炼化常减压装置挥发性有机物无组织源谱分析

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Abstract The fugitive volatile organic compounds (VOCs) emitted from the process pipelines in typical atmospheric and vacuum distillation units were investigated to specify the characteristics of the fugitive emission source spectrum in the refining and chemical industry. The US EPA bagging and sampling method-standard was adopted for the sampling of VOCs, and the gaseous VOCs samples were then transferred to the combined three adsorption tubes according to the HJ 644-2013 standard. In the sequence, the gas chromatography-mass spectrometer was used for quantitative analysis of VOCs. The results showed that the unorganized VOCs emitted by atmospheric and vacuum distillation units contained 116 substances, dominated by alkanes, alkenes, aldehydes and ketones, in which alkanes accounted for more than 65% of the emissions total. Moreover, the quantitative analysis of detected substances indicated that the fugitive emission factors of VOCs in atmospheric and vacuum distillation units were mainly 2-methylbutane, butene, benzene, etc. The trace amounts of naphthalene had also been detected. These results can provide strong support for the construction of VOCs emission inventory in the refining and chemical enterprises, presenting a promising tool for the subsequent refined management of VOCs.

Key words： volatile organic compounds (VOCs) atmospheric and vacuum distillation unit fugitive emissions bagging method sampling source spectrometry

Received: 10 May 2021

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X511

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	GAO Wen-xiu
	XIE Hui
	WANG Wen-li
	HAN Yuan
	HAN Ya-jiao

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GAO Wen-xiu,XIE Hui,WANG Wen-li等. Unorganized source spectrum analysis of volatile organic compounds (VOCs) in atmospheric and vacuum unit of refining-chemical plant[J]. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(12): 5561-5569.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2021/V41/I12/5561

