华北地区南部城市秋冬季黑碳来源解析——基于改进后的黑碳仪模型

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Abstract The concentration of black carbon (BC) was measured in Luohe City, southern North China, from September 1, 2022, to February 28, 2023, using a 7-band black carbon meter (AE33), and the variation characteristics of black carbon in autumn and winter in Luohe City were analyzed, and the source apportionment was carried out using the improved potassium ion dynamic constrained black carbon meter model. In addition, the effects of fireworks on eBC_EC and K⁺ during the New Year's Day and Spring Festival were analyzed, in order to provide reasonable suggestions for BC pollution control in cities in southern North China. The results showed that the average concentration of eBC_EC in autumn and winter was 3.62μg/m³, the concentration in winter (5.17μg/m³) was about 2.4times that the autumn concentration (2.15μg/m³), and the daily concentration of eBC_EC revealed a ‘bimodal’ distribution with peaks at 8:00 and 21:00. Using the improved black carbon meter model, it was found that the contribution of BC in autumn and winter was mainly from fossil fuel combustion (74.69±15.63%), followed by biomass combustion contribution (25.31±15.63%), and it was more effective to control the reduction of BC pollution from fossil fuel combustion sources. The average daily concentrations of eBC_EC during fireworks and fireworks firing periods such as New Year's Day, Lantern Festival, and Spring Festival were 11.45, 8.42 and 8.12μg/m³, respectively, which were 2.6, 1.9 and 1.8 times of that during non-fireworks and fireworks periods, respectively. The average daily concentrations of K⁺ during Spring Festival, Lantern Festival, and New Year's Day were 26.11, 16.23, and 5.79 μg/m³, respectively, which were 6.9, 6.3, and 3.6 times of that during non-fireworks and fireworks periods, respectively. The increased rate of K⁺ concentration during the above fireworks discharge period is significantly higher than that of eBC_EC, which will interfere with the results of the constrained model. It is recommended that the data for the fireworks discharge period be excluded when using the model.

Key words： black carbon aethalometer absorption Ångström exponent firecrackers source apportionment

Received: 19 October 2023

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X513

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	XIN Zhi-xuan
	NIU Da-wei
	ZHANG Nan
	YANG Wen
	KONG Shao-fei
	YE Si-hang
	ZHAO Xue-yan
	HAN Bin

Cite this article:

XIN Zhi-xuan,NIU Da-wei,ZHANG Nan等. Source apportionment of black carbon in autumn and winter in a southern city of Northern China: Based on the improved black carbon meter model[J]. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(5): 2386-2398.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2024/V44/I5/2386

