室内木柴燃烧排放水溶性离子粒径分布特征

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Abstract Six kinds of domestic firewood were burned in a laboratory. The emitted particles in fourteen sizes were collected using a dilution sampling system and an electrical low-pressure impactor. The emission characteristic and size-resolved emission factors (EFs) of eight types of water-soluble ions were identified. Results showed that the EFs of Ca²⁺ exhibited a bimodal size distribution, with peaks of 0.14 and 0.16mg/kg for particles within 0.25~0.38 and 2.5~3.6μm, respectively. The EFs of other ions were characterized by a unimodal size distribution. The EFs of NH₄⁺, NO₃^- and SO₄^2- peaked at 0.25~0.38μm, with peaks of 0.41, 0.58 and 0.84mg/kg, respectively. The EFs of K⁺ and Cl^- exhibited highest values at 0.15~0.25μm of 0.89 and 0.99mg/kg, respectively. The mass median diameters of total water-soluble ions from firewood burning were (0.30±0.07)μm, and those of individual ions ranged in 0.24~0.44μm. The EFs of water-soluble ions in PM_0.094, PM_0.94, PM_2.5 and PM₁₀ were 1.04~9.33, 5.00~48.87, 5.46~52.00 and 6.14~53.68mg/kg, respectively. The ratios of K⁺/Cl^-, K⁺/NO₃^-, K⁺/SO₄^2- and SO₄^2-/NO₃^- in particles emitted from firewood burning varied with particle size. Their primary emission values should be emphasized when they were used in source apportionment and smoke aging researches. The anion/cation equivalent ratios of PM₁₀ from firewood burning were 0.80±0.11. The acidity of PM_0.94 and PM_2.5 were higher than those of PM_0.094 and PM_2.5~10. This study is significant to establish emission inventory of size-resolved water-soluble ions, update and improve the parameter settings of corresponding climate and air quality models, and identify the evolution mechanisms of smokes during transport and aging.

Key words： domestic firewood burning dilution tunnel water-soluble ions size distribution emission factors

Received: 09 October 2020

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	FAN Ze-wei
	KONG Shao-fei
	YAN Qin
	ZHENG Shu-rui
	ZHENG Huang
	YAO Li-quan
	WU Jian
	ZHANG Ying
	NIU Zhen-zhen
	WU Fang-qi
	CHENG Yi
	ZENG Xin
	QIN Si
	LIU Xi
	YAN Ying-ying
	QI Shi-hua

Cite this article:

FAN Ze-wei,KONG Shao-fei,YAN Qin等. Size distribution of water-soluble ions in particles emitted from domestic firewood burning[J]. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(5): 2064-2072.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2021/V41/I5/2064

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