β-PbO<sub>2</sub>和BDD电极处理印染反渗透浓水性能

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Abstract Two electrode systems of β-PbO₂/Ti-Ti and BDD/Si-Ti were systematically compared for the performance in treating reverse osmosis concentrate (ROC) from a real printing and dyeing industry. Kinetics of simultaneous remove chemical oxygen demand (COD) and total nitrogen (TN), as well as the improvement of the biochemical properties of the effluent were also investigated. It is shown that the BDD/Si-Ti electrode system has a high anodic oxygen evolution reaction (OER) potential (2.45V) and chlorine evolution reaction (CER) potential (1.90V), and the absolute values of anodic oxidation potential and cathodic reduction potential are higher than those of the β-PbO₂/Ti-Ti electrode system; the degradation of COD and TN followed pseudo-first-order kinetics. The BDD/Si-Ti electrode system is more effective in COD removal and current efficiency while the β-PbO₂/Ti-Ti electrode system is more effective in TN removal. Electrolysis at a low current density (5mA/cm²) for 15min resulted in a rise in BOD/COD from 0.18 to 0.42 (a 1.33-fold enhancement) for the ROC for the β-PbO₂/Ti-Ti electrode system, while the BDD/Si-Ti electrode system only showed a 0.78-fold enhancement. As a result, the BDD/Si-Ti electrode system is suitable for pollutant mineralization, and the β-PbO₂/Ti-Ti system is more suitable for the improvement of wastewater biochemical properties.

Key words： reverse osmosis concentrate electrochemistry printing & dyeing wastewater kinetics

Received: 01 November 2021

PACS:

X703.1

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	Articles by authors
	LIU Zi-feng
	ZHENG Rui-hao
	ZHOU Qing-qing
	WANG Jia-de
	SHI Xue-ru

Cite this article:

LIU Zi-feng,ZHENG Rui-hao,ZHOU Qing-qing等. Performance comparison of β-PbO₂ and BDD electrodes for treating reverse osmosis concentrate in printing and dyeing industry[J]. CHINA ENVIRONMENTAL SCIENCECE, 2022, 42(6): 2671-2679.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2022/V42/I6/2671

