深圳工业区夏秋季大气挥发性有机物来源研究

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Abstract The long-term online observation of atmospheric volatile organic compounds (VOCs) was carried out in the northern industrial area of Shenzhen from July to October 2021 to analyze pollution characteristics of VOCs during ozone polluted days and non-polluted days. The refined source apportionment of VOCs was carried out by using ratio method of characteristics species and positive matrix factorization (PMF) model to analyze the concentration and OFP contribution of each emission source and the influence of meteorological conditions. The results showed that the average mixing ratio of TVOCs was 50.48×10^-9, of which alkane contributed the most, followed by OVOCs and aromatic, accounting for 41.3%, 22.2% and 17.0% respectively. Comparing with non-polluted days, the mixing ratio of OVOCs increased the most during polluted days (63.1%). The ratio of characteristic species indicated that the area was mainly affected by vehicle emission and industrial solvent use. Five VOCs emission sources were determined by the PMF model, of which vehicle emissions and gasoline volatilization contributed the most to the concentration (28.2%), followed by solvent use (22.9%), process emissions (25.0%) and biomass combustion (20.4%). OFP contribution of process emissions and solvent use exceeded 70% during polluted days. The distribution characteristics with wind speed and direction indicated that vehicle emissions and gasoline volatilization, process emissions and solvent use mainly came from local emissions, while biomass combustion was more influenced by transmission from northeast. It is suggested to intensify local industrial and traffic source controls, while also paying attention to biomass combustion and strengthening joint prevention and control with neighboring areas.

Key words： industrial area volatile organic compounds (VOCs) ozone formation potential (OFP) ratio method of characteristics species positive matrix factorization (PMF)

Received: 05 January 2023

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X511

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	ZHANG Yue
	XIA Shi-yong
	WEI Cheng-bo
	LIU Shi-qi
	CAO Li-ming
	YU Guang-he
	HUANG Xiao-feng

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ZHANG Yue,XIA Shi-yong,WEI Cheng-bo等. Source apportionment of atmospheric volatile organic compounds in summer and autumn in Shenzhen industrial area[J]. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(8): 3857-3866.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2023/V43/I8/3857

