聚烯丙基磺酸钠接枝空心玻璃微珠的制备及其吸附性能研究

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Abstract A noval hollow glass bead-based adsorbent (KNH-g-PSAS) was successfully fabricated by grafting sodium allyl sulfonate (SAS) and silane coupling agent onto the surface of hollow glass beads. KNH-g-PSAS was characterized by scanning electron microscope, energy dispersion spectroscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis and X-ray diffractometer, showing the successful grafting of SAS. In addition, the effects of pH value, reaction time, initial concentration and temperature on the adsorption of cationic dyes by KNH-g-PSAS were systematically studied. The pseudo-order kinetic model and Langmuir isotherm model fitted the kinetics and isotherm data well, indicating that the adsorption were determined by chemsorption and uniform monolayer adsorption. Adsorption experiment showed that the adsorption capacity of KNH-g-PSAS for basic fuchsin, auramine O, crystal violet and malachite green were 2247.19mg/g, 23174.61mg/g, 2557.54mg/g and 2808.98mg/g, respectively. In addition, KNH-g-PSAS had excellent self-floating performance and recovery performance.

Key words： dye adsorption graft copolymerization π-π stacking electrostatic interaction hydrogen bonding

Received: 02 April 2021

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X703

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	Articles by authors
	ZHENG Huai-li
	LIU Wang-qing
	AN Yan-yan
	CHEN Wei
	SUN Qiang
	WAN Xin-yuan
	ZHAO Rui

Cite this article:

ZHENG Huai-li,LIU Wang-qing,AN Yan-yan等. Synthesis of polyallyl sodium sulfonate grafted hollow glass microbeads and its adsorption properties research[J]. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(11): 5177-5186.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2021/V41/I11/5177

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