吸附树脂和活性炭吸附气体中二硫化碳的性能差异及成因研究

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Abstract The reasons for the variations in adsorption performance were investigated as they related to the effects of water vapor and hydrogen sulfide on the adsorption of carbon disulfide onto activated carbon and polymeric resin in a fixed bed column. The findings demonstrated that water, whether co-adsorbed or pre-adsorbed, had a much greater influence on the adsorption of carbon disulfide onto activated carbon than it did onto polymeric resin. This was primarily due to the fact that activated carbon had more oxygen-containing groups (hydroxy and carbonyl groups) with strong affinity for water molecules, which led to the water molecules occupying the adsorption sites. Pre-adsorbed hydrogen sulfide dramatically reduced the ability of carbon disulfide to adsorb onto activated carbon while having no impact on polymeric resin. The results of X-ray photoelectron spectroscopy (XPS) and pore structure analysis demonstrated that hydrogen sulfide reacted on the surface of activated carbon to produce by-products like elemental sulfur, resulting in a reduction of specific surface area and total pore volume by 59.6% and 57.3%, respectively. In addition, inverse gas chromatography was used to evaluate the dispersive components of the surface free energy of the two adsorbents. Higher surface free energy dispersive components were present in activated carbon. The dispersive components of surface free energy can be used to more effectively explain why activated carbon is better at adsorbing a single component of carbon disulfide than W-8resin when compared to pore structure parameters like specific surface area.

Key words： VOCs carbon disulfide water vapor hydrogen sulfide hypercrosslinked resin activated carbon

Received: 14 February 2023

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X511

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	QU Hong-chang
	MA Jia-kai
	LONG Chao

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QU Hong-chang,MA Jia-kai,LONG Chao. An investigation of the causes of different adsorption properties of carbon disulfide vapor in gas on polymeric resin and activated carbon[J]. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(9): 4534-4541.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2023/V43/I9/4534