[1]	中国环境科学学会.中国大气臭氧污染防治蓝皮书[M]. 2020. Chinese Society of Environmental Sciences. China blue book of atmospheric ozone pollution prevention and control[M]. 2020.
[2]	Wang G, Zhao N, Zhang H, et al. Spatiotemporal Distributions of Ambient Volatile Organic Compounds in China:Characteristics and Sources[J]. Aerosol and Air Quality Research, 2022,22(5).
[3]	Mirowsky J E, Carraway M S, Dhingra R, et al. Ozone exposure is associated with acute changes in inflammation, fibrinolysis, and endothelial cell function in coronary artery disease patients[J]. Environmental Health, 2017,16(1):126.
[4]	陈浪,赵川,关茗洋,等.我国大气臭氧污染现状及人群健康影响[J].环境与职业医学, 2017,34(11):1025-1030. Chen L, Zhao C, Guan M Y, et al. Ozone pollution in China and its adverse health effects[J]. Journal of Environmental and Occupational Medicine, 2017,34(11):1025-1030.
[5]	Pina J M, Moraes R M. Gas exchange, antioxidants and foliar injuries in saplings of a tropical woody species exposed to ozone[J]. Ecotoxicology and Environmental Safety, 2010,73(4):685-691.
[6]	列淦文,叶龙华,薛立.臭氧胁迫对植物主要生理功能的影响[J].生态学报, 2014,34(2):294-306. Lie G W, Ye L H, Xue L Effects of ozone stress on major plant physiological functions[J]. Acta Ecologica Sinica, 2014,34(2):294-306.
[7]	Ren W, Tian H Q, Liu M L, et al. Effects of tropospheric ozone pollution on net primary productivity and carbon storage in terrestrial ecosystems of China[J]. Journal of Geophysical Research, 2007,112(D22S09).
[8]	Liao H, Zhang Y, Chen W-T, et al. Effect of chemistry-aerosol-climate coupling on predictions of future climate and future levels of tropospheric ozone and aerosols[J]. Journal of Geophysical Research, 2009,114(D10).
[9]	He Z, Wang X, Ling Z, et al. Contributions of different anthropogenic volatile organic compound sources to ozone formation at a receptor site in the Pearl River Delta region and its policy implications[J]. Atmospheric Chemistry and Physics, 2019,19(13):8801-8816.
[10]	Shao M, Lu S, Liu Y, et al. Volatile organic compounds measured in summer in Beijing and their role in ground-level ozone formation[J]. Journal of Geophysical Research, 2009,114.
[11]	李悦,邵敏,陆思华.城市大气中挥发性有机化合物监测技术进展[J].中国环境监测, 2015,31(4):1-7. Li Y, Shao M, Lu S H. Review on technologies of ambient volatile organic compounds measurement[J]. Environmental Monitoring in China, 2015,31(4):1-7.
[12]	刘兴隆,曾立民,陆思华,等.大气中挥发性有机物在线监测系统[J].环境科学学报, 2009,29(12):2471-2477. Liu X L, Zeng L M, Lu S H, et al. Online monitoring system for volatile organic compounds in the atmosphere[J]. Acta Scientiae Circumstantiae, 2009,29(12):2471-2477.
[13]	Atkinson R. Gas-phase tropospheric chemistry of organic compounds:a review[J]. Atmospheric Environment, 2007,41:S200-S240.
[14]	陈雪.深圳市光化学活跃季大气挥发性有机物时空变化特征[D].北京:北京大学, 2021. Chen X. Temporal and spatial variation characteristics of volatile organic compounds during the period with active photochemical reaction in Shenzhen[D]. Beijing:Peking University, 2021.
[15]	Guo H, Wang T, Simpson I J, et al. Source contributions to ambient VOCs and CO at a rural site in eastern China[J]. Atmospheric Environment, 2004,38(27):4551-4560.
[16]	Zheng B, Tong D, Li M, et al. Trends in China's anthropogenic emissions since 2010 as the consequence of clean air actions[J]. Atmospheric Chemistry and Physics, 2018,18(19):14095-14111.
[17]	Sun W, Shao M, Granier C, et al. Long-term trends of anthropogenic SO2, NOx, CO, and NMVOCs emissions in China[J]. Earth's Future, 2018,6(8):1112-1133.
[18]	Li B, Ho S S H, Li X, et al. A comprehensive review on anthropogenic volatile organic compounds (VOCs) emission estimates in China:Comparison and outlook[J]. Environment International, 2021,156.
[19]	Shao M, Zhang Y, Zeng L, et al. Ground-level ozone in the Pearl River Delta and the roles of VOCs and NOx in its production[J]. Environmental Management, 2009,90(1):512-518.
[20]	Meng Y, Song J, Zeng L, et al. Ambient volatile organic compounds at a receptor site in the Pearl River Delta region:Variations, source apportionment and effects on ozone formation[J]. Journal of Environmental Sciences, 2022,111:104-117.
