菱形片状铁锰催化剂活化过硫酸盐降解四环素

Abstract
Figure/Table
References
Related Citation (15)

Download: PDF (750 KB) HTML (0 KB)
Export: BibTeX | EndNote (RIS)

Abstract The first-attempt study used iron-manganese bimetallic catalyst derived from the Prussian blue analogues, and etched by the oxalic acid for activating peroxymonosulfate (PMS) to degrade tetracycline. According to thermogravimetric analyzer (TGA), X-ray diffraction (XRD), scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), the synthesized catalyst FeMn/OA-350 owned a special rhombic shape. Apparently, combined synergy of iron and manganese and abundant active sites on the sheet structure significantly augmented the oxidation performance of tetracycline. When catalyst dosage and PMS concentration were of 0.6g/L, and 2mmol/L, the removal rate of 20mg/L tetracycline was as high as 100% within only 30 min at neutral pH. The reaction process seemed to follow the second-order kinetics (R²>0.9). The free radical quenching experiments showed that hydroxyl radical, sulfate radical, singlet oxygen and superoxide radical existed in this system and singlet oxygen was the main functional group. X-ray Photoelectron Spectroscopy (XPS) data clearly exhibited the valence states of iron and manganese elements and the synergistic interactions between Fe and Mn. It was suggested that changes of different iron and manganese valence directly promoted the activation performance of the catalyst. Meanwhile, based on the quenching experiment, XPS and LC-MS analyses, the degradation process and mechanism were first proposed.

Key words： rhomboid sheet structure iron-manganese bimetallic catalyst peroxymonosulfate tetracycline

Received: 01 April 2021

PACS:

X703.5

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHU Zi-qi
	LI Li
	XU Ming-jun
	ZHANG Qian
	HONG Jun-ming

Cite this article:

ZHU Zi-qi,LI Li,XU Ming-jun等. Rhombic sheet iron-manganese catalyst-activating peroxymonosulfate for tetracycline degradation[J]. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(11): 5142-5152.

URL:

http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2021/V41/I11/5142

[1]	Lin Z, Zhen Z, Luo S W, et al. Effects of two ecological earthworm species on tetracycline degradation performance, pathway and bacterial community structure in laterite soil[J]. Journal of Hazardous Materials, 2021,412:125212.
[2]	Xu L Y, Zhang H, Xiong P, et al. Occurrence, fate, and risk assessment of typical tetracycline antibiotics in the aquatic environment:A review[J]. Science of the Total Environment, 2021,753:141975.
[3]	Wang A Q, Zheng Z K, Wang H, et al. 3D hierarchical H2-reduced Mn-doped CeO2 microflowers assembled from nanotubes as a high-performance Fenton-like photocatalyst for tetracycline antibiotics degradation[J]. Applied Catalysis B:Environmental, 2020,277:119171.
[4]	Li J, Xu M, Yao G, et al. Enhancement of the degradation of atrazine through CoFe2O4 activated peroxymonosulfate (PMS) process:Kinetic, degradation intermediates, and toxicity evaluation[J]. Chemical Engineering Journal, 2018,348:1012-1024.
[5]	Jawad A, Lang J, Liao Z, et al. Activation of persulfate by CuOx@Co-LDH:a novel heterogeneous system for contaminant degradation with broad pH window and controlled leaching[J]. Chemical Engineering Journal, 2018,335:548-559.
[6]	Du J K, Bao J G, Liu Y, et al. Facile preparation of porous Mn/Fe3O4cubes as peroxymonosulfate activating catalyst for effective bisphenol A degradation[J]. Chemical Engineering Journal, 2019,376:119193.
[7]	Dong Z Y, Zhang Q, Chen B Y, et al. Oxidation of bisphenol A by persulfate via Fe3O4-α-MnO2 nanoflower-like catalyst:Mechanism and efficiency-Science Direct[J]. Chemical Engineering Journal, 2019,357:337-347.
[8]	Duan P J, Qi Y F, Feng S S, et al. Enhanced degradation of clothianidin in peroxymonosulfate/catalyst system via core-shell FeMn@N-C and phosphate surrounding[J]. Applied Catalysis B:Environmental, 2020,267:118717.
[9]	李立,吴丽颖,董正玉,等.高晶度Mn-Fe LDH催化剂活化过一硫酸盐降解偶氮染料RBK5[J]. 环境科学, 2020,41(6):2736-2745.Li L, Wu L Y, Dong Z Y, et al. Degradation of RBK5 by high crystallinity Mn-Fe LDH catalyst activating peroxymonosulfate[J]. Environmental Science, 2020,41(6):2736-2745.
[10]	Hou M J, Gong S Q, Ji L L, et al. Three-dimensional porous ultrathin carbon networks reinforced PBAs-derived electrocatalysts for efficient oxygen evolution[J]. Chemical Engineering Journal, 2021,419:129575.
[11]	Liu C, Liu S Q, Liu L Y, et al. Novel carbon based Fe-Co oxides derived from Prussian blue analogues activating peroxymonosulfate:Refractory drugs degradation without metal leaching[J]. Chemical Engineering Journal, 2020,379:122274.
[12]	Chen X, Xue X, Gong X. A novel Z-scheme porous g-C3N4 nanosheet/Ag3PO4 photocatalyst decorated with N-doped CDs for high efficiency removal of antibiotics[J]. Dalton Transactions, 2020,49:5205-5218.
[13]	张坤,宋铁红,肖书虎,等.Ag-TiO2纳米管电极光电催化降解四环素的优化与分析[J]. 环境工程学报, 2016,10(9):4726-4732.Zhang K, Song T H, Xiao S H, et al. Optimization and analysis of Ag-TiO2 nanotube electrode for the degradation of tetracycline[J]. Chinese Journal of Environmental Engineering, 2016,10(9):4726-4732.
[14]	Cheng M, Liu Y, Huang D L, et al. Prussian blue analogue derived magnetic Cu-Fe oxide as a recyclable photo-Fenton catalyst for the efficient removal of sulfamethazine at near neutral pH values[J]. Chemical Engineering Journal, 2019,362:865-876.
[15]	Qiu X J, Yang S J, Mawuli Dzakpasu, et al. Attenuation of BPA degradation by SO4- in a system of peroxymonosulfate coupled with Mn/Fe MOF-templated catalysts and its synergism with Cl- and bicarbonate[J]. Chemical Engineering Journal, 2019,372:605-615.
[16]	Huang Z Y, Wu P X, Liu J, et al. Defect-rich carbon based bimetallic oxides with abundant oxygen vacancies as highly active catalysts for enhanced 4-aminobenzoic acid ethyl ester (ABEE) degradation toward peroxymonosulfate activation[J]. Chemical Engineering Journal, 2020,395:124936.
[17]	董正玉,吴丽颖,王霁,等.新型Fe3O4@α-MnO2活化过一硫酸盐降解水中偶氮染料[J]. 中国环境科学, 2018,38(8):3003-3010.Dong Z Y, Wu L Y, Wang J, et al. Novel Fe3O4@α-MnO2 activated peroxymonosulfate degradation of azo dyes in aqueous solution[J]. China Environmental Science, 2018,38(8):3003-3010.
[18]	Gu Y J, Sun S R, Liu Y Q, et al. Solvent effect on the solvothermal synthesis of mesoporous NiO catalysts for activation of peroxymonosulfate to degrade organic dyes[J]. ACS Omega, 2019, 4(18):17672-17683.
[19]	Tang W S, Su Y, Li Q, et al. Superparamagnetic magnesium ferrite nanoadsorbent for effective arsenic (III, V) removal and easy magnetic separation[J]. Water Research, 2013,47:3624-3634.
[20]	Zhang S W, Fan Q H, Gao H H, et al. Formation of Fe3O4@MnO2 ball-in-ball hollow spheres as a high performance catalyst with enhanced catalytic performances[J]. Journal of Materials Chemistry A, 2016,4:1414-1422.