[1] 朱晓晶,钱岩,李晓倩,等.黑碳气溶胶的研究现状:定义及对健康、气候等的影响[J].环境科学研究, 2021,34(10):2536-2546. Zhu X J, Qian Y, Li X Q, et al. Research status of black carbon aerosol:Definitions and impacts on health, climate and other welfare[J]. Research of Environmental Sciences, 2021,34(10):2536-2546.
[2] Nienow A M, Roberts J T. Heterogeneous chemistry of carbon aerosols[J]. Annual Review of Physical Chemistry, 2006,57(1):105-128.
[3] 秦世广,汤洁,温玉璞.黑碳气溶胶及其在气候变化研究中的意义[J].气象, 2001,27(11):3-7. Qin S G, Tang J, Wen Y P. Black carbon and its importance in climate change studies[J]. Meteorological Monthly, 2001,27(11):3-7.
[4] Shrestha G, Traina S, Swanston C. Black carbon's properties and role in the environment:a comprehensive review[J]. Sustainability, 2010, 2(1):294-320.
[5] Bond T C, Doherty S J, Fahey D W, et al. Bounding the role of black carbon in the climate system:A scientific assessment:black carbon in the climate system[J]. Journal of Geophysical Research:Atmospheres, 2013,118(11):5380-5552.
[6] Cohen A J, Brauer M, Burnett R, et al. Estimates and 25-year trends of the global burden of disease attributable to ambient air pollution:An analysis of data from the Global Burden of Diseases Study 2015[J]. The Lancet, 2017,389(10082):1907-1918.
[7] 程丁,吴晟,吴兑,等.深圳市城区和郊区黑碳气溶胶对比研究[J].中国环境科学, 2018,38(5):1653-1662. Cheng D, Wu S, Wu D, et al. Comparative study on the characteristics of black carbon aerosols in urban and suburban area of Shenzhen[J]. China Environmental Science, 2018,38(5):1653-1662.
[8] Ding A J, Huang X, Nie W, et al. Enhanced haze pollution by black carbon in megacities in China[J]. Geophysical Research Letters, 2016,43(6):2873-2879.
[9] Twomey S. The influence of pollution on the shortwave Albedo of clouds[J]. Journal of the Atmospheric Sciences, 1977,34(7):1149-1152.
[10] Luben T J, Nichols J L, Dutton S J, et al. A systematic review of cardiovascular emergency department visits, hospital admissions and mortality associated with ambient black Carbon[J]. Environment International, 2017,107:154-162.
[11] 徐海保,马楠,杨争,等.华南高山背景地区黑碳云内清除特征[J].中国环境科学, 2022,42(10):4475-4485. Xu H B, Ma N, Yang Z, et al. In-cloud scavenging characteristics of black carbon in the mountain background region of South China[J]. China Environmental Science, 2022,42(10):4475-4485.
[12] 欧奕含,张小玲,张莹,等.西安BC、PM_2.5与气温协同对心脑血管疾病死亡的影响[J].中国环境科学, 2021,41(9):4415-4425. Ou Y H, Zhang X L, Zhang Y, et al. Influence of BC, PM_2.5, temperature and their synergy on mortality of cardiovascular diseases in Xi'an[J]. China Environmental Science, 2021,41(9):4415-4425.
[13] Riddle S G, Robert M A, Jakober C A, et al. Size-resolved source apportionment of airborne particle mass in a roadside environment[J]. Environmental Science&Technology, 2008,42(17):6580-6586.
[14] Green M C, Chow J C, Chang M O, et al. Source apportionment of atmospheric particulate carbon in Las Vegas, Nevada, USA[J]. Particuology, 2013,11(1):110-118.
[15] Gianini M F D, Fischer A, Gehrig R, et al. Comparative source apportionment of PM₁₀ in Switzerland for 2008/2009 and 1998/1999 by Positive Matrix Factorisation[J]. Atmospheric Environment, 2012,54:149-158.
[16] Herich H, Hueglin C, Buchmann B. A 2.5 year's source apportionment study of black carbon from wood burning and fossil fuel combustion at urban and rural sites in Switzerland[J]. Atmospheric Measurement Techniques, 2011,4(7):1409-1420.
[17] Zhang Y L, Li J, Zhang G, et al. Radiocarbon-Based source apportionment of carbonaceous aerosols at a regional background site on Hainan Island, South China[J]. Environmental Science&Technology, 2014,48(5):2651-2659.
[18] Liu J, Li J, Liu D, et al. Source apportionment and dynamic changes of carbonaceous aerosols during the haze bloom-decay process in China based on radiocarbon and organic molecular tracers[J]. Atmospheric Chemistry and Physics, 2016,16(5):2985-2996.
