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Composition characteristics and source apportionment of water-soluble ions in atmospheric wet precipitation of Jiaozhou Bay |
FENG Chen-long1,4, XING Jian-wei1,2,3, YUAN Hua-mao1,2,3, SONG Jin-ming1,2,3 |
1. Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China; 2. University of Chinese Academy of Sciences, Beijing 100049, China; 3. Center for Ocean Mega-science, Chinese Academy of Sciences, Qingdao 266071, China; 4. School of Chemical and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China |
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Abstract The composition, sources and wet deposition fluxes of major water-soluble ions [Na+、K+、Ca2+、Mg2+、NH4+、F-、Cl-、SO42-、NO3-、MAS- (methylsulfonate)] in precipitation were analyzed based on the atmospheric precipitation samples along the coast of Jiaozhou Bay from June 2019 to August 2020. The contribution of water-soluble ions to nutrients and potential ecological effects on coastal ecosystem were evaluated, and their main sources were analyzed using the air mass backward trajectory and Positive Matrix Factorization (PMF) model. Volume-weighted Mean (VWM) pH of precipitation over Jiaozhou Bay is 6.41, and the VWM value of electrical conductivity is 19.3μS/cm. The water-soluble ions in precipitation are mainly Na+、NH4+、NO3-、Cl- and SO42- and their concentrations in winter and spring are significantly higher than those in summer and autumn, while the wet deposition flux is mainly concentrated in summer (about 55%) due to the control of precipitation. During the study period, the atmospheric precipitation removed 7274.6t of water-soluble ions from atmosphere and about 951.9t/a of nutrients (mainly NH4+and NO3-, in terms of nitrogen) were deposited into Jiaozhou Bay, indicating that the atmospheric precipitation exacerbated marine environment pollution and led to the imbalance of marine ecosystem in the process of cleaning the atmosphere. Four types of air masses controlling the precipitation over Jiaozhou Bay were obtained from the analysis of the air mass backward trajectory. In different seasons, the precipitation process was affected by different air masses, among which the air masses from East China and northeast direction had a greater influence. The source analysis results based on PMF showed that the water-soluble ions in the atmospheric precipitation in Jiaozhou Bay were jointly controlled by agricultural sources, marine sources, dust sources, biomass and refuse combustion sources, industrial and traffic sources. The contribution of agricultural sources was the most prominent (26.7%), while the contribution of other four sources is roughly equal. The study proves that the atmospheric environment of Jiaozhou Bay is constrained by complex anthropogenic emissions, mineral dust and marine emissions, and the contribution of anthropogenic emissions is dominant.
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Received: 07 July 2023
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Corresponding Authors:
邢建伟,研究员,jwxing@qdio.ac.cn
E-mail: jwxing@qdio.ac.cn