[1]	Zhang Q, Zheng Y X, Tong D, et al. Drivers of improved PM2.5 air quality in China from 2013 to 2017[J]. Proceedings of the National Academy of Sciences of the United States of America, 2019,116(49): 24463-24469.
[2]	Kumar A, Singh D, Kumar K, et al. Distribution of VOCs in urban and rural atmospheres of subtropical India: Temporal variation, source attribution, ratios, OFP and risk assessment[J]. Science of the Total Environment, 2017,613-614:492-501.
[3]	Li K, Jacob D J, Liao H, et al. Anthropogenic drivers of 2013~2017 trends in summer surface ozone in China[J]. Proceedings of the National Academy of Sciences of the United States of America, 2019,116(2):422-427.
[4]	Xu W Y, Kuang Y, Bian Y X, et al. Current challenges in visibility improvement in southern China[J]. Environmental Science & Technology Letters, 2020,7(6):395-401.
[5]	吕兆丰,魏巍,杨干,等.VOCs排放源强反演研究[J]. 中国环境科学, 2015,35(10):2958-2963. Lu Z F, Wei W, Yang G, et al. Inversion research in VOCs source emission of a petroleum refinery[J]. China Environmental Science, 2015,35(10):2958-2963.
[6]	Wu R R, Xie S D. Spatial distribution of ozone formation in China derived from emissions of speciated volatile organic compounds[J]. Environmental Science & Technology, 2017,51(5):2574-2583.
[7]	王红丽,杨肇勋,景盛翱.工艺过程源和溶剂使用源挥发性有机物排放成分谱研究进展[J]. 环境科学, 2017,38(6):2617-2628. Wang H L, Yang Z X, Jing S A, et al. Volatile organic compounds (VOCs) source profiles of industrial processing and solvent use emissions: A review[J]. Environmental Science, 2017,38(6):2617-2628.
[8]	何梦林,肖海麟,陈小方,等.化工园区基于排放环节的VOCs排放特征研究[J]. 中国环境科学, 2017,37(1):38-48. He M L, Xiao H L, Chen X F, et al. Emission characteristics of volatileorganic compounds in chemical industry park based on emission links[J]. China Environmental Science, 2017,37(1):38-48.
[9]	王刚,魏巍,米同清,等.典型工业无组织源VOCs排放特征[J]. 中国环境科学, 2015,35(7):1957-1964. Wang G, Wei W, Mi T Q, et al. Characteristics of VOCs emitted from typical industrial fugitive[J]. China Environmental Science, 2015, 35(7):1957-1964.
[10]	谢添,杨文,郭婷,等.化工行业挥发性有机物无组织排放特征研究——以天津化工企业为例[J]. 南开大学学报(自然科学版), 2017,50(3):79-83. Xie T, Yang W, Guo T, et al. Study on the characteristics of unorganized emissions of volatile organic compounds in chemical industry-Taking Tianjin chemical enterprises as an example[J]. Acta Scientiarum Naturalium Universitatis Nankaiensis, 2017,50(3):79-83.
[11]	盛涛,陈筱佳,高松,等.上海某石化园区周边区域VOCs污染特征及健康风险[J]. 环境科学, 2018,39(11):4901-4908. Sheng T, Chen X J, Gao S, et al. Pollution characteristics and health risk assessment of VOCs in areas surrounding a petrochemical park in Shanghai[J]. Environmental Science, 2018,39(11):4901-4908.
[12]	毛瑶,李刚,胡天鹏,等.某典型石油化工园区冬季大气中VOCs污染特征[J]. 环境科学, 2018,39(2):525-532. Mao Y, Li G, Hu T P, et al. Characteristics of VOCs pollution in the winter atmosphere of a typical petrochemical industry park[J]. Environmental Science, 2018,39(2):525-532.
[13]	胡天鹏,李刚,毛瑶,等.某石油化工园区秋季VOCs污染特征及来源解析[J]. 环境科学, 2018,39(2):517-524. Hu T P, Li G, Mao Y, et al. Characteristics and source apportionment of VOCs of a petrochemical industrial park during autumn in China[J]. Environmental Science, 2018,39(2):517-524.
[14]	虎啸宇,刘航,王乃玉,等.秦皇岛市工业行业挥发性有机物排放特征[J]. 环境科学, 2018,39(2):543-550. Hu X Y, Liu H, Wang N Y, et al. Industrial VOCs emission in Qinhuangdao[J]. Environmental Science, 2018,39(2):543-550.
[15]	吴丽萍,欧盛菊,殷宝辉,等.新疆维吾尔自治区石化企业典型工艺无组织VOCs排放特征及光化学反应活性[J]. 环境科学研究, 2018, 31(12):2103-2111. Wu L P, Ou S J, Yin B H, et al. Emission characteristics and photochemical reaction activity of VOCs in the non-organized emission of typical processes of the petrochemical enterprise in Xinjiang Uygur Autonomous Region[J]. Research of Environmental Sciences, 2018,31 (12):2103-2111.
[16]	武蕾丹,王秀艳,杨文,等.某工业园区VOCs臭氧生成潜势及优控物种[J]. 环境科学, 2018,39(2):511-516. Wu L D, Wang X Y, Yang W, et al. Ozone formation potential and priority species of VOCs in an industrial park[J]. Environmental Science, 2018,39(2):511-516.
[17]	张桂芹,李思遠,潘光,等.化工企业优控VOCs污染物分析及生成机理[J]. 中国环境科学, 2019,39(4):1380-1389. Zhang G Q, Li S Y, Pan G, et al. Analysis and generation mechanism of optimal control of VOCs pollutants in chemical enterprises[J]. China Environmental Science, 2019,39(4):1380-1389.