[19] Díaz-Robles L A, Fu J S, Reed G D. Modeling and source apportionment of diesel particulate matter[J]. Environment International, 2008,34(1):1-11.
[20] Zhao S, Tie X, Cao J, et al. Seasonal variation and four-year trend of black carbon in the Mid-west China:The analysis of the ambient measurement and WRF-Chem Modeling[J]. Atmospheric Environment, 2015,123:430-439.
[21] Li N, He Q, Tie X, et al. Quantifying sources of elemental carbon over the Guanzhong Basin of China:A consistent network of measurements and WRF-Chem Modeling[J]. Environmental Pollution, 2016,214:86-93.
[22] Sandradewi J, Prévôt A S H, Szidat S, et al. Using aerosol light absorption measurements for the quantitative determination of wood burning and traffic emission contributions to particulate matter[J]. Environmental Science&Technology, 2008,42(9):3316-3323.
[23] Favez O, El Haddad I, Piot C, et al. Inter-comparison of source apportionment models for the estimation of wood burning aerosols during wintertime in an Alpine City (Grenoble, France)[J]. Atmospheric Chemistry and Physics, 2010,10(12):5295-5314.
[24] Briggs N L, Long C M. Critical review of black carbon and elemental carbon source apportionment in Europe and the United States[J]. Atmospheric Environment, 2016,144:409-427.
[25] Gianini M F D, Piot C, Herich H, et al. Source apportionment of PM₁₀, organic carbon and elemental carbon at Swiss sites:An intercomparison of different Approaches[J]. Science of the Total Environment, 2013,454-455:99-108.
[26] McClure C D, Lim C Y, Hagan D H, et al. Biomass-burning-derived particles from a wide variety of fuels-Part 1:Properties of primary particles[J]. Atmospheric Chemistry and Physics, 2020,20(3):1531-1547.
[27] Lack D A, Cappa C D. Impact of brown and clear carbon on light absorption enhancement, single scatter albedo and absorption wavelength dependence of black carbon[J]. Atmospheric Chemistry and Physics, 2010,10(9):4207-4220.
[28] Wu C, Wu D, Yu J Z. Quantifying black carbon light absorption enhancement with a novel statistical approach[J]. Atmospheric Chemistry and Physics, 2018,18(1):289-309.
[29] Liu C, Chung C E, Yin Y, et al. The absorption Ångström exponent of black carbon:from numerical aspects[J]. Atmospheric Chemistry and Physics, 2018,18(9):6259-6273.
[30] You R, Radney J G, Zachariah M R, et al. Measured wavelength-dependent absorption enhancement of internally mixed black carbon with absorbing and nonabsorbing materials[J]. Environmental Science&Technology, 2016,50(15):7982-7990.
[31] Tami C, Robert W. Light absorption by carbonaceous particles:an investigative review[J]. Aerosol Science and Technology, 2006,40(1):27-67.
[32] Blanco-Alegre C, Calvo A I, Alves C, et al. Aethalometer measurements in a road tunnel:A step forward in the characterization of black carbon emissions from Traffic[J]. Science of The Total Environment, 2020,703:135483.
[33] Kirchstetter T W, Novakov T, Hobbs P V. Evidence that the spectral dependence of light absorption by aerosols is affected by organic carbon[J]. Journal of Geophysical Research:Atmospheres, 2004,109(D21).
[34] Reid J S, Eck T F, Christopher S A, et al. A review of biomass burning emissions Part III:Intensive optical properties of biomass burning particles[J]. Atmospheric Chemistry and Physics, 2005,5(3):827-849.
[35] Lewis K, Arnott W P, Moosmüller H, et al. Strong spectral variation of biomass smoke light absorption and single scattering albedo observed with a novel dual-wavelength photoacoustic Instrument[J]. Journal of Geophysical Research, 2008,113(D16):D16203.
[36] Zheng H, Kong S, Chen N, et al. A method to dynamically constrain black carbon aerosol sources with online monitored Potassium[J]. Npj Climate and Atmospheric Science, 2021,4(1):43.