[21]	宋鑫,袁斌,王思行,等.珠三角典型工业区挥发性有机物(VOCs)组成特征:含氧挥发性有机物的重要性[J].环境科学, 2023,44(3):1336-1345. Song X, Yuan B, Wang S X, et al. Compositional characteristics of volatile organic compounds in typical industrial areas of the Pearl River Delta:Importance of oxygenated volatile organic compounds[J]. Environmental Science, 2023,44(3):1336-1345.
[22]	李佳佳.典型工业园挥发性有机物的三维空间分布特征及其健康风险评估研究[D].广东:广东工业大学, 2022. Li J J. Study on the three-dimensional spatial distribution characteristics and health risk assessment of volatile organic compounds in typical industrial parks[D]. Guangdong:Guangdong University of Technology, 2022.
[23]	邓思欣,刘永林,司徒淑娉,等.珠三角产业重镇大气VOCs污染特征及来源解析[J].中国环境科学, 2021,41(7):2993-3003. Deng S X, Liu Y L, Situ S P, et al. Characteristics and source apportionment of volatile organic compounds in an industrial town of Pearl River Delta[J]. China Environmental Science, 2021,41(7):2993-3003.
[24]	朱波.深圳市大气挥发性有机物空间分布特征与溯源研究[D].北京:北京大学, 2022. Zhu B. Characteristics of Spatial distributionj and source apportionment of atmospheric volatile organic compounds in Shenzhen[D]. Beijing:Peking University, 2022.
[25]	于广河,林理量,夏士勇,等.深圳市工业区VOCs污染特征与臭氧生成敏感性[J].中国环境科学, 2022,42(5):1994-2001. Yu G H, Lin L L, Xia S Y, et al. The characteristics of VOCs and ozone formation sensitivity in a typical industrial area in Shenzhen[J]. China Environmental Science, 2022,42(5):1994-2001.
[26]	于广河,夏士勇,曹礼明,等.深圳市工业区大气PAN污染特征与影响因素[J].中国环境科学, 2023,43(2):497-505. Yu G H, Xia S Y, Cao L M, et al. Pollution characteristics and influencing factors of atmospheric PAN in industrial area of Shenzhen[J]. China Environmental Science, 2023,43(2):497-505.
[27]	黄沛荣.深圳市典型工业园VOCs排放特征研究[D].北京:北京大学, 2022. Huang P R. Emission characteristics of VOCs from typical industrial sources in Shenzhen[D]. Beijing:Peking University, 2022.
[28]	HJ1010-2018环境空气挥发性有机物气相色谱连续监测系统技术要求及检测方法[S]. HJ1010-2018 Technical requirements and test methods for continuous monitoring system of volatile organic compounds in ambient air by gas chromatography[S].
[29]	Carter W P L. Development of a condensed SAPRC-07chemical mechanism[J]. Atmospheric Environment, 2010,44(40):5336-5345.
[30]	Paatero Pentti, Tapper Unto. Positive matrix factorization:A non-negative factor model with optima utilization of error estimates of data values[J]. Environmetrics, 1994,5(2):111-126.
[31]	Saeaw N, Thepanondh S. Source apportionment analysis of airborne VOCs using positive matrix factorization in industrial and urban areas in Thailand[J]. Atmospheric Pollution Research, 2015,6(4):644-650.
[32]	Wadden R A, Uno I, Wakamatsu S. Source discrimination of short-term hydrocarbon samples measured aloft[J]. Environmental Science & Technology, 1986,20(5):473-483.
[33]	Liu C T, Ma Z B, Mu Y J, et al. The levels, variation characteristics, and sources of atmospheric non-methane hydrocarbon compounds during wintertime in Beijing, China[J]. Atmospheric Chemistry and Physics, 2017,17(17):10633-10649.
[34]	朱玉凡,陈强,刘晓,等.基于气团老化程度对挥发性有机物分类改善PMF源解析效果[J].环境科学, 2022,43(2):707-713. Zhu Y F, Chen Q, Liu X, et al. Improved performance of PMF source apportionment for volatile organic compounds based on classification of VOCs aging degree in air mass[J]. Environmental Science, 2022, 43(2):707-713.
[35]	Zheng H, Kong S, Chen N, et al. Source apportionment of volatile organic compounds:Implications to reactivity, ozone formation, and secondary organic aerosol potential[J]. Atmospheric Research, 2021, 249.
[36]	环境空气质量指数(AQI)技术规定(试行)[J].中国环境管理干部学院学报, 2012,22(1):44. Technical regulation of ambient air quality index (AQI)[J]. Journal of China Academy of Environmental Management, 2012,22(1):44.
[37]	曹梦瑶,林煜棋,章炎麟.南京工业区秋季大气挥发性有机物污染特征及来源解析[J].环境科学, 2020,41(6):2565-2576. Cao M Y, Lin Y Q, Zhang Y L. Characteristics and source apportionment of atmospheric VOCs in the Nanjing Industrial Area in autumn[J]. Environmental Science, 2020,41(6):2565-2576.
[38]	刘芮伶,翟崇治,李礼,等.重庆主城区夏秋季挥发性有机物(VOCs)浓度特征及来源研究[J].环境科学学报, 2017,37(4):1260-1267. Liu R L, Zhai C Z, Li L, et al. Concentration characteristics and source analysis of ambient VOCs in summer and autumn in the urban area of Chongqing[J]. Acta Scientiae Circumstantiae, 2017,37(4):1260-1267.
[39]	徐晨曦,陈军辉,韩丽,等.成都市2017年夏季大气VOCs污染特征、臭氧生成潜势及来源分析[J].环境科学研究, 2019,32(4):619-626. Xu C X, Chen J H, Han L, et al. Analyses of pollution characteristics, ozone formation potential and sources of VOCs Atmosphere in Chengdu City in summer 2017[J]. Research of Environmental Sciences, 2019,32(4):619-626.
