负载镍锌氧体木质素基活性炭吸附磺胺噻唑

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Abstract Alkali lignin was used as raw material to prepare alkali lignin-based activated carbon (LAC). And then, lignin-based activated carbon-supported with nickel-zinc oxides (NiZn-DO/LAC) was fabricated by hydrothermal synthesis after adding nickel nitrate and zinc nitrate onto LAC. The structure of NiZn-DO/LAC was characterized by BET, SEM and XRD, and the adsorption behavior of sulfathiazole (ST) in aqueous solution was also studied. The results showed that the NiZn-DO/LAC had evident obvious three-dimensional porous structure and stable crystal structure with a large specific surface area of 759.1m²/g. In the process of ST adsorption, the NiZn-Do/Lac showed excellent adsorption performance, with the maximum adsorption capacity up to 328.2mg/g, which was better than other reported adsorbents. Additionally, the ST was easily desorbed from NiZn-DO/LAC with NaOH solution and the analytical rate of NiZn-DO/LAC was still reach up to 79.43% after 4times of recycles. Furthermore, it showed that the adsorption behavior of ST over NiZn-DO/LAC was mainly through the synergistic effect of electrostatic interaction, π-π interaction, complexation, hydrophobic effects and hydrophobicity, resulting in a great improvement of adsorption performance.

Key words： alkali lignin activated carbon metallic oxide sulfathiazole synergy

Received: 08 January 2021

PACS:

X703.5

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	Articles by authors
	QIU Shi-jie
	LIANG Zu-xue
	HUA Jie
	LIU Yi-fan
	YE Xiao-xia
	LIU Ming-hua

Cite this article:

QIU Shi-jie,LIANG Zu-xue,HUA Jie等. Adsorption of sulfathiazole from aqueous solution by lignin-based activated carbon supported metallic oxide[J]. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(8): 3642-3652.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2021/V41/I8/3642

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