基于OMI的汾渭平原对流层NO<sub>2</sub>长期变化趋势

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Abstract This study explored the long-term trends of NO₂ tropospheric vertical column density (NO₂ TVCD) and its responses to NO_x emissions, as well as their impacts on the lower tropospheric O₃ over the Fenwei Plain of China. The long-term observations from 2007 to 2020 used here consist of:NO₂ TVCD data of Ozone Monitoring Instrument (OMI) OMNO2d, NO_x emissions of European Quality Assurance for Essential Climate Variables project (QA4ECV) products by Daily Emission estimation Constrained by Satellite Observations (DECSO) algorithm, and ozone (O₃) vertical profile data of Atmospheric Infrared Sounder instrument (AIRS) AIRS2SUP. The results showed that:(1) NO₂ TVCD peaked at (9.8±4.6)×10¹⁵molec/cm² in 2012, then tended to decline generally after 2013; (2) NO₂ TVCD was higher by 260% in winter than in summer; (3) The variations in NO₂ TVCD were not exactly consistent with the anthropogenic mitigation of NO_x emissions but increased in Summer at its lower percentiles with a rate of (-1.5±0.6)%/a (less than a third of the reduction in NO_x emissions), which was probably due to the large contribution of natural sources of tropospheric NO_x and its increasing relative contribution under the background of massive anthropogenic NO_x emissions mitigation; (4) The O₃ variability was (-0.2±0.2)%/a in the middle-lower troposphere and (0.8±0.1)%/a in the near surface, indicating that the tropospheric O₃ generation in the Fenwei Plain was basically within the VOCs-limited or VOCs-NO_x transitional regimes, and the anthropogenic NO_x emissions reduction could not reduce the tropospheric O₃; (5) The anthropogenic NO_x emission reduction could effectively reduce NO₂ in urban high emission areas, but in the rural areas where natural NO_x sources dominated. Generally, the efficiency of the anthropogenic NO_x emissions reduction was not significant over the Fenwei Plain.

Key words： Fenwei Plain OMI tropospheric NO₂ pollution characteristics

Received: 31 January 2022

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X511

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	CHEN Ling
	YAN Shi-ming
	NI Cheng-cheng
	ZHU Ling-yun
	XIAO Hui
	WANG Yan
	WANG Wen-ya
	HE Jie-ying
	GUO Wei

Cite this article:

CHEN Ling,YAN Shi-ming,NI Cheng-cheng等. Long-term trends of tropospheric NO₂ over the Fenwei Plain of China based on OMI data[J]. CHINA ENVIRONMENTAL SCIENCECE, 2022, 42(8): 3492-3501.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2022/V42/I8/3492

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