[37] Hu Y, Kong S, Zheng H, et al. Chemical compositions, sources, and intra-regional transportation of submicron particles between North China Plain and Twain-Hu Basin of Central China in winter[J]. Journal of Geophysical Research:Atmospheres, 2022,127(24).
[38] Wang N, Zhao X, Wang J, et al. Chemical composition of PM_2.5 and its impact on inhalation health risk evaluation in a city with light industry in Central China[J]. Atmosphere, 2020,11:340.
[39] Sandradewi J, Prévôt A S H, Weingartner E, et al. A study of wood burning and traffic aerosols in an Alpine valley using a multi-wavelength Aethalometer[J]. Atmospheric Environment, 2008,42(1):101-112.
[40] Drinovec L, Močnik G, Zotter P, et al. The"dual-spot "Aethalometer:An improved measurement of aerosol black carbon with real-time loading compensation[J]. Atmospheric Measurement Techniques, 2015,8(5):1965-1979.
[41] Chow J C, Watson J G, Crow D, et al. Comparison of IMPROVE and NIOSH carbon measurements[J]. Aerosol Science and Technology, 2001,34(1):23-34.
[42] Tian J, Wang Q, Ni H, et al. Emission characteristics of primary brown carbon absorption from biomass and coal burning:Development of an optical emission inventory for China[J]. Journal of Geophysical Research:Atmospheres, 2019,124:1879-1893.
[43] Petzold A, Ogren J A, Fiebig M, et al. Recommendations for reporting" black carbon"measurements[J]. Atmospheric Chemistry and Physics, 2013,13(16):8365-8379.
[44] Zhao G, Yu Y, Tian P, et al. Evaluation and correction of the ambient particle sectral light absorption measured using a filter-based aethalometer[J]. Aerosol and Air Quality Research, 2020,20:1833-1841.
[45] 王璐,袁亮,张小玲,等.成都地区黑碳气溶胶变化特征及其来源解析[J].环境科学, 2020,41(4):1561-1572. Wang L, Yuan L, Zhang X L, et al. Characteristics and source apportionment of black carbon in Chengdu[J]. Environmental Science, 2020,41(4):1561-1572.
[46] Fuller G W, Tremper A H, Baker T D, et al. Contribution of wood burning to PM₁₀ in London[J]. Atmospheric Environment, 2014,87:87-94.
[47] Helin A, Niemi J V, Virkkula A, et al. Characteristics and source apportionment of black carbon in the Helsinki metropolitan area, Finland[J]. Atmospheric Environment, 2018,190:87-98.
[48] Taylor K E. Summarizing multiple aspects of model performance in a single diagram[J]. Journal of Geophysical Research:Atmospheres, 2001,106(D7):7183-7192.
[49] Vecchi R, Bernardoni V, Cricchio D, et al. The impact of fireworks on airborne particles[J]. Atmospheric Environment, 2008,42(6):1121-1132.
[50] Chhabra A, Turakhia T, Sharma S, et al. Environmental impacts of fireworks on aerosol characteristics and radiative properties over a mega city, India[J]. City and Environment Interactions, 2020,7:100049.
[51] Barman N, Gokhale S. Urban black carbon-source apportionment, emissions and long-range transport over the Brahmaputra River Valley[J]. Science of the Total Environment, 2019,693.
[52] 车军辉,赵平,史茜,等.大气边界层研究进展[J].地球物理学报, 2021,64(3):735-751. Che J H, Zhao P, Shi Q, et al. Research progress in atmospheric boundary layer. Chinese Journal of Geophysics. 2021,64(3):735-751.
[53] Tyagi S, Tiwari S, Mishra A, et al. Characteristics of absorbing aerosols during winter foggy period over the National Capital Region of Delhi:impact of planetary boundary layer dynamics and solar radiation flux[J]. Atmospheric Research, 2017,188:1-10.
[54] Tiwari S, Srivastava A K, Bisht D S, et al. Diurnal and seasonal variations of black carbon and PM_2.5 over New Delhi, India:influence of meteorology[J]. Atmospheric Research, 2013,125126:50-62.
[55] Henry G, Rodriguez D. Robust nonparametric regression on Riemannian manifolds[J]. Journal of Nonparametric Statistics, 2009, 21(5):611-628.