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| Vertical distribution of atmospheric ozone in Hangzhou Region |
| QI Bing1,2, XU Xiao-fei2, JIN Jun-li3, YANG Xin-Jie1, NIU Yu-wen4, ZHANG Jin-qiang5,6 |
1. Hangzhou Meteorological Bureau, Hangzhou 310051, China;
2. Zhejiang Lin'an Atmospheric Background National Observation and Research Station, Hangzhou 311307, China;
3. Meteorological Observation Center of CMA, Beijing 100081, China;
4. Zhejiang Institute of Meteorological Sciences, Hangzhou 310056, China;
5. Key Laboratory of Middle Atmosphere and Global Environment Observation, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China;
6. College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China |
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Abstract By using the domestic ECC ozonesonde to conduct one year (December 2021 to November 2022) measurements in Hangzhou,this paper investigated the characteristics of vertical ozone distribution, total column ozone and tropospheric column ozone, and evaluated the ozone profile products retrieved from the Atmospheric Infrared Sounder (AIRS) onboard the Aqua satellite and Microwave Limb Sounder (MLS) onboard the Aura satellite, and also compared the total column ozone products retrieved from AIRS, OMI DOAS and TROPOMI. The results indicated a high consistency of surface ozone measurements between the ozonesonde and ground-based ozone analyzer. The vertical ozone structure exhibited significant monthly variation in Hangzhou. A descending structure of high ozone transmission was observed in the upper troposphere-lower stratosphere region (12~16km) in May, and a high ozone content layer was observed in the boundary layer below 1.5km from April to September. The ozone concentration in the boundary layer was highest in summer, with inconspicuous vertical variation, which was followed by that in spring, autumn and winter when the ozone concentration increased with the increase of height. The ozonesonde measurements and satellite retrievals showed similar variability in the vertical ozone profiles, with a relative difference mostly <10% in the height range analyzed. The average total column ozone and tropospheric column ozone were 302.1DU and 40.5DU, respectively, which showed obviously seasonal variation. The total column ozone and the tropospheric column ozone were highest in spring and summer, respectively, and the tropospheric column ozone was highest in May. The total column ozone from ozonesonde measurements showed a good agreement with the products retrieved by AIRS, OMI DOAS and TROPOMI, with correlation coefficients of 0.78, 0.88, and 0.76, respectively.
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Received: 27 February 2024
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[1] Gaudel A, Cooper O R, Gérard A, et al. Tropospheric ozone assessment report: present-day distribution and trends of tropospheric ozone relevant to climate and global atmospheric chemistry model evaluation [J]. Elementa-Science of the Anthropocene, 2018,6(1):39.
[2] Farman J D, Gardiner B G, Shanklin J D. Large losses of total ozone in Antarctica reveal seasonal CIOx/NOx interaction [J]. Nature, 1985, 315:207–210.
[3] IPCC. Climate change 2013: the physical science basis: Working Group I contribution to the Fifth assessment report of the Intergovernmental Panel on Climate Change [M]. Cambridge University Press, Cambridge, 2014.
[4] 朱彤,万薇,刘俊,等.世界卫生组织《全球空气质量指南》修订解读[J]. 科学通报, 2022,67(8):697–706. Zhu T, Wan W, Liu J, et al. Insights into the new WHO global air quality guidelines [J]. Science Bulletin, 2022,67(8):697–706.
[5] Zhao Y, Y Li, A Kumar, et al. Separately resolving NOx and VOC contributions to ozone formation [J]. Atmospheric Environment, 2022,285:119224.
[6] 许亦非,崔寅平,朱溢啸,等.广东省区域臭氧污染过程三维输送特征分析与定量来源解析[J]. 中国环境科学, 2023,43(5):2119–2127. Xu Y F, Cui Y P, Zhu Y X, et al. Assessment of three-dimensional transport processes and quantitative source analysis of regional ozone pollution in Guangdong Province [J]. China Environmental Science, 2023,43(5):2119-2127.
