|
|
Research progress of nano zero-valentiron coupling clay for remediation of polluted soil |
HU Pei-wei1,2, GAO Run-qin1, DAI Yan-ni1, ZHANG Yan1, YANG Wen-zhao1 |
1. College of Resources and Environment Engineering, Wuhan University of Science and Technology, Wuhan 430081, China; 2. Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan 430081, China |
|
|
Abstract Clay-supported nZVI possess excellent comprehensive performance, such as low cost, easy preparation and environmental compatibility. On the basis of summarizing the modification strategies of nZVI, the effects of clay types on the morphology and properties of nZVI are compared. This paper poses the optimal order of ideal clay carrier, analyses the relationship between the iron content, specific surface area, nZVI size and the removal performance. The application of nZVI coupling clay for soil remediation, such as heavy metals, halogenated organics, nitrates, new pollutants in soil are reviewed, and the negative effects of nZVI technology in soil remediation are also summarized. Finally, the paper prospects the future direction of nZVI coupled clay technology and its mineral materials for remediation of polluted soil.
|
Received: 28 March 2022
|
|
|
|
|
[1] |
Wang J L,Bai Z Y.Fe-based catalysts for heterogeneous catalytic ozonation of emerging contaminants in water and wastewater[J].Chemical Engineering Journal, 2017,312:79-98.
|
[2] |
Li Y R, Zhao H P, Zhu L Z.Remediation of soil contaminated with organic compounds by nanoscale zero-valent iron:A review[J].Science of The Total Environment, 2021,760:143413.
|
[3] |
Sang L,Wang G H,Liu L, et al.Immobilization of Ni (II) at three levels of contaminated soil by rhamnolipids modified nano zero valent iron (RL@nZVI):Effects and mechanisms[J].Chemosphere, 2021,276:130139.
|
[4] |
Fu F L, Dionysiou D D, Liu H.The use of zero-valent iron for groundwater remediation and wastewater treatment:A review[J].Journal of Hazardous Materials, 2014,267:194-205.
|
[5] |
Mukherjee R,Kumar R,Sinha A, et al.A review on synthesis, characterization, and applications of nano zero valent iron (nZVI) for environmental remediation[J].Critical Reviews in Environmental Science and Technology, 2016,46(5):443-466.
|
[6] |
Stefaniuk M, Oleszczuk P, Ok Y S.Review on nano zerovalent iron (nZVI):From synthesis to environmental applications[J].Chemical Engineering Journal, 2016,287:618-632.
|
[7] |
Hu P W,Yang H M.Insight into the physicochemical aspects of kaolins with different morphologies[J].Applied Clay Science, 2013,74(1):58-65.
|
[8] |
Ezzatahmadi N,Ayoko G A,Millar G J, et al.Clay-supported nanoscale zero-valent iron composite materials for the remediation of contaminated aqueous solutions:A review[J].Chemical Engineering Journal, 2017,312:336-350.
|
[9] |
Habish A J,Lazarević S,Janković-Častvan I, et al.Nanoscale zerovalent iron (nZVI) supported by natural and acid-activated sepiolites:the effect of the nZVI/support ratio on the composite properties and Cd2+ adsorption[J].Environmental Science and Pollution Research, 2017,24(1):628-643.
|
[10] |
Zhu F,Li L W,Ma S Y, et al.Effect factors, kinetics and thermodynamics of remediation in the chromium contaminated soils by nanoscale zero valent Fe/Cu bimetallic particles[J].Chemical Engineering Journal, 2016,302:663-669.
|
[11] |
Tran M L,Nguyen C H,Tran T T V, et al.One-pot synthesis of bimetallic Pt/nZVI nanocomposites for enhanced removal of oxytetracycline:Roles of morphology changes and Pt catalysis[J].Journal of the Taiwan Institute of Chemical Engineers, 2020,111:130-140.
|
[12] |
Su M,Yin W Z,Liu L, et al.Enhanced Cr(VI) stabilization in soil by carboxymethyl cellulose-stabilized nanosized Fe0 (CMC-nFe0) and mixed anaerobic microorganisms[J].Journal of Environmental Management, 2020,257:109951.
|
[13] |
Gong K D,Hu Q,Xiao Y Y, et al.Triple layered core-shell ZVI@carbon@polyaniline composite enhanced electron utilization in Cr (VI) reduction[J].Journal of Materials Chemistry A, 2018,6(24):11119-11128.
|
[14] |
Garcia A N,Boparai H K,Boer C V d, et al.Fate and transport of sulfidated nano zerovalent iron (S-nZVI):A field study[J].Water Research, 2020,170:115319.
