H<sub>2</sub>O<sub>2</sub>辅助污泥水热过程水DOM的光化学行为研究

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Abstract In this study, HTC and 4% H₂O₂-assisted HTC were used to treat dewatered sludge. Based on the determination of the basic physicochemical properties of the two process-water DOMs, we focused on comparing the photobleaching behaviors of the two DOMs and the generation of photogenerated species. The results showed that DOM derived from H₂O₂-assisted HTC process water had lower pH, higher conductivity, TOC, humic-like substance content, aromatic functional groups, molecular weight, and degree of humification, and exhibited greater photosensitivity compared to DOM form HTC process water. Under the simulated natural light irradiation conditions, the aromaticity and humicity of DOM decreased with the prolongation of light exposure, and the content of fluorescent components in DOM decreased significantly, with the humic-like components decreasing most significantly. During the irradiation process, more singlet oxygen (¹O₂) and triplet excited state (³DOM*) were generated, which can significantly promote the photodegradation of tetracycline (93.22%), and ³DOM* played a leading role. This study clarifies the photochemical behavior of DOM derived from H₂O₂-assisted HTC, which can provide a theoretical basis for the further treatment and utilization of process water produced by HTC of sludge.

Key words： assisted hydrothermal carbonization dissolved organic matter photobleaching photodegradation tetracycline

Received: 23 November 2023

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X703

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	ZHANG Chuang
	WANG Bing-yu
	XIE Hui-fang
	FENG Yan-fang
	QU Hong-xia

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ZHANG Chuang,WANG Bing-yu,XIE Hui-fang等. Photochemical behavior of dissolved organic matter in process water from hydrogen peroxide assisted hydrothermal carbonization of sludge[J]. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(6): 3179-3188.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2024/V44/I6/3179