[7] 樊文雁,蔡子颖,姚青,等.区域输送对天津臭氧污染的影响[J]. 中国环境科学, 2022,42(11):4991–4999. Fan W Y, Cai Z Y, Yao Q, et al. Effect of regional transport on ozone pollution in Tianjin [J]. China Environmental Science, 2022,42(11): 4991–4999.
[8] Neu J L, Flury T, Manney G L, et al. Tropospheric ozone variations governed by changes in stratospheric circulation [J]. Nature Geoscience, 2014,7:340–344.
[9] Hess P G, Zbinden R. Stratospheric impact on tropospheric ozone variability and trends:1990~2009[J]. Atmospheric Chemistry and Physics, 2013,13(2):649–674.
[10] Li D, Vogel B, Müller R, et al. High tropospheric ozone in Lhasa within the Asian summer monsoon anticyclone 2013: influence of convective transport and stratospheric intrusions [J]. Atmospheric Chemistry and Physics, 2018,18(24):17979–17994.
[11] Stauffer R M, Thompson A M, Young G S. Tropospheric ozonesonde profiles at long-term US monitoring sites: 1. A climatology based on self-organizing maps [J]. Journal of Geophysical Research: Atmospheres, 2016,121:1320–1339.
[12] Fu Y, Liao H, Yang Y. Interannual and decadal changes in tropospheric ozone in China and the associated chemistry-climate interactions: A review [J]. Advances in Atmospheric Sciences, 2019,36(9):975–993.
[13] Li J, Nagashima T, Kong L, et al. Model evaluation and intercomparison of surface-level ozone and relevant species in East Asia in the context of MICS-Asia Phase III – Part 1: Overview [J]. Atmospheric Chemistry and Physics, 2019,19(20):12993–13015.
[14] Komhyr W D. Electrochemical concentration cells for gas analysis [J]. Annals of Geophysics, 1969,25:203–210.
[15] Terao Y, Logan J A. Consistency of time series and trends of stratospheric ozone as seen by ozonesonde, SAGE II, HALOE, and SBUV(/2) [J]. Journal of Geophysical Research: Atmospheres, 2007, 112(D6):D06310.
[16] Thompson A M, Oltmans S J, Tarasick D W, et al. Strategic ozone sounding networks: review of design and accomplishments [J]. Atmospheric Environment, 2011,45(13):2145–2163.
[17] Stauffer R M, Thompson A M, Witte J C. Characterizing global ozonesonde profile variability from surface to the UT/LS with a clustering technique and MERRA-2reanalysis [J]. Journal of Geophysical Research: Atmospheres, 2018,123(11):6213–6229.
[18] 孔琴心,王庚辰,刘广仁,等.大气臭氧垂直分布的电化学测量[J]. 大气科学, 1992,16(5):636–640. Kong Q X, Wang G C, Liu G R, et al. A electrochemical measurement of the vertical distribution of ozone in the atmosphere [J]. Chinese Journal of Atmospheric Sciences, 1992,16(5):636–640.
[19] 王庚辰,孔琴心,宣越健,等.中国大气臭氧探空仪的研制和应用[J]. 地球科学进展, 2003,18(3):471–475. Wang G C, Kong Q X, Xuan Y J, et al. Development and application of ozonesonde system in China [J]. Advances in Earth Science, 2003,18(3):471–475.
[20] 宣越健,马舒庆,陈洪滨,等.国产GPSO3与芬兰Vaisala臭氧探空仪的比对试验[J]. 高原气象, 2004,23(3):394–399. Xuan Y J, Ma S Q, Chen H B, et al. Intercomparisons of GPSO3 and Vaisala ECC ozone sondes [J]. Plateau Meteorology, 2004,23(3):394– 399.
[21] Zhang J Q, Xuan Y J, Yan X L, et al. Development and preliminary evaluation of a double-cell ozonesonde [J]. Advances in Atmospheric Sciences, 2014,31:938–947.
[22] 郑向东,宣越健,林伟立,等.国产ECC型O3探空仪性能测试及室外比对观测[J]. 应用气象学报, 2018,29(4):460–473. Zheng X D, Xuan Y J, Lin W L, et al. Performance tests and outdoor comparison observations of domestic remade ECC ozonesondes [J]. Journal of Applied Meteorological Science, 2018,29(4):460–473.
