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A pilot scale study of low-temperature De-NOx in cement furnace |
LIU Huai-ping1, YIN Hai-bin2, XIONG Shang-chao1, FANG Jing-rui3, LI Jun-hua1 |
1. School of Environment, Tsinghua University, Beijing 100084, China; 2. Jiangsu Kehang Environmental Protection Co. LTD, Yancheng 224051, China; 3. State Key Laboratory of Green Building Materials, China Building Materials Academy, Beijing 100024, China |
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Abstract Low temperature selective catalytic reduction (SCR) combined with low-nitrogen combustion and selective non-catalytic reduction (SNCR) were used for deep De-NOx in a cement kiln. The SCR pilot plant with a flue gas of 10000m3/h was designed and constructed. The De-NOx effect of SCR using residual NH3 after SNCR was investigated, and the influence of inlet NOx concentration on the catalytic efficiency was also studied. To meet the emission standard, the SNCR and low-NOx burner techniques were carried out and the concentration NOx in flue gas was 100~135mg/m3. The De-NOx efficiency of SCR could reach more than 50% without the ammonia injection, which indicated the existence of NH3 slip of SNCR. With the increase of ammonia injection quantity, the De-NOx efficiency of SCR can be significantly improved. After a long time of test, the proposed De-NOx technology scheme could stably and effectively control the NOx emission in flue gas, and could meet the ultra-low emission standard. Finally, the influence of dust on the micropore blockage of catalyst was investigated, which indicated that the soot blowing system of catalyst was very important to guarantee the performance of catalyst.
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Received: 23 November 2020
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