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[1] Liu B, Kang S, Sun J, et al. Wet precipitation chemistry at a high-altitude site (3,326m a. s. l.) in the southeastern Tibetan Plateau[J]. Environmental Science and Pollution Research, 2013,20(7):5013-5027. [2] Akpo A B, Galy-lacaux C, Laouali D, et al. Precipitation chemistry and wet deposition in a remote wet savanna site in West Africa:Djougou (Benin)[J]. Atmospheric Environment, 2015,115:110-123. [3] Garaga R, Chakraborty S, Zhang H, et al. Influence of anthropogenic emissions on wet deposition of pollutants and rainwater acidity in Guwahati, a UNESCO heritage city in North-east India[J]. Atmospheric Research, 2020,232:104683-104691. [4] 陈乃华.东南沿海典型岛屿大气降水化学特征及来源分析[J]. 环境监控与预警, 2023,15(2):71-77. Chen N H. Chemical characteristics and source apportionment of precipitation in a typical coastal island city of Southeastern China[J]. Environmental Monitoring and Forewarning, 2023,15(2):71-77. [5] 张思蕊,樊曙先,王元,等.南京雾过程对大气气溶胶谱分布及化学组成的影响[J]. 中国环境科学, 2022,42(11):4961-4973. Zhang S R, Fan S X, Wang Y, et al. Effects of Nanjing fog process on the spectral distribution and chemical composition of atmospheric aerosols. China Environmental Science, 2022,42(11):4961-4973. [6] Qiao L P, Cai J, Wang H L, et al. PM2.5 constituents and hospital emergency-room visits in Shanghai, China[J]. Environmental Science and Technology, 2014,48(17):10406-10414. [7] Wang L Q, Shen Z X, Lu D, et al. Water-soluble components in rainwater over Xi'an in Northwest China:source apportionment and pollution controls effectiveness evaluation[J]. Atmospheric Pollution Research, 2019,10(2):395-403. [8] Yang F, Tan J, Shi Z B, et al. Five-year record of atmospheric precipitation chemistry in urban Beijing, China[J]. Atmospheric Chemistry and Physics, 2012,11(10):28097-28124. [9] 周东,黄智浦,李思敏,等.西安市大气降水的主要化学组分及其来源[J]. 环境科学, 2023,44(16):3142-3151. Zhou D, Huang Z P, Li S M, et al. Main chemical components in atmospheric precipitation and their sources in Xi'an[J]. Environmental Science, 2023,44(16):3142-3151. [10] 任洁.太原农村地区颗粒物污染特征及其健康风险研究[D]. 太原:中北大学, 2022. Ren J. Characteristics and health risks of particulate matter pollution in the rural area of Taiyuan[D]. Taiyuan:North University of China, 2022. [11] 刘一鸣,郑浩阳,陈阁香,等.华南沿海地区夏初PM2.5水溶性离子特征及来源解析[J]. 环境科学学报, 2023,43(1):237-246. Liu Y M, Zheng H Y, Chen G X, et al. Characteristics and source apportionment of water-soluble ions in PM2.5 in early summer in coastal south China[J]. Acta Scientiae Circumstantiae, 2023,43(1):237-246. [12] 张谦栋,曲红拥,李家宁.烟台市大气湿沉降中水溶性离子污染特征及来源研究[J]. 环境生态学, 2022,4(8):85-90. Zhang Q D, Qu H Y, Li J N. Pollution characteristics and sources of water-soluble ions in atmospheric wet deposition in Yantai[J]. Environmental Ecology, 2022,4(8):85-90. [13] Xing J W, Song J M, Yuan H M, et al. Chemical characteristics, deposition fluxes and source apportionment of precipitation components in the Jiaozhou Bay, North China[J]. Atmospheric Research, 2017,190:10-20. [14] 冯辰龙,邢建伟,袁华茂,等.近20年中国近海和海岸带大气黑碳干湿沉降及源解析[J]. 海洋科学, 2023,47(2):71-85. Feng C L, Xing J W, Yuan H M, et al. Atmospheric dry and wet deposition of black carbon and source apportionment in offshore and coastal zones of China over the past 20 years[J]. Marine Sciences, 2023,47(2):71-85. [15] Ayers G P. Some practical aspects of acid deposition measurement[R]. The Third Expert Meeting on Acid Deposition Monitoring Network in East Asia. Japan:Niigata Prefecture, 1995:1-20. [16] 亓靓,盖冬君,董君,等."