[1]	Joo S H, Tansel B. Novel technologies for reverse osmosis concentrate treatment:A review[J]. Journal of Environmental Management, 2015, 150:322-335.
[2]	Weng J, Jia H, Wu B, et al. Is ozonation environmentally benign for reverse osmosis concentrate treatment?Four-level analysis on toxicity reduction based on organic matter fractionation[J]. Chemosphere, 2018,191:971-978.
[3]	Lin X H, Li S F Y. Impact of the spatial distribution of sulfate species on the activities of SO42−/TiO2 photocatalysts for the degradation of organic pollutants in reverse osmosis concentrate[J]. Applied Catalysis B:Environmental, 2015,170-171:263-272.
[4]	Barreto-Rodrigues M, Silva F T, Paiva T C B. Combined zero-valent iron and fenton processes for the treatment of Brazilian TNT industry wastewater[J]. Journal of Hazardous materials, 2009,165(1):1224-1228.
[5]	Chen M, Pan S, Zhang C, et al. Electrochemical oxidation of reverse osmosis concentrates using enhanced TiO2-NTA/SnO2-Sb anodes with/without PbO2 layer[J]. Chemical Engineering Journal, 2020, 399:125756.
[6]	Radjenovic J, Bagastyo A, Rozendal R A, et al. Electrochemical oxidation of trace organic contaminants in reverse osmosis concentrate using RuO2/IrO2-coated titanium anodes[J]. Water Research, 2011, 45(4):1579-1586.
[7]	李金城,宋永辉,汤洁莉.电化学氧化法去除兰炭废水中COD和NH3-N[J].中国环境科学, 2022,42(2):697-705.Li J C, Song Y H, Tang J L Removing of COD and NH3-N from blue-coke wastewater by electrochemical oxidation[J]. China Environmental Science, 2022,42(2):697-705.
[8]	Onn S W, Bashir M J K, Sethupathi S, et al. Colour and COD removal from mature landfill leachate using electro-persulphate oxidation process[J]. Materials Today:Proceedings, 2020,31:69-74.
[9]	Olvera-Vargas H, Gore-Datar N, Garcia-Rodriguez O, et al. Electro-Fenton treatment of real pharmaceutical wastewater paired with a BDD anode:Reaction mechanisms and respective contribution of homogeneous and heterogeneous OH[J]. Chemical Engineering Journal, 2021,404:126524.
[10]	Pereira G F, Rocha-Filho R C, Bocchi N, et al. Electrochemical degradation of the herbicide picloram using a filter-press flow reactor with a boron-doped diamond or β-PbO2 anode[J]. Electrochimica Acta, 2015,179:588-598.
[11]	Garcia-Segura S, Ocon J D, Chong M N. Electrochemical oxidation remediation of real wastewater effluents-A review[J]. Process Safety and Environmental Protection, 2018,113:48-67.
[12]	Zhou X, Wang s, Ma C, et al. Effect of Ag Content and β-PbO2 Plating on the Properties of Al/Pb-Ag Alloy[J]. Rare Metal Materials and Engineering, 2018,47(7):1999-2004.
[13]	Sirés I, Low C T J, Ponce-de-León C, et al. The characterisation of PbO2-coated electrodes prepared from aqueous methanesulfonic acid under controlled deposition conditions[J]. Electrochimica Acta, 2010,55(6):2163-2172.
[14]	Abaci S, Yildiz A. Electropolymerization of thiophene and 3-methylthiophene on PbO2 electrodes[J]. Journal of Electroanalytical Chemistry, 2004,569(2):161-168.
[15]	Zhou X, Zhou Q, Chen H, et al. Influence of dimethylphenol isomers on electrochemical degradation:Kinetics, intermediates, and DFT calculation[J]. Science of The Total Environment, 2021,794:148284.
[16]	Pérez G, Saiz J, Ibañez R, et al. Assessment of the formation of inorganic oxidation by-products during the electrocatalytic treatment of ammonium from landfill leachates[J]. Water Research, 2012,46(8):2579-2590.
[17]	Panizza M, Kapalka A, Comninellis C. Oxidation of organic pollutants on BDD anodes using modulated current electrolysis[J]. Electrochimica Acta, 2008,53(5):2289-2295.
[18]	He Y, Huang W, Chen R, et al. Anodic oxidation of aspirin on PbO2, BDD and porous Ti/BDD electrodes:Mechanism, kinetics and utilization rate[J]. Separation and Purification Technology, 2015,156:124-131.
[19]	Panizza M, Cerisola G. Application of diamond electrodes to electrochemical processes[J]. Electrochimica Acta, 2005,51(2):191-199.
[20]	Martı́nez-Huitle C A, Ferro S, De Battisti A. Electrochemical incineration of oxalic acid:Role of electrode material[J]. Electrochimica Acta, 2004,49(22):4027-4034.
[21]	Li A, Weng J, Yan X, et al. Electrochemical oxidation of acid orange 74using Ru, IrO2, PbO2, and boron doped diamond anodes:Direct and indirect oxidation[J]. Journal of Electroanalytical Chemistry, 2021, 898:115622.
[22]	Santos J E L, de Moura D C, Cerro-López M, et al. Electro-and photo-electrooxidation of 2,4,5-trichlorophenoxiacetic acid (2,4,5-T) in aqueous media with PbO2, Sb-doped SnO2, BDD and TiO2-NTs anodes:A comparative study[J]. Journal of Electroanalytical Chemistry, 2020,873:114438.
[23]	Xing X, Ni J, Zhu X, et al. Maximization of current efficiency for organic pollutants oxidation at BDD, Ti/SnO2-Sb/PbO2, and Ti/SnO2-Sb anodes[J]. Chemosphere, 2018,205:361-368.
