊二烯排放研究[J]. 环境化学, 1999,1:21-27.Mu Y J, Song W Z, Zhang X S, et al. Study on emissions of isoprene from deciduous and broadleaf trees[J]. Environmental Chemistry, 1999,1:21-27.
[48]	白郁华,李金龙,夏羽,等.杨树排放碳氢化合物的相关因素[J]. 环境化学, 1995,2:118-123.Bai Y H, Li J L, Xia Y, et al. Relative factor of hydrocarbons emission from popular tree[J]. Environmental Chemistry, 1995,2:118-123.
[49]	方精云,陈安平.中国森林植被碳库的动态变化及其意义[J]. 植物学报, 2001,43(9):967-973.Fang J Y, Chen A P. Dynamic forest biomass carbon pools in China and their significance[J]. Bulletin of Botany, 2001,43(9):967-973.
[50]	张莉.中国森林生态系统异戊二烯排放研究[D]. 南京:南京气象学院, 2002.Zhang L. Isoprene emission from forest ecosystem in China[D]. Nanjing:Nanjing Institute of Meteorology, 2002.
[51]	Guenther A, Geron C, Pierce T, et al. Natural emissions of non-methane volatile organic compounds, carbon monoxide, and oxides of nitrogen from North America[J]. Atmospheric Environment, 2000,34(12-14):2205-2230.
[52]	宋媛媛,张艳燕,王勤耕,等.基于遥感资料的中国东部地区植被VOCs排放强度研究[J]. 环境科学学报, 2012,32(9):2216-2227.Song Y Y, Zhang Y Y, Wang Q G, et al. Estimation of biogenic VOCs emissions in Eastern China based on remote sensing data[J]. Acta Scientiae Circumstantiae, 2012,32(9):2216-2227.
[53]	刘岩,李莉,安静宇,等.长江三角洲2014年天然源BVOCs排放、组成及时空分布[J]. 环境科学, 2018,39(2):608-617.Liu Y, Li L, An J Y, et al. Emissions, Chemical Composition, and Spatial and Temporal Allocation of the BVOCs in the Yangtze River Delta Region in 2014[J]. Environmental Science, 2018,39(2):608-617.
[54]	Li L Y, Xie S D. Historical variations of biogenic volatile organic compound emission inventories in China, 1981~2003[J]. Atmospheric environment, 2014,95:185-196.
[55]	Li L Y, Chen Y, Xie S D. Spatio-temporal variation of biogenic volatile organic compounds emissions in China[J]. Environmental pollution, 2013,182:157-168.
[56]	张倩,李洪远.城市绿地对大气环境的潜在负面效应[J]. 景观设计, 2019,(2):4-11.Zhang Q, Li H Y. Potential Negative Effects of Urban Green Space on the Atmospheric Environment[J]. Landscape Design, 2019,(2):4-11.
[57]	张钢锋,谢绍东.基于树种蓄积量的中国森林VOC排放估算[J]. 环境科学, 2009,30(10):2816-2822.Zhang G F, Xie S D. Estimation of VOC emission from forests in China based on the volume of tree species[J]. Environmental Science, 2009,30(10):2816-2822.
[58]	Chang J, Ren Y, Shi Y, et al. An inventory of biogenic volatile organic compounds for a subtropical urban-rural complex[J]. Atmospheric Environment, 2012,56:115-123.
[59]	Li L, An J Y, Shi Y Y, et al. Source apportionment of surface ozone in the Yangtze River Delta, China in the summer of 2013[J]. Atmospheric Environment, 2016,144:194-207.
[60]	Harrison S P, Morfopoulos C, Dani K G S, et al. Volatile isoprenoid emissions from plastid to planet[J]. New Phytologist, 2013,197(1):49-57.
[61]	徐敬,马建中.北京地区有机物种人为源排放量及O3生成潜势估算[J]. 中国科学:化学, 2013,43(1):104-115.Xu J, Ma J Z. Estimation of anthropogenic emissions and ozone formation potential of speciated VOCs in Beijing area[J]. Scientia Sinica:Chimica, 2013,43(1):104-115.
[62]	龚芳.我国人为源VOCs排放清单及行业排放特征分析[D]. 西安:西安建筑科技大学, 2013.Gong F. Anthropogenic volatile organic compounds emission inventory and characteristics[D]. Xi'an:Xi'an University of Architecture and Technology, 2013.
[63]	Arneth A, Harrison S P, Zaehle S, et al. Terrestrial biogeochemical feedbacks in the climate system[J]. Nature Geoscience, 2010,3(8):525-532.
[64]	Leuzinger S, Koerner C. Tree species diversity affects canopy leaf temperatures in a mature temperate forest[J]. Agricultural and Forest Meteorology, 2007,146(1/2):29-37.
[65]	Xu J, Ma J Z, Zhang X L, et al. Measurements of ozone and its precursors in Beijing during summertime:impact of urban plumes on ozone pollution in downwind rural areas[J]. Atmospheric Chemistry and Physics, 2011,11(23):12241-12252.