[40]	Huang X F, Wang C, Zhu B, et al. Exploration of sources of OVOCs in various atmospheres in southern China[J]. Environmental Pollution, 2019,249:831-842.
[41]	Qu H, Wang Y, Zhang R, et al. Chemical production of oxygenated volatile organic compounds strongly enhances boundary-layer oxidation chemistry and ozone production[J]. Environmental Science&Technology, 2021,55(20):13718-13727.
[42]	Lai C H, Chang C C, Wang C H, et al. Emissions of liquefied petroleum gas (LPG) from motor vehicles[J]. Atmospheric Environment, 2009,43(7):1456-1463.
[43]	Huang A, Yin S, Yuan M, et al. Characteristics, source analysis and chemical reactivity of ambient VOCs in a heavily polluted city of central China[J]. Atmospheric Pollution Research, 2022,13(4).
[44]	Liu B, Liang D, Yang J, et al. Characterization and source apportionment of volatile organic compounds based on 1-year of observational data in Tianjin, China[J]. Environmental Pollution, 2016, 218:757-769.
[45]	Song C, Liu Y, Sun L, et al. Emissions of volatile organic compounds (VOCs) from gasoline-and liquified natural gas (LNG)-fueled vehicles in tunnel studies[J]. Atmospheric Environment, 2020,234.
[46]	Hong Z, Li M, Wang H, et al. Characteristics of atmospheric volatile organic compounds (VOCs) at a mountainous forest site and two urban sites in the southeast of China[J]. Science of The Total Environment, 2019,657:1491-1500.
[47]	Hui L, Liu X, Tan Q, et al. VOC characteristics, chemical reactivity and sources in urban Wuhan, central China[J]. Atmospheric Environment, 2020,224.
[48]	中华人民共和国生态环境部.大气挥发性有机物源排放清单编制技术指南(试行)[S]. 2014. Ministry of Ecology and Environment. People's Republic of China. Technical Guide for Compilation of emission inventories of atmospheric volatile Organic Compounds (Trial)[S]. 2014.
[49]	Hui L, Liu X, Tan Q, et al. Characteristics, source apportionment and contribution of VOCs to ozone formation in Wuhan, Central China[J]. Atmospheric Environment, 2018,192:55-71.
[50]	Barletta B, Meinardi S, Simpson I J, et al. Ambient mixing ratios of nonmethane hydrocarbons (NMHCs) in two major urban centers of the Pearl River Delta (PRD) region:Guangzhou and Dongguan[J]. Atmospheric Environment, 2008,42(18):4393-4408.
[51]	Kumar A, Singh D, Kumar K, et al. Distribution of VOCs in urban and rural atmospheres of subtropical India:Temporal variation, source attribution, ratios, OFP and risk assessment[J]. Science of The Total Environment, 2018,613-614:492-501.
[52]	Yurdakul S, Civan M, KuntasalÖ, et al. Temporal variations of VOC concentrations in Bursa atmosphere[J]. Atmospheric Pollution Research, 2018,9(2):189-206.
[53]	Li B, Ho S S H, Xue Y, et al. Characterizations of volatile organic compounds (VOCs) from vehicular emissions at roadside environment:The first comprehensive study in Northwestern China[J]. Atmospheric Environment, 2017,161:1-12.
[54]	林理量.深圳市不同功能区夏秋季挥发性有机物污染特征研究[D].北京:北京大学, 2021. Lin L L. Characteristics of volatile organic compounds in different functional areas of Shenzhen in summer and autumn[D]. Beijing:Peking University, 2022.
[55]	Zhu B, Huang X F, Xia S Y, et al. Biomass-burning emissions could significantly enhance the atmospheric oxidizing capacity in continental air pollution[J]. Environmental Pollution, 2021,285:117523.
[56]	Zheng J, Yu Y, Mo Z, et al. Industrial sector-based volatile organic compound (VOC) source profiles measured in manufacturing facilities in the Pearl River Delta, China[J]. Science of The Total Environment, 2013,456-457:127-136.
[57]	于广河,朱乔,夏士勇,等.深圳市典型工业行业VOCs排放谱特征研究[J].环境科学与技术, 2018,41(S1):232-236. Yu G H, Zhu Q, Xia S Y, et al. Emission characteristics of volatile organic compounds (VOCs) source profile from typical industries in Shenzhen[J]. Environmental Science & Technology, 2018,41(S1):232-236.
[58]	黄沛荣,朱波,张月,等.PM2.5与O3协同控制视角下深圳市工业VOCs源谱特征[J].中国环境科学, 2022,42(8):3473-3482. Huang P R, Zhu B, Zhang Y, et al. Source profile characteristics of industrial VOCs in Shenzhen from the perspective of PM2.5 and O3 synergistic control[J]. China Environmental Science, 2022,42(8):3473-3482.