十三五"期间青岛市降水化学组成特征研究[J]. 科学技术创新, 2021,17:62-63. Qi L, Gai D J, Dong J, et al. The study of the characteristics of precipitation chemistry in Qingdao city during the 13th five period[J]. Scientific and Technological Innovation, 2021,17:62-63. [17] 贾文雄,李宗省.祁连山东段降水的水化学特征及离子来源研究[J]. 环境科学, 2016,37(9):3322-3332. Jia W X, Li Z X. Hydrochemical characteristics and sources of ions in precipitation at the East Qilian Mountains[J]. Environmental Science, 2016,37(9):3322-3332. [18] Xu Z, Wu Y, Liu W J, et al. Chemical composition of rainwater and the acid neutralizing effect at Beijing and Chizhou city, China[J]. Atmospheric Research, 2015,164:278-285. [19] 邢建伟,宋金明.中国近海大气颗粒物来源解析研究进展[J]. 环境化学, 2023,42(3):942-962. Xing J W, Song J M. Source apportionment of atmospheric particulates in China sea:A review[J]. Environmental Chemistry, 2023,42(3):942-962. [20] 杨璟爱,韩少强,杨健安,等.天津降水季节特征及不同气团来向离子来源分析[J]. 中国环境科学, 2023,43(4):1844-1856. Yang J A, Han S Q, Yang J A, et al. Seasonal characteristics of precipitation in Tianjin and sources of ion from different air masses[J]. China Environmental Science, 2023,43(4):1844-1856. [21] 方言,曹芳,范美益,等.中国东海近海岛屿冬季与夏季气溶胶中水溶性离子化学组分特征及来源解析[J]. 环境科学, 2020,41(3):1025-1035. Fang Y, Cao F, Fan M Y, er al. Chemical characteristics and source apportionment of water-soluble ions in atmosphere aerosols over the East China Sea island during winter and summer[J]. Environmental Science, 2020,41(3):1025-1035. [22] 张国忠,崔阳,潘月鹏,等.渤海湾大气金属元素沉降和来源解析研究[J]. 环境科学学报, 2019,39(8):2708-2716. Zhang G Z, Cui Y, Pan Y P, et al. Deposition fluxes and source apportionment of atmospheric trace metals in the Bohai Bay[J]. Acta Scientiae Circumstantiae, 39(8):2708-2716. [23] Ding X, Qi J, Meng X. Characteristics and sources of organic carbon in coastal and marine atmospheric particulates over East China[J]. Atmospheric Research, 2019,228:281-291. [24] QX/T 372-2017酸雨和酸雨区等级[S]. QX/T 372-2017 Grades of acid rain and acid rain aera[S]. [25] 刘建军,郭萌萌,孙军,等.2016~2020年济南市大气降水化学组分变化特征及来源分析[J]. 环境监控与预警, 2022,14(6):64-70. Liu J J, Guo M M, Sun J, et al. Variation characteristics and sources of chemical components of precipitation in Jinan from 2016 to 2020[J]. Environmental Monitoring and Forewarning, 2022,14(6):64-70. [26] Du W, Hong Z, Chen Y, et al. Spatiotemporal distribution and source apportionment of low molecular weight organic acids in wet precipitation at a coastal city, China[J]. Environment Science Pollution Research, 2017,24:8399-8410. [27] 杨笑影,曹芳,林煜棋,等.南京北郊降水无机离子和有机酸的化学特征及来源分析[J]. 环境科学, 2020,41(6):2519-2528. Yang X Y, Cao F, Lin Y Q, et al. Characteristics and sources of inorganic ions and organic acids in precipitation in the northern suburb of Nanjing, China[J]. Environmental Science, 2020,41(6):2519-2528. [28] Zou C W, Yang X Y, Zhang Y K, et al. Characteristics and distribution of inorganic ions in segmented precipitation and contribution of below-cloud/in-cloud scavenging in Nanchang[J]. Air Quality, Atmosphere and Health, 2022,15:903-916. [29] 姚小红,郝吉明,王玮,等.厦门海岸气溶胶中氯亏损研究[J]. 