|
[15] |
Pang H W,Liu L J,Bai Z, et al.Fabrication of sulfide nanoscale zero-valent iron and heterogeneous Fenton-like degradation of 2,4-Dichlorophenol[J].Separation and Purification Technology, 2022,285:120408.
|
[16] |
Gao R Q, Hu P W, Dai Y N, et al.Removal of cadmium(II) from aqueous solutions by a novel sulfide-modified nanoscale zero-valent iron supported on kaolinite:Treatment efficiency, kinetics and mechanisms[J].Applied Surface Science, 2022,602:154353.
|
[17] |
Li X G,Zhao Y,Xi B D, et al.Removal of nitrobenzene by immobilized nanoscale zero-valent iron:Effect of clay support and efficiency optimization[J].Applied Surface Science, 2016,370:260-269.
|
[18] |
Wang S S,Zhao M Y,Zhou M, et al.Biochar-supported nZVI (nZVI/BC) for contaminant removal from soil and water:A critical review[J].Journal of Hazardous Materials, 2019,373:820-834.
|
[19] |
Zhu F,He S Y,Liu T.Effect of pH, temperature and co-existing anions on the Removal of Cr(VI) in groundwater by green synthesized nZVI/Ni[J].Ecotoxicology and Environmental Safety, 2018,163:544-550.
|
[20] |
Jia Y T,Hu F,Lv Y C, et al.Biomineralization of 2'2'4'4'-Tetrabromodiphenyl ether in a Pseudomonas putida and Fe/Pd nanoparticles integrated system[J].Chemosphere, 2019,221:301-313.
|
[21] |
Chen L S,Ni R,Yuan T J, et al.Effects of green synthesis, magnetization, and regeneration on ciprofloxacin removal by bimetallic nZVI/Cu composites and insights of degradation mechanism[J].Journal of Hazardous Materials, 2020,382:121008.
|
[22] |
Kumari B, Dutta S.Integrating starch encapsulated nanoscale zero-valent iron for better chromium removal performance[J].Journal of Water Process Engineering, 2020,37:101370.
|
[23] |
Sewwandi K A H S, Nitisoravut R.Nano zero valent iron embedded on chitosan for enhancement of biohydrogen production in dark fermentation[J].Energy Reports, 2020,6:392-396.
|
[24] |
Wang W,Li S L,Lei H, et al.Enhanced separation of nanoscale zero-valent iron (nZVI) using polyacrylamide:Performance, characterization and implication[J].Chemical Engineering Journal, 2015,260:616-622.
|
[25] |
Wu G C,Kong W J,Gao Y, et al.Removal of chloramphenicol by sulfide-modified nanoscale zero-valent iron activated persulfate:Performance, salt resistance, and reaction mechanisms[J].Chemosphere, 2022,286:131876.
|
[26] |
Li R, Li Q, Zhang W, et al.Low dose of sulfur-modified zero-valent iron for decontamination of trace Cd(II)-complexes in high-salinity wastewater[J].Science of The Total Environment, 2021,793:148579.
|
[27] |
Mortazavian S, An H, Chun D W, et al.Activated carbon impregnated by zero-valent iron nanoparticles (AC/nZVI) optimized for simultaneous adsorption and reduction of aqueous hexavalent chromium:Material characterizations and kinetic studies[J].Chemical Engineering Journal, 2018,353:781-795.
|
[28] |
Fan J,Chen X,Xu Z B, et al.One-pot synthesis of nZVI-embedded biochar for remediation of two mining arsenic-contaminated soils:Arsenic immobilization associated with iron transformation[J].Journal of Hazardous Materials, 2020,398:122901.
|
[29] |
Zhang X,Lin S,Chen Z L, et al.Kaolinite-supported nanoscale zero-valent iron for removal of Pb2+ from aqueous solution:Reactivity, characterization and mechanism[J].Water Research, 2011,45(11):3481-3488.
|
[30] |
Xu J L,Li Y L,Jing C, et al.Removal of uranium from aqueous solution using montmorillonite-supported nanoscale zero-valent iron[J].Journal of Radioanalytical and Nuclear Chemistry, 2014,299:329-336.
|
[31] |
Wu J X,Wang B,Blaney L, et al.Degradation of sulfamethazine by persulfate activated with organo-montmorillonite supported nano-zero valent iron[J].Chemical Engineering Journal, 2019,361:99-108.
|
[32] |
Baldermann A, Kaufhold S, Dohrmann R, et al.A novel nZVI-bentonite nanocomposite to remove trichloroethene (TCE) from solution[J].Chemosphere, 2021,282:131018.
|
[33] |
Wang Q, Song X, Tang S Y, et al.Enhanced removal of tetrachloroethylene from aqueous solutions by biodegradation coupled with nZVI modified by layered double hydroxide[J].Chemosphere, 2020,243:125260.