[21]	Kou L D, Wang J, Zhao L, et al. Coupling of KMnO4- assisted sludge dewatering and pyrolysis to prepare Mn, Fe-codoped biochar catalysts for peroxymonosulfate-induced elimination of phenolic pollutants[J]. Chemical Engineering Journal, 2021,411:128459.
[22]	Liu L L, Mi H S, Zhang M, et al. Efficient moxifloxacin degradation by CoFe2O4 magnetic nanoparticles activated peroxymonosulfate:Kinetics, pathways and mechanisms[J]. Chemical Engineering Journal, 2021,407:127201.
[23]	Ahmad Jonidi Jafari, Babak Kakavandi, Nemat Jaafarzadeh, et al. Fenton-like catalytic oxidation of tetracycline by AC@Fe3O4 as a heterogeneous persulfate activator:Adsorption and degradation studies[J]. Journal of Industrial and Engineering Chemistry, 2017,45:323-333.
[24]	张元龙,魏琛,盛贵尚.BiFeO3可见光协同活化过硫酸盐降解四环素的研究[J]. 广州化学, 2020,45(6):30-35.Zhang Y L, Wei C, Sheng S G, et al. Degradation of tetracycline by BiFeO3 visible light activated persulfate[J]. Guangzhou Chemistry, 2020,45(6):30-35.
[25]	Li W, Wang Z M, Liao H Y, et al. Enhanced degradation of 2,4,6-trichlorophenol by activated peroxymonosulfate with sulfur doped copper manganese bimetallic oxides[J]. Chemical Engineering Journal, 2020,417:128121.
[26]	Guo Y X, Yan L G, Li X G, et al. Goethite/biochar-activated peroxymonosulfate enhances tetracycline degradation:Inherent roles of radical and non-radical processes[J]. Science of The Total Environment, 2021,783:147102.
[27]	Hu J, Dong H Y, Qu J H, et al. Enhanced degradation of iopamidol by peroxymonosulfate catalyzed by two pipe corrosion products (CuO and δ-MnO2)[J]. Water Research, 2017,112:1-8.
[28]	Li X G, Hou T L, Yan L G. et al. Efficient degradation of tetracycline by CoFeLa-layered double hydroxides catalyzed peroxymonosulfate:Synergistic effect of radical and nonradical pathways[J]. Journal of Hazardous Materials, 2020,398:122884.
[29]	王柯晴,徐劼,陈家斌,等.氧基氯化铁非均相活化过一硫酸盐降解金橙Ⅱ[J]. 中国环境科学, 2020,40(8):3385-3393.Wang K Q, Xu J, Chen J B, et al. Degradation of AO7 by PMS activated by Fe Ocl[J]. China Environmental Science, 2020,40(8):3385-3393.
[30]	Cao J Y, Lai L D, Lai B, et al. Degradation of tetracycline by peroxymonosulfate activated with zero-valent iron:Performance, intermediates, toxicity and mechanism[J]. Chemical Engineering Journal, 2019,364:45-56.
[31]	Bai R, Yan W F, Xiao Y, et al. Acceleration of peroxymonosulfate decomposition by a magnetic MoS2/CuFe2O4 heterogeneous catalyst for rapid degradation of fluoxetine[J]. Chemical Engineering Journal, 2020,397:125501.
[32]	Gao Y J, Zhao Q, Li Y H, et al. Degradation of sulfamethoxazole by peroxymonosulfate activated by waste eggshell supported Ag2O-Ag nano-particles[J]. Chemical Engineering Journal, 2021,405:126719.
[33]	Huang G X, Wang C Y, Yang C W, et al. Degradation of bisphenol A by peroxymonosulfate catalytically activated with Mn1.8Fe1.2O4 nanospheres:Synergism between Mn and Fe[J]. Environmental Science & Technology, 2017,51(21):12611-12618.
[34]	Ye J, Wang Y, Li Z G, et al. 2D confinement freestanding graphene oxide composite membranes with enriched oxygen vacancies for enhanced organic contaminants removal via peroxymonosulfate activation[J]. Journal of Hazardous Materials, 2021,417:126028.
[35]	Giovanni Cagnetta, Huang J, Mengnan Lu, et al. Defect engineered oxides for enhanced mechanochemical destruction of halogenated organic pollutants[J]. Chemosphere, 2017,184:879-883.
[36]	Liu F, Zhou H Y, Pan Z C, et al. Degradation of sulfamethoxazole by cobalt-nickel powder composite catalyst coupled with peroxymonosulfate:Performance, degradation pathways and mechanistic consideration[J]. Journal of Hazardous Materials, 2020,400:123322.
[37]	Zhao Z W, Zhao J H, Yang C. Efficient removal of ciprofloxacin by peroxymonosulfate/Mn3O4-MnO2 catalytic oxidation system[J]. Chemical Engineering Journal, 2017,327:481-489.
[38]	佘月城,董正玉,吴丽颖,等.MnFe2O4活化过一硫酸盐降解废水中LAS[J]. 中国环境科学, 2019,39(8):3323-3331.She Y C, Dong Z Y, Wu L Y, et al. Degradation of LAS in wastewater by peroxymonosulfate activated by MnFe2O4[J]. China Environmental Science, 2019,39(8):3323-3331.
[39]	Wu L Y, Zhang Q, Hong J M, et al. Degradation of bisphenol A by persulfate activation via oxygen vacancy-rich CoFe2O4-x[J]. Chemosphere, 2019,221:412-422.
[40]	Chen Z H, Wan Q Q, Wen G, et al. Effect of borate buffer on organics degradation with unactivated peroxymonosulfate:Influencing factors and mechanisms[J]. Separation and Purification Technology, 2021, 256:117841.
[41]	李文章,张莉,王圣瑞,等.洱海沉积物水提取态有机氮特征及与其他来源溶解性有机氮的差异[J]. 环境科学, 2017,38(7):2801-2809.Li W Z, Zhang L, Wang S R, et al. Characteristics of water extractable organic nitrogen from Erhai Lake sediment and its differences with other sources[J]. Environmental Science, 2017,38(7):2801-2809.
[42]	王翔,罗艳丽,邓雯文,等.新疆奎屯地区高砷地下水DOM三维荧光特征[J]. 中国环境科学, 2020,40(11):4974-4981.Wang X, Luo Y L, Deng W W, et al. The 3D-EEM characteristics of DOM in high arsenic groundwater of Kuitun, Xinjiang[J]. China Environmental Science, 2020,40(11):4974-4981.