[1]	Huang F Y, Wu Y L, Zhang D L, et al. Carbon disulfide induced decidualization disorder in the mice uterus at the window of implantation[J]. Ecotoxicology and Environmental Safety, 2020, 190:110069.
[2]	Bocos-Bintintan V, Ratiu IA. Hunting for toxic industrial chemicals:real-time detection of carbon disulfide traces by means of ion mobility spectrometry[J]. Toxics, 2021,8(4):121.
[3]	Xu T, Wang B, Wang X, et al. Associations of urinary carbon disulfide metabolite with oxidative stress, plasma glucose and risk of diabetes among urban adults in China[J]. Environmental Pollution, 2021,272:115959.
[4]	Bortnikova S B, Devyatova A Y, Yurkevich N V, et al. Gas anomalies in the air above the sulfide tailings and adjacent soils in komsomolsk settlement[J]. Water Air and Soil Pollution, 2021,232(10):412.
[5]	Liu Y J, Lu W J, Wang H T, et al. Odor impact assessment of trace sulfur compounds from working faces of landfills in Beijing, China[J]. Journal of Environmental Management, 2018,220(15):136-141.
[6]	Gharehveran M M, Shah A D. Indirect photochemical formation of carbonyl sulfide and carbon disulfide in natural waters:role of organic sulfur precursors, water quality constituents, and temperature[J]. Environmental Science & Technology, 2018,52(16):9108-9117.
[7]	Majumdar D, Bhanarkar A, Rao C, et al. Carbon disulphide and hydrogen sulphide emissions from viscose fibre manufacturing industry:A case study in India[J]. Atmospheric Environment-X, 2022, 13:100157.
[8]	田昀,刘庆岭,纪娜,等.挥发性污染物二硫化碳处理技术[J]. 环境工程, 2018,36(7):87-92. Tian J, Liu Q L, Ji N, et al. Volatile pollutant carbon disulfide treatment technology[J]. Environmental Engineering, 2018,36(7):87-92.
[9]	Chen J Y, Chen A G, Qiu P L, et al. Removal of carbon disulfide from air stream by absorption combined with electrochemical oxidation[J]. Journal of Environmental Chemical Engineering, 2019,7(3):103167.
[10]	余岩松,吴柳彦,刘慧娟,等.双组分VOCs在吸附树脂上的吸附穿透特性[J]. 中国环境科学, 2020,40(5):1982-1990. Yu Y S, Wu L Y, Liu H J, et al. The adsorption penetration characteristics of two component VOCs on adsorption resins[J]. China Environmental Science, 2020,40(5):1982-1990.
[11]	龙传光,甘安辉,邵虎.GLT络合铁在处理粘胶纤维废气中硫化氢的试验研究[J]. 山西化工, 2021,41(2):21-23. Long C G, Gan A H, Shao H. Experimental study on GLT complex iron in treating hydrogen sulfide in viscose fiber waste Gas[J]. Shanxi Chemical Industry, 2021,41(2):21-23.
[12]	Xia J H, Zhu X L, Hu J, et al. Simultaneous removal of carbon disulfide and hydrogen sulfide from viscose fibre waste gas with a biotrickling filter in pilot scale[J]. Journal of Cleaner Production, 2019,230:21-28.
[13]	Xie Z Y, Wang F, Zhao N, et al. Hydrophobisation of activated carbon fiber and the influence on the adsorption selectivity towards carbon disulfide[J]. Applied Surface Science, 2011,257(8):3596-3602.
[14]	建晓朋.活性炭对二硫化碳吸附和解吸行为研究[D]. 北京:中国林业科学研究院, 2021. Jian X P. Study on adsorption and desorption behavior of activated carbon on carbon disulfide[D]. Beijing:Chinese Academy of Forestry, 2021.
[15]	袁世阳.金属掺杂ZSM-5分子筛制备及脱硫性能研究[D]. 郑州:河南大学, 2018. Yuan S Y. Preparation and desulfurization performance of metal doped ZSM-5molecular sieve[D]. Zhengzhou:Henan University, 2018
[16]	孟令刚,张现策,李芹,等.焙烧气氛对K2CO3/γ-Al2O3吸附剂脱除异戊二烯中二硫化碳性能的影响[J]. 化工进展, 2021,40(1):221-226. Meng L G, Zhang X C, Li Q, et al. Effect of roasting atmosphere on K2CO3/γ-Al2O3 adsorbent on removal of carbon disulfide from isoprene[J]. Chemical Industry and Engineering Progress, 2021,40(1):221-226.
[17]	Wang S S, Zhang L, Long C, et al. Enhanced adsorption and desorption of VOCs vapor on novel micro-mesoporous polymeric adsorbents[J]. Journal of Colloid and Interface Science, 2014,428:185-190.
[18]	Li X Q, Zhang L, Yang Z Q, et al. Adsorption materials for volatile organic compounds (VOCs) and the keyfactors for VOCs adsorption process:A review[J]. Separation and Purification Technology, 2020, 235:116213.
[19]	杨新玉,史秋怡,龙超.吸附树脂吸附多组分VOCs的动力学特性及预测[J]. 中国环境科学, 2019,39(5):1830-1837. Yang X Y, Shi Q Y, Long C. The kinetic characteristics and prediction of adsorption resin for multi-component VOCs[J]. Chin Environmental Science, 2019,39(5):1830-1837.
[20]	郭鹏涛,成西涛,郑阿龙,等.超高交联吸附树脂的合成及应用研究[J]. 应用化工, 2021,50(10):2892-2894. Guo P T, Cheng X T, Zheng A L, et al. Research on the synthesis and application of hypercrosslinked adsorption resin[J]. Applied Chemical Industry, 2021,50(10):2892-2894.
[21]	Boehm H P. Some aspects of the surface-chemistry of carbon-blacks and other carbons[J]. Carbon, 1994,32(5):759-769.
[22]	Salehi E, Askari M, Darvishi Y. Novel combinatorial extensions to breakthrough curve modeling of an adsorption column-Depth filtration hybrid process[J]. Journal of Industrial and Engineering Chemistry, 2020,86:232-243.
[23]	Zhu L L, Shen D K, Luo K H. A critical review on VOCs adsorption by different porous materials:Species, mechanisms and modification methods[J]. Journal of Hazardous Materials, 2020,389:122102.1-122102.27.
[24]	Jia L J, Niu B, Jing X X, et al. Equilibrium and hysteresis formation of water vapor adsorption on microporous adsorbents:Effect of adsorbent properties and temperature[J]. 2022,72(2):176-186.
[25]	Lu S C, Liu Q L, Han R, et al. Potential applications of porous organic polymers as adsorbent for the adsorption of volatile organic compounds[J]. Journal of Environmental Sciences, 2021,105:184-203.
[26]	Yang C T, Miao G, Pi Y H, et al. Abatement of various types of VOCs by adsorption/catalytic oxidation:A review[J]. Journal of Environmental Chemical Engineering, 2019,370:1128-1153.
[27]	Liu H J, Wang L S, Long C, et al. Mechanistic insights into and modeling the effects of relative humidity on low-concentration VOCs adsorption on hyper-cross-linked polymeric resin by inverse gas chromatography[J]. Journal of Hazardous Materials, 2021,418:126335.