[1] Bevan E, Fu J L, Luberti M, et al. Challenges and opportunities of hydrothermal carbonisation in the UK; case study in Chirnside[J]. Rsc Advances, 2021,11(55):34870-34897.
[2] Kang S M, Li X L, Fan J, et al. Characterization of hydrochars produced by hydrothermal carbonization of lignin, cellulose, d-Xylose, and wood meal[J]. Industrial&Engineering Chemistry Research, 2012,51(26):9023-9031.
[3] Libra J A, Ro K S, Kammann C, et al. Hydrothermal carbonization of biomass residuals:a comparative review of the chemistry, processes and applications of wet and dry pyrolysis[J]. Biofuels, 2014,2(1):71-106.
[4] Fernández-Sanromán A, Lama G, Pazos M, et al. Bridging the gap to hydrochar production and its application into frameworks of bioenergy, environmental and biocatalysis areas[J]. Bioresource Technology, 2021,320:13.
[5] 赵博玮,牛宇锟,谢飞,等.剩余污泥碳化裂解液的资源化中试研究[J].中国给水排水, 2021,37(19):1-6. Zhao B W, Niu Y K, Xie F, et al. Pilot-scale study on resource recycling of excess sludge carbonized pyrolysis liquid[J]. China Water&Wastewater, 2021,37(19):1-6.
[6] Usman M, Chen H H, Chen K F, et al. Characterization and utilization of aqueous products from hydrothermal conversion of biomass for bio-oil and hydro-char production:A review[J]. Green Chemistry, 2019,21(7):1553-1572.
[7] Merzari F, Langone M, Andreottola G, et al. Methane production from process water of sewage sludge hydrothermal carbonization. A review. Valorising sludge through hydrothermal carbonization[J]. Critical Reviews in Environmental Science and Technology, 2019,49(11):947-988.
[8] 胡振坤,张守玉,张一帆,等.H₂O₂对城市污泥水热氧化产物的影响分析[J].热能动力工程, 2021,36(5):134-140. Hu Z K, Zhang S Y, Zhang Y F, et al. Effects of H₂O₂ on hydrothermal oxidation products of municipal sludge[J]. Journal of Engineering for Thermal Energy and Power, 2021,36(5):134-140.
[9] 张培争,张守玉,张一帆,等.H₂O₂添加对城市污泥水热处理产物理化特性的影响[J].环境工程学报, 2021,15(9):2996-3003. Zhang P Z, Zhang S Y, Zhang Y F, et al. Effects of H₂O₂ addition on the physicochemical properties of the hydrothermal products from municipal sludge[J]. Chinese Journal of Environmental Engineering, 2021,15(9):2996-3003.
[10] Zhang Y F, Zhang S Y, Li H, et al. Treatment of municipal sludge by hydrothermal oxidation process with H₂O₂[J]. Chemosphere, 2020, 257:6.
[11] Wang X, Shen Y, Liu X, et al. Fly ash and H₂O₂ assisted hydrothermal carbonization for improving the nitrogen and sulfur removal from sewage sludge[J]. Chemosphere, 2022,290:133209.
[12] Gao Y and Zhang Y H. Formation and photochemical investigation of brown carbon by hydroxyacetone reactions with glycine and ammonium sulfate[J]. Rsc Advances, 2018,8(37):20719-20725.
[13] Niu X Z, Liu C, Gutierrez L, et al. Photobleaching-induced changes in photosensitizing properties of dissolved organic matter[J]. Water Research, 2014,66:140-148.
[14] Zhou Z C, Chen B N, Qu X L, et al. Dissolved black carbon as an efficient sensitizer in the photochemical transformation of 17β-Estradiol in aqueous solution[J]. Environmental Science&Technology, 2018,52(18):10391-10399.
[15] Sharpless C M. Lifetimes of triplet dissolved natural organic matter (DOM) and the effect of NaBH₄ reduction on singlet oxygen quantum yields:Implications for DOM photophysics[J]. Environmental Science&Technology, 2012,46(8):4466-4473.
[16] 邹继颖,宫婉婷,翁士睿,等.秸秆DOM对光催化降解四环素废水的影响[J].北华大学学报, 2021,22(1):102-105. Zou J Y, Gong W T, Weng S R, et al. Effect of straw DOM on photocatalytic degradation of tetracycline waste water[J]. Journal of Beihua University, 2021,22(1):102-105.
[17] Liu Y F, Wang M L, Yin S J, et al. Comparing photoactivities of dissolved organic matter released from rice straw-pyrolyzed biochar and composted rice straw[J]. Environmental Science&Technology, 2022,56(4):2803-2815.
[18] Fu H Y, Liu H T, Mao J D, et al. Photochemistry of dissolved black carbon released from biochar:Reactive oxygen species generation and phototransformation[J]. Environmental Science&Technology, 2016, 50(3):1218-1226.
[19] Lai C C, He H, Liao Z C, et al. Variation in photochemical properties of dissolved black carbon during bio-transformation and iron mineral fractionation process[J]. Science of the Total Environment, 2023, 891:11.
[20] Han X X, Li Y B, Li D, et al. Role of free radicals/reactive oxygen species in MeHg photodegradation:Importance of utilizing appropriate scavengers[J]. Environmental Science&Technology, 2017,51(7):3784-3793.
[21] Leng L J, Zhang W J, Peng H Y, et al. Nitrogen in bio-oil produced from hydrothermal liquefaction of biomass:A review[J]. Chemical Engineering Journal, 2020,401:126030.
[22] Zheng X, Jiang Z, Ying Z, et al. Role of feedstock properties and hydrothermal carbonization conditions on fuel properties of sewage sludge-derived hydrochar using multiple linear regression technique[J]. Fuel, 2020,271:117609.
[23] Liu X, Zhai Y, Li S, et al. Hydrothermal carbonization of sewage sludge:Effect of feed-water pH on hydrochar's physicochemical properties, organic component and thermal behavior[J]. Journal of Hazardous Materials, 2020,388:122084.