|
[34] |
庞宏伟,唐昊,王佳琦,等.三元水滑石负载的硫化纳米零价铁对铀的高效去除与机理研究[J].无机材料学报, 2020,35(3):381-389.Pang H W, Tang H, Wang J Q, et al.Ternary layered double hydroxide supported sulfide nZVI:efficient U(VI) elimination and mechanism[J].Journal of Inorganic Materials, 2020,35(3):381-389.
|
[35] |
Zhang W Y,Qian L B,Ouyang D, et al.Effective removal of Cr(VI) by attapulgite-supported nanoscale zero-valent iron from aqueous solution:Enhanced adsorption and crystallization[J].Chemosphere, 2019,221:683-692.
|
[36] |
Ding C X,Xiao S J,Lin Y J, et al.Attapulgite-supported nano-Fe0/peroxymonsulfate for quinclorac removal:Performance, mechanism and degradation pathway[J].Chemical Engineering Journal, 2019,360:104-114.
|
[37] |
徐海玉,张明青,陈翌昱.有机凹凸棒石负载纳米零价铁去除水中六价铬[J].中国环境科学, 2019,39(12):5079-5084.Xu H Y, Zhang M Q, Chen Y Y.Removal of Cr(VI) from aqueous solution using organically modified attapulgite-supported nanoscale zero-valent iron[J].China Environmental Science, 2019,39(12):5079-5084.
|
[38] |
Lin J J, Sun M Q, Liu X W, et al.Functional kaolin supported nanoscale zero-valent iron as a Fenton-like catalyst for the degradation of Direct Black G[J].Chemosphere, 2017,184:664-672.
|
[39] |
刘柳,胡佩伟,高润琴,等.纳米零价铁强化高岭石去除水中Cr(Ⅵ)及机制研究[J].硅酸盐通报, 2021,40(5):1529-1535.Liu L, Hu P W, Gao R Q, et al.Removal of chromate(vi) from water using kaolinite enhanced by nano-zero-valent iron and its mechanism[J].Bulletin of The Chinese Ceramic Society, 2021,40(5):1529-1535.
|
[40] |
Sun Y M, Feng L,Yang L.Degradation of PCB67 in soil using the heterogenous Fenton process induced by montmorillonite supported nanoscale zero-valent iron[J].Journal of Hazardous Materials, 2021, 406:124305.
|
[41] |
胡六江,李益民.有机膨润土负载纳米铁去除废水中硝基苯[J].环境科学学报, 2008,(6):1107-1112.Hu L J, Li Y M.Removal of nitrobenzene from synthetic waste water by nanoscale zero-valent iron supported on organobentonite[J].Acta Scientiae Circumstantiae, 2008,(6):1107-1112.
|
[42] |
Li Q,Wang H H,Chen Z S, et al.Adsorption-reduction strategy of U(VI) on NZVI-supported zeolite composites via batch, visual and XPS techniques[J].Journal of Molecular Liquids, 2021,339:116719.
|
[43] |
Zhao R R, Zhou Z M, Zhao X D, et al.Enhanced Cr(VI) removal from simulated electroplating rinse wastewater by amino-functionalized vermiculite-supported nanoscale zero-valent iron[J].Chemosphere, 2019,218:458-467.
|
[44] |
Ma B, Yao J, Chen Z H, et al.Superior elimination of Cr(VI) using polydopamine functionalized attapulgite supported nZVI composite:Behavior and mechanism[J].Chemosphere, 2022,287:131970.
|
[45] |
Zhang W Y, Qian L B, Ouyang D, et al.Effective removal of Cr(VI) by attapulgite-supported nanoscale zero-valent iron from aqueous solution:Enhanced adsorption and crystallization[J].Chemosphere, 2019,221:683-692.
|
[46] |
Fu R B,Yang Y P,Xu Z, et al.The removal of chromium (VI) and lead (II) from groundwater using sepiolite-supported nanoscale zero-valent iron (S-NZVI)[J].Chemosphere, 2015,138:726-734.
|
[47] |
Shi L N, Zhang X, Chen Z L.Removal of Chromium (VI) from wastewater using bentonite-supported nanoscale zero-valent iron[J].Water Research, 2011,45(2):886-892.
|
[48] |
Yang J, Wang S Q, Xu N, et al.Synthesis of montmorillonite-supported nano-zero-valent iron via green tea extract:Enhanced transport and application for hexavalent chromium removal from water and soil[J].Journal of Hazardous Materials, 2021,419:126461.
|
[49] |
Zhang Y Y, Jiang H, Zhang Y, et al.The dispersity-dependent interaction between montmorillonite supported nZVI and Cr(VI) in aqueous solution[J].Chemical Engineering Journal, 2013,229:412-419.