[24]	邓冬莉,吴明珠,李应,等.电催化氧化处理邻苯二甲酸酯类物质阳极材料的研究进展[J].化工新型材料, 2021,49(4):267-271.Deng D L, Wu M Z, LI Y. Advance on anode material for electrocatalytic oxidation of phthalate ester[J]. New Chemical Materials, 2021,49(4):267-271.
[25]	Song S, Fan J, He Z, et al. Electrochemical degradation of azo dye C.I. Reactive Red 195by anodic oxidation on Ti/SnO2-Sb/PbO2 electrodes[J]. Electrochimica Acta, 2010,55(11):3606-3613.
[26]	叶志平,周丹飞,刘梓锋,等.对甲基苯磺酸在Ti/PbO2电极上的电氧化反应信息.[J].化工学报, 2021,72(5):2810-2816.Ye Z P, Zhou D F, Liu Z F, et al Electro-oxidation information of p-toluene sulfonic acid on Ti/PbO2 electrode[J]. CIESC Journal, 2021,72(5):2810-2816.
[27]	Zhang C, Lu X, Lu Y, et al. Titaniumboron doped diamond composite:A new anode material[J]. Diamond and Related Materials, 2019,98:107490.
[28]	Santos J E L, Gómez M A, Moura D C d, et al. Removal of herbicide 1-chloro-2,4-dinitrobenzene (DNCB) from aqueous solutions by electrochemical oxidation using boron-doped diamond (BDD) and PbO2 electrodes[J]. Journal of Hazardous materials, 2021,402:123850.
[29]	Chen X, Gao F, Chen G. Comparison of Ti/BDD and Ti/SnO2-Sb2O5 electrodes for pollutant oxidation[J]. Journal of Applied Electrochemistry, 2005,35(2):185-191.
[30]	Sun J, Lu H, Du L, et al. Anodic oxidation of anthraquinone dye Alizarin Red S at Ti/BDD electrodes[J]. Applied Surface Science, 2011,257(15):6667-6671.
[31]	Deborde M, von Gunten U. Reactions of chlorine with inorganic and organic compounds during water treatment-Kinetics and mechanisms:A critical review[J]. Water Research, 2008,42(1):13-51.
[32]	Zhou Q, Zhou X, Zheng R, et al. Application of lead oxide electrodes in wastewater treatment:A review[J]. Science of The Total Environment, 2022,806:150088.
[33]	Huang Y K, Li S, Wang C, et al. Simultaneous removal of COD and NH3-N in secondary effluent of high-salinity industrial waste-water by electrochemical oxidation[J]. Journal of Chemical Technology and Biotechnology, 2012,87(1):130-136.
[34]	Labiadh L, Barbucci A, Carpanese M P, et al. Comparative depollution of Methyl Orange aqueous solutions by electrochemical incineration using TiRuSnO2, BDD and PbO2 as high oxidation power anodes[J]. Journal of Electroanalytical Chemistry, 2016,766:94-99.
[35]	Santos J E L, Antonio Quiroz M, Cerro-Lopez M, et al. Evidence for the electrochemical production of persulfate at TiO2 nanotubes decorated with PbO2[J]. New Journal of Chemistry, 2018,42(7):5523-5531.
[36]	Zaidi S Z J, Harito C, Walsh F C, et al. Decolourisation of reactive black-5at an RVC substrate decorated with PbO2/TiO2 nanosheets prepared by anodic electrodeposition[J]. Journal of Solid State Electronics, 2018:1-12.
[37]	Kuang P, Natsui K, Einaga Y, et al. Annealing enhancement in stability and performance of copper modified boron-doped diamond (Cu-BDD) electrode for electrochemical nitrate reduction[J]. Diamond and Related Materials, 2021,114:108310.
[38]	Kapałka A, Joss L, AngladaÁ, et al. Direct and mediated electrochemical oxidation of ammonia on boron-doped diamond electrode[J]. Electrochemistry Communications, 2010,12(12):1714-1717.
[39]	Yao J, Mei Y, Yuan T, et al. Electrochemical removal of nitrate from wastewater with a Ti cathode and Pt anode for high efficiency and N2selectivity[J]. Journal of Electroanalytical Chemistry, 2021,882:115019.
[40]	Su L, Li K, Zhang H, et al. Electrochemical nitrate reduction by using a novel Co3O4/Ti cathode[J]. Water Research, 2017,120:1-11.
[41]	Kokabian B, Bonakdarpour B, Fazel S. The effect of salt on the performance and characteristics of a combined anaerobic-aerobic biological process for the treatment of synthetic wastewaters containing Reactive Black 5[J]. Chemical Engineering Journal, 2013, 221:363-372.
[42]	Abou-Elela S I, Kamel M M, Fawzy M E. Biological treatment of saline wastewater using a salt-tolerant microorganism[J]. Desalination, 2010,250(1):1-5.
[43]	Asaithambi P, Sajjadi B, Abdul Aziz A R, et al. Ozone (O3) and sono (US) based advanced oxidation processes for the removal of color, COD and determination of electrical energy from landfill leachate[J]. Separation and Purification Technology, 2017,172:442-449.
[44]	Daneshvar N, Aleboyeh A, Khataee A R. The evaluation of electrical energy per order (EEo) for photooxidative decolorization of four textile dye solutions by the kinetic model[J]. Chemosphere, 2005, 59(6):761-767.
[45]	Long Y, Li H, Jin H, et al. Interpretation of high perchlorate generated during electrochemical disinfection in presence of chloride at BDD anodes[J]. Chemosphere, 2021,284:131418.
[46]	He Y, Zhu Y, Chen J, et al. Assessment of energy consumption of municipal wastewater treatment plants in China[J]. Journal of Cleaner Production, 2019,228:399-404.
[47]	Yao J, Pan B, Shen R, et al. Differential control of anode/cathode potentials of paired electrolysis for simultaneous removal of chemical oxygen demand and total nitrogen[J]. Science of The Total Environment, 2019,687:198-205.