[23] 宗雪梅,王庚辰,陈洪滨,等.北京地区边界层大气臭氧浓度变化特征分析[J]. 环境科学, 2007,28(11):2615–2619. Zong X M, Wang G C, Chen H B, et al. Analysis on concentration variety characteristics of atmospheric ozone under the boundary layer in Beijing [J]. Environmental Science, 2017,28(11):2615–2619.
[24] 郑向东,周秀骥,秦瑜,等.西宁夏季对流层臭氧垂直分布变化与气象要素的关系[J]. 气象学报, 2002,60(1):47–52. Zheng X D, Zhou X J, Qin Y, et al. Ariations in vertical distribution of tropospheric ozone and relationship with meteorological elements over Xinjiang in summer season [J]. Acta Meteorologica Sinica, 2002,60(1): 47–52.
[25] 石广玉,白宇波,岩坂泰信,等.拉萨上空大气臭氧垂直分布的高空气球探测[J]. 地球科学进展, 2000,15(5):522–524. Shi G Y, Bai Y B, Iwasaka Y, et al. A balloon measurement of the ozone vertical distribution over Lahsa [J]. Advances in Earth Science, 2000,15(5):522–524.
[26] 崔宏,赵春生,郑向东,等.2001年春季临安地区对流层臭氧异常增加的一次过程分析[J]. 大气科学, 2005,29(2):259–266. Cui H, Zhao C S, Zheng X D, et al. Analysis of an extraordinary tropospheric ozone enhancement event at Lin’an in the Spring of 2001[J]. Chinese Journal of Atmospheric Sciences, 2005,29(2):259–266.
[27] 彭丽,高伟,耿福海,等.上海地区臭氧垂直分布特征分析[J]. 北京大学学报:自然科学版, 2011,47(5):805–811. Peng L, Gao W, Geng F H, et al. Analysis of ozone vertical distribution in Shanghai area [J]. Aca Scientiarum Naturalium Universitatis Pekinensis, 2011,47(5):805–811.
[28] Song Y S, Lv D R, Li Q, et al. The impact of cut-off lows on ozone in the upper troposphere and lower stratosphere over Changchun from ozonesonde observations [J]. Advances in Atmospheric Sciences, 2016,33:135–150.
[29] Bian J C, Gettelman A, Chen H B, et al. Validation of satellite ozone profile retrievals using Beijing ozonesonde data [J]. Journal of Geophysical Research: Atmospheres, 2007,112(D6):D06305.
[30] Zhang J Q, Li D, Bian J C, et al. Long-term ozone variability in the vertical structure and integrated column over the North China Plain: Results based on ozonesonde and Dobson measurements during 2001–2019[J]. Environmental Research Letters, 2021,16(7):074053.
[31] Zeng Y S, Zhang J Q, Li D, et al. Vertical distribution of tropospheric ozone and its sources of precursors over Beijing: Results from ~ 20years of ozonesonde measurements based on clustering analysis [J]. Atmospheric Research, 2023,284:106610.
[32] Zeng Y S, Zhang J Q, Li Y J, et al. Wavelet analysis of ozone driving factors Based on ~20years of ozonesonde measurements in Beijing [J]. Atmosphere, 2023,14(12):1733.
[33] 齐冰,牛彧文,杜荣光,等.杭州市近地面大气臭氧浓度变化特征分析[J]. 中国环境科学, 2017,37(2):443–451. Qi B, Niu Y W, Du R G, et al. Characteristics of surface ozone concentration in urban site of Hangzhou [J]. China Environmental Science, 2017,37(2):443–451.
[34] 张嘉月,康娜,邵生成,等.杭州地区臭氧污染及台风烟花过程影响[J]. 中国环境科学, 2024,44(3):1195–1203. Zhang J Y, Kang N, Shao S C, et al. Ozone pollution in Hangzhou and the impact of typhoon fireworks process [J]. China Environmental Science, 2024,44(3):1195–1203.
[35] 柯碧钦,何超,杨璐,等.华北地区地表臭氧时空分布特征及驱动因子[J]. 中国环境科学, 2022,42(2):1562–1574. Ke B Q, He C, Yang L, et al. The spatiotemporal variation of surface ozone and the main driving factors in North China [J]. China Environmental Science, 2022,42(2):1562–1574.
[36] 张金强,宣越健,刘明远,等.臭氧探空仪电化学反应池检测设备研制与应用[J]. 气象科技, 2014,42(3):397–401. Zhang J Q, Xuan Y J, Liu M Y, et al. Development and application of test system for electrochemical concentration cell of ozonesonde [J]. Meteorological Science and Technology, 2014,42(3):397–401.
[37] Zhang J Q, Xuan Y J, Bian J C, et al. Comparison between ozonesonde measurements and satellite retrievals over Beijing,China [J]. Atmospheric and Oceanic Science Letters, 2024,17(1):100378.
[38] McPeters R D, Labow G J. Climatology 2011: An MLS and sonde derived ozone climatology for satellite retrieval algorithms [J]. Journal of Geophysical Research: Atmospheres, 2012,117(D10):D10303.
[39] Tarasick D W, Smit H G, Thompson A M, et al. Improving ECC ozonesonde data quality: Assessment of current methods and outstanding issues [J]. Earth and Space Science, 2021,8(3): e2019EA000914.
[40] Oltmans S J, Johnson B J, Harris M, et al. Tropospheric ozone over the north pacific from ozonesonde observations [J]. Journal of Geophysical Research: Atmospheres, 2004,109:D15S01.
[41] Tong N, Leung D, Liu C. A review on ozone evolution and its relationship with boundary layer characteristics in urban environments [J]. Waste Air Soil Pollution, 2011,214:13–36.
[42] Garrido-perez J M, Ordóňez C, García-Herrera R, et al. The differing impact of air stagnation on summer ozone across Europe [J]. Atmospheric Environment, 2019,219:117062.
[43] Liao Z, Gao M, Zhang J, et al. Mixing-layer-height-referenced ozone vertical distribution in the lower troposphere of Chinese megacities: stratification, classification, and meteorological and photochemical mechanisms [J]. Atmospheric Chemistry and Physics, 2024,24:3541– 3557.
[44] Tang G Q, Zhu X W, Xin J Y, et al. Modelling study of boundary-layer ozone over northern China -Part I: Ozone budget in summer [J]. Atmospheric Research, 2017,187:128–137.
[45] 罗丽彤,章炎麟,林煜棋,等.南京夏季大气臭氧光化学特征与敏感性分析[J]. 环境科学, 2024,45(3):1382–1391. Luo L T, Zhang Y L, Lin Y Q, et al. Analysis of photochemical characteristics and sensitivity of atmospheric ozone in Nanjing in Summer [J]. Environmental Science, 2024,45(3):1382–1391.
[46] Petetin H, Thouret V, Fontaine A, et al. Characterising tropospheric O3 and CO around Frankfurt over the period 1994–2012based on MOZAIC–IAGOS aircraft measurements [J]. Atmospheric Chemistry and Physics, 2016,16:15147–15163.
[47] Tang G Q, Liu Y T, Huang X, et al. Aggravated ozone pollution in the strong free convection boundary layer [J]. Science of the Total Environment, 2021,788:147740.
[48] Murty D, Christopher B, Mitchell G, et al. Evaluation of Atmospheric Infrared Sounder ozone profiles and total ozone retrievals with matched ozonesonde measurements, ECMWF ozone data, and Ozone Monitoring Instrument retrievals [J]. Journal of Geophysical Research, 2008,113:D15308.
[49] Fu D, Kulawik S S, Miyazaki K, et al. Retrievals of tropospheric ozone profiles from the synergism of AIRS and OMI: methodology and validation [J]. Atmospheric Measurement Techniques, 2018,11(10): 5587–5605.
[50] Jiang Y B, Froidevaux L, Lambert A, et al. Validation of Aura Microwave Limb Sounder Ozone by ozonesonde and lidar measurements [J]. Journal of Geophysical Research, 2007,112: D24S34.
[51] Stauffer R M, Morris G A, Thompson A M, et al. Propagation of radiosonde pressure sensor errors to ozonesonde measurements [