[18]	Chen C H, Chuang Y C, Hsieh C C, et al. VOC characteristics and source apportionment at a PAMS site near an industrial complex in central Taiwan[J]. Atmospheric Pollution Research, 2019,10(4):1060-1074.
[19]	景盛翱,王红丽,朱海林,等.典型工业源VOCs治理现状及排放组成特征[J]. 环境科学, 2018,39(7):3090-3095. Jing S A, Wang H L, Zhu H L, et al. Treatment status and emission characteristics of volatile organic compounds from typical industrial sources[J]. Environmental Science, 2018,39(7):3090-3095.
[20]	Nicholas P. Cheremisinoff. Pollution control handbook for oil and gas engineering[M]. New York: Wiley-Scrivener, 2016:1-1332.
[21]	闵健,腾东玉,王云,等.密封点挥发性有机物(VOCs)排放速率的数值模拟及实测应用[J]. 化工进展, 2020,39(7):2599-2605. Min J, Teng D Y, Wang Y, et al. Numerical simulation and practical application of VOCs emission rate at sealing point[J]. Chemical Industry and Engineering Progress, 2020,39(7):2599-2605.
[22]	高洁,张春林,王伯光,等.基于包扎法的石化乙烯装置挥发性有机物排放特征[J]. 中国环境科学, 2016,36(3):694-701. Gao J F, Zhang C L, Wang B G, et al. Emission characteristics of volatile organic compounds emitted from an ethylene process unit in petrochemical industry based on blow-through method[J]. China Environmental Science, 2016,36(3):694-701.
[23]	HJ 644—2013 环境空气挥发性有机物的测定吸附管采样-热脱附/气相色谱-质谱法[S]. HJ 644—2013 Determination of ambient air volatile organic compounds adsorption tube sampling-thermal desorption/gas chromatography- mass spectrometry[S].
[24]	HJ 734—2014 固定污染源废气挥发性有机物的测定固相吸附-热脱附/气相色谱-质谱法[S]. HJ 734—2014 Fixed pollution source waste gas determination of volatile organic compounds solid phase adsorption-thermal desorption /gas chromatography-mass spectrometry[S].
[25]	EPA/625/R-96/010b Method TO-15Determination of volatile organic compounds (VOCs) in air collected in specially-prepared canisters and analyzed by gas chromatography/mass spectrometry (GC/MS)[S].
[26]	Mo Z W, Shao M, Lu S H, et al. Process-specific emission characteristics of volatile organic compounds (VOCs) from petrochemical facilities in the Yangtze River Delta, China[J]. Science of the Total Environment, 2015,533:422-431.
[27]	Wei W, Cheng S Y, Li G H, et al, Characteristics of volatile organic compounds (VOCs) emitted from a petroleum refinery in Beijing, China[J]. Atmospheric Environment, 2014,89:358-366.
[28]	Liu Y, Shao M, Fu L L, et al. Source profiles of volatile organic compounds (VOCs) measured in China: Part I[J]. Atmospheric Environment, 2008,42(25):6247-60.
[29]	陈小方,张嘉妮,张伟霞,等.化工园区挥发性有机物排放清单及其环境影响[J]. 中国环境科学, 2017,37(11):4062-4071. Chen X F, Zhang J N, Zhang W X, et al. VOCs emission inventory of a chemical industry park and its influence on atmospheric environment.[J]. China Environmental Science, 2017,37(11):4062-4071.
[30]	Liu H, Wu B, Liu S, et al. A regional high-resolution emission inventory of primary air pollutants in 2012 for Beijing and the surrounding five provinces of North China[J]. Atmospheric Environment, 2018,181:20-33.
[31]	王红丽,高雅琴,景盛翱,等.基于走航监测的长三角工业园区周边大气挥发性有机物污染特征[J]. 环境科学, 2021,42(3):1298-1305. Wang H L, Gao Y Q, Jing S A, et al. Characterization of VOCs Using Mobile Monitoring Around the Industrial Parks in the Yangzte River Delta Region of China[J]. Environmental Science, 2021,42(3):1298-1305.
[32]	黄鹤雯,沙青娥,朱曼妮,等.珠三角2010~2017年主要工业源VOCs排放结构与组分变化[J]. 中国环境科学, 2020,40(11):4641-4651. Huang H W, Sha Q E, Zhu M N, et al. Evolution of emission characteristics and species of industrial VOCs emission in Pearl River Delta Region, 2010~2017[J]. China Environmental Science, 2020, 40(11):4641-4651.
[33]	李勤勤,张志娟,李杨,等.石油炼化无组织VOCs的排放特征及臭氧生成潜力分析[J]. 中国环境科学, 2016,36(5):1323-1331. Li Q Q, Zhang Z J, Li Y, et al. Characteristics and ozone formation potential of fugitive VOCs emitted from petrochemical industry in Pearl River Delta[J]. China Environmental Science, 2016,36(5):1323-1331.
[34]	张渊钰,王新明,刘晓玲,等.新疆独山子区VOCs组成及其对O3和SOA的贡献[J]. 中国环境科学, 2020,40(5):1915-1923. Zhang Y Y, Wang X M, Liu X L, et al. VOCs in Dushanzi, Xinjiang Compositions and contributions to the formation of O3 and SOA.[J]. China Environmental Science, 2020,40(5):1915-1923.
[35]	孙佳宁,谢绍东.基于环境空气中VOCs在线监测数据精准识别化工园区VOCs排放源[J]. 环境科学, 2020,41(11):4874-4884. Sun J N, Xie S D. Accurate identification of ambient VOCs emission sources in an industrial park using on-line monitoring data[J]. Environmental Science, 2020,41(11):4874-4884.