[24] Xu Z X, Shan Y Q, Zhang Z, et al. Hydrothermal carbonization of sewage sludge:effect of inorganic salts on hydrochar's physicochemical properties[J]. Green Chemistry, 2020,22(20):7010-7022.
[25] Xu J Q, Zhang S Y, Zhou Y, et al. Comparative study on the properties of wood vinegar prepared from the pretreated Chinese fir:Effect of hydrothermal parameters and hydrogen peroxide[J]. Journal of Analytical and Applied Pyrolysis, 2022,167:105674.
[26] 任冬,王涛,陈芳,等.次氯酸钠对水中腐殖酸结构及光学特性的影响[J].中国环境科学, 2018,38(6):2264-2272. Ren D, Wang T, Chen F, et al. Effect of sodium hypochlorite on the structural and optical characteristics of humic acid in waters[J]. China Environmental Science, 2018,38(6):2264-2272.
[27] 蒋何静,刘慧,张玉婷,等.氯化消毒对溶解性有机质光化学活性影响研究进展[J].中国环境科学, 2023,43(5):2310-2318. Jiang H J, Liu H, Zhang Y T, et al. Research progress in the effect of chlorination disinfection on the photochemical activity of dissolved organic matter[J]. China Environmental Science, 2023,43(5):2310-2318.
[28] Zhang P, Shao Y F, Xu X J, et al. Phototransformation of biochar-derived dissolved organic matter and the effects on photodegradation of imidacloprid in aqueous solution under ultraviolet light[J]. Science of the Total Environment, 2020,724:137913.
[29] Ward C P, Sleighter R L, Hatcher P G, et al. Insights into the complete and partial photooxidation of black carbon in surface waters[J]. Environmental Science-Processes&Impacts, 2014,16(4):721-731.
[30] Helms J R, Mao J D, Stubbins A, et al. Loss of optical and molecular indicators of terrigenous dissolved organic matter during long-term photobleaching[J]. Aquatic Sciences, 2014,76(3):353-373.
[31] 刘堰杨,孙辉,刘琛,等.川西高原河流水体CDOM的光化学降解特性[J].环境科学, 2019,40(12):5318-5329. Liu Y Y, Sun H, Liu S, et al. Characteristics of chromophoric dissolved organic matter (CDOM) in natural rivers of western Sichuan plateau[J]. Environmental Science, 2019,40(12):5318-5329.
[32] Lambert T, Bouillon S, Darchambeau F, et al. Effects of human land use on the terrestrial and aquatic sources of fluvial organic matter in a temperate river basin (The Meuse River, Belgium)[J]. Biogeochemistry, 2017,136(2):191-211.
[33] Kim J, Song B C, Kim T H. Origin of dissolved organic carbon under phosphorus-limited coastal-bay conditions revealed by fluorescent dissolved organic matter[J]. Frontiers in Marine Science, 2022,9:971550.
[34] Hong H L, Wu S J, Wang Q, et al. Trace metal pollution risk assessment in urban mangrove patches:Potential linkage with the spectral characteristics of chromophoric dissolved organic matter[J]. Environmental Pollution, 2021,272:115996.
[35] Winter A R, Fish T A E, Playle R C, et al. Photodegradation of natural organic matter from diverse freshwater sources[J]. Aquatic Toxicology, 2007,84(2):215-222.
[36] 李海斌,谢发之,李国莲,等.南漪湖上覆水溶解性有机质的光谱特征[J].中国环境科学, 2022,42(7):3306-3315. Li H B, Xie F Z, Li G L, et al. Spectral characteristics of dissolved organic matter in the overlying water from Nanyi Lake[J]. China Environmental Science, 2022,42(7):3306-3315.
[37] Maie N, Parish K J, Watanabe A, et al. Chemical characteristics of dissolved organic nitrogen in an oligotrophic subtropical coastal ecosystem[J]. Geochimica et Cosmochimica Acta, 2006,70(17):4491-4506.
[38] McElmurry S P, Long D T, Voice T C. Stormwater dissolved organic matter:Influence of land cover and environmental factors[J]. Environmental Science&Technology, 2013,48(1):45-53.
[39] 王斌,黄廷林,李楠,等.水源水库沉积物及其上覆水DOM光谱特征[J].中国环境科学, 2022,42(3):1309-1317. Wang B, Huang T L, Li N, et al. Spectral characteristics of dissolved organic matter in sediment and overlying water of water source reservoir[J]. China Environmental Science, 2022,42(3):1309-1317.
[40] Ohno T. Fluorescence inner-filtering correction for determining the humification index of dissolved organic matter[J]. Environmental Science&Technology, 2002,36(4):742-746.
[41] Chin K K, Trevithick-Sutton C C, McCallum J, et al. Quantitative determination of singlet oxygen generated by excited state aromatic amino acids, proteins, and immunoglobulins[J]. Journal of the American Chemical Society, 2008,130(22):6912-6913.
[42] Feng Z J, Fan Z L, Song H P, et al. Biochar induced changes of soil dissolved organic matter:The release and adsorption of dissolved organic matter by biochar and soil[J]. Science of the Total Environment, 2021,783:147091.
[43] Golanoski K S, Fang S, Del Vecchio R, et al. Investigating the mechanism of phenol photooxidation by humic substances[J]. Environmental Science&Technology, 2012,46(7):3912-3920.
[44] Chen H M, Abdulla H A N, Sanders R L, et al. Production of black carbon-like and aliphatic molecules from terrestrial dissolved organic matter in the presence of sunlight and iron[J]. Environmental Science&Technology Letters, 2014,1(10):399-404.
[45] Cory R M, McNeill K, Cotner J P, et al. Singlet oxygen in the coupled photochemical and biochemical oxidation of dissolved organic matter[J]. Environmental Science&Technology, 2010,44(10):3683-3689.
[46] 张宵,刘一帆,刘强,等.溶解性黑碳促进水环境中四环素的光降解[J].环境化学, 2023,42(6):2064-2075. Zhang X, Liu Y F, Liu Q, et al. Dissolved black carbon enhanced the photodegradation of tetracycline in aqueous solution[J]. Environmental Chemistry, 2023,42(6):2064-2075.