|
[50] |
Sheng G D,Hu J,Li H, et al.Enhanced sequestration of Cr(VI) by nanoscale zero-valent iron supported on layered double hydroxide by batch and XAFS study[J].Chemosphere, 2016,148:227-232.
|
[51] |
Wang C, Xu Z, Ding G, et al.Comprehensive study on the removal of chromate from aqueous solution by synthesized kaolin supported nanoscale zero-valent iron[J].Desalination and Water Treatment, 2016,57(11):5065-5078.
|
[52] |
徐雷,代惠萍,魏树和.淋洗剂在重金属污染土壤修复中的研究进展[J].中国环境科学, 2021,41(11):5237-5244.Xu L, Dai H P, Wei S H.Advances of washing agents in remediation of heavy metal contaminated soil[J].China Environmental Science, 2021,41(11):5237-5244.
|
[53] |
Soliemanzadeh A, Fekri M.The application of green tea extract to prepare bentonite-supported nanoscale zero-valent iron and its performance on removal of Cr(VI):Effect of relative parameters and soil experiments[J].Microporous and Mesoporous Materials, 2017, 239:60-69.
|
[54] |
Xu C B,Qi J,Yang W J, et al.Immobilization of heavy metals in vegetable-growing soils using nano zero-valent iron modified attapulgite clay[J].Science of The Total Environment, 2019,686:476-483.
|
[55] |
Li Q, Chen Z S, Wang H H, et al.Removal of organic compounds by nanoscale zero-valent iron and its composites[J].Science of The Total Environment, 2021,792:148546.
|
[56] |
何思莹.高岭土负载硫化纳米零价铁激活过硫酸盐去除电子垃圾拆解地土壤中的十溴联苯醚[D].太原:太原理工大学, 2019.He S Y.Degradation of decabromodiphenyl ether in the soil of e-waste dismantling site by activating persulfate using kaolin supported-modified nanoscale zero-valent iron[D].Taiyuan:Taiyuan University of Technology, 2019.
|
[57] |
Yu K, Sheng G D, McCall W.Cosolvent effects on dechlorination of soil-sorbed polychlorinated biphenyls using bentonite clay-templated nanoscale zero valent iron[J].Environmental Science & Technology, 2016,50(23):12949-12956.
|
[58] |
Liu Y, Wang J L.Reduction of nitrate by zero valent iron (ZVI)-based materials:A review[J].Science of The Total Environment, 2019, 671:388-403.
|
[59] |
Zeng Y B, Walker H, Zhu Q Z.Reduction of nitrate by NaY zeolite supported Fe, Cu/Fe and Mn/Fe nanoparticles[J].Journal of Hazardous Materials, 2017,324:605-616.
|
[60] |
修瑞瑞,何世颖,宋海亮,等.改性硅藻土负载纳米零价铁去除水中硝酸盐氮[J].化工学报, 2016,67(9):3888-3894.Xiu R R, He S Y, Song H L, et al.Removal of nitrate nitrogen by nanoscale zero-valent iron supported on modified diatomite[J].Acta ChimicaSinica, 2016,67(9):3888-3894.
|
[61] |
Liu X, Cao Z,Yuan Z L, et al.Insight into the kinetics and mechanism of removal of aqueous chlorinated nitroaromatic antibiotic chloramphenicol by nanoscale zero-valent iron[J].Chemical Engineering Journal, 2018,334:508-518.
|
[62] |
Zhu C Y, Fang G D, Dionysiou D D, et al.Efficient transformation of DDTs with persulfate activation by zero-valent iron nanoparticles:A mechanistic study[J].Journal of Hazardous Materials, 2016,316:232-241.
|
[63] |
Zhou Z,Ma J,Liu X T, et al.Activation of peroxydisulfate by nanoscale zero-valent iron for sulfamethoxazole removal in agricultural soil:Effect, mechanism and ecotoxicity[J].Chemosphere, 2019,223:196-203.
|
[64] |
Xue W J, Huang D L, Zeng G M, et al.Performance and toxicity assessment of nanoscale zero valent iron particles in the remediation of contaminated soil:A review[J].Chemosphere, 2018,210:1145-1156.
|
[65] |
Zhang F, He M Y, Zhang C L, et al.Combined toxic effects of dioxin-like PCB77 with Fe-based nanoparticles in earthworm Eisenia fetida[J].Science of The Total Environment, 2021,766:144347.
|
[66] |
Zhou L, Thanh T L, Gong J Y, et al.Carboxymethyl cellulose coating decreases toxicity and oxidizing capacity of nanoscale zerovalent iron[J].Chemosphere, 2014,104:155-161.
|
|
|
|