中国环境科学, 1998,18(1):34-38. Yao X H, Hao J M, Wang W, et al. Chloride depletion in coastal aerosol at Xiamen[J]. China Environmental Science, 1998,18(1):34-38. [30] 王珉,胡敏.青岛沿海大气气溶胶中氯亏损的研究[J]. 环境科学学报, 2000,40:40-43. Wang M, Hu M. Chloride depletion in Qingdao coastal aerosol[J]. Acta Scientiae Circumstantiae, 2000,40:40-43. [31] 张棕巍,胡恭任,于瑞莲,等.厦门市大气PM2.5中水溶性离子污染特征及来源解析[J]. 中国环境科学, 2016,36(7):1947-1954. Zhang Z W, Hu G R, Yu R L, et al. Characteristics and sources apportionment of water-soluble ions in PM2.5 of Xiamen City, China[J]. China Environmental Science, 2016,36(7):1947-1954. [32] 姚星灿,康汉青,杜亚宁,等.基于二次无机气溶胶研究南京冬春季霾污染过程的形成特征和来源解析[J]. 环境化学, 2023,42(12):1-10. Yao X C, Kang H Q, Du Y N, et al. Formation characteristics and source analysis of haze pollution process during winter and spring in Nanjing based on secondary inorganic aerosol[J]. Environmental Chemistry, 2023,42(12):1-10. [33] 张吉,黄柳斌,赵敏,等.海陆交换对崂山臭氧和二次气溶胶的影响[J]. 中国环境科学, 2023,43(6):2683-2693. Zhang J, Huang L B, Zhao M, et al. Effects of sea-land exchange on ozone and secondary aerosols in Mount Lao. China Environmental Science, 2023,43(6):2683-2693. [34] 蒋冰艳,吴尧,李少艾,等.深圳市2010~2017年降水中化学组分特征及来源解析[J]. 环境化学, 2019,38(8):1872-1881. Jiang B Y, Wu Y, Li S A, et al. Chemical compositions and sources of precipitation in Shenzhen from 2010 to 2017[J]. Environmental Chemistry, 2019,38(8):1872-1881. [35] 宋金明,袁华茂,李学刚,等.胶州湾的生态环境演变与营养盐变化的关系[J]. 海洋科学, 2020,44(8):106-117. Song J M, Yuan H M, Li X G, et al. Ecological environment evolution and nutrient variations in Jiaozhou Bay[J]. Marine Sciences, 2020, 44(8):106-117. [36] 徐梦琪,娄琦,崔晓莹,等.胶州湾水体氮磷营养物基准研究[J]. 中国海洋大学学报(自然科学版), 2023,53(3):38-51. Xu M Q, Lou Q, Cui X Y, et al. Study on nutrient criteria of nitrogen and phosphorus in Jiaozhou Bay[J]. Periodical of Ocean University of China, 2023,53(3):38-51. [37] Li R F, Dong X Y, Xie C, et al. Long-term observations of the chemical composition, fluxes and sources of atmospheric wet deposition at an urban site in Xi'an, northwest China[J]. Environmental Monitoring and Assessment, 2022,194(2):68. [38] Xu W, Wen Z, Shang B, et al. Precipitation chemistry and atmospheric nitrogen deposition at a rural site in Beijing, China[J]. Atmospheric Environment, 2020,223:117253. [39] Zhang R, Jing J, Tao J, et al. Chemical characterization and source apportionment of PM2.5 in Beijing:seasonal perspective[J]. Atmospheric Chemistry and Physics, 2013,13(14):7053-7074. [40] 张清华,黎永珊,于奭,等.桂林市大气降水的化学组成特征及来源分析[J]. 环境化学, 2020,39(1):229-239. Zhang Q H, Li Y S, Yu S, et al. Characteristics and source analysis of chemical composition of atmospheric precipitation in Guilin City, Southwest China[J]. Environmental Chemistry, 2020,39(1):229-239. [41] Safai P D, Budhavant K B, Rao P S P, et al. Source characterization for aerosol constituents and changing roles of calcium and ammonium aerosols in the neutralization of aerosol acidity at a semi-urban site in SW India[J]. Atmospheric Research, 2010,98(1):78-88. [42] 韩力慧,时瑞芳,崔建硕,等.北京市典型区域大气亚微米颗粒物理化特性及其来源[J]. 中国环境科学, 2022,42(8):3522-3535. Han L H, Shi R F, Cui J S, et al. Physicochemical characteristics and sources of atmospheric submicro particulate matter at a typical area in Beijing[J]. China Environmental Science, 2022,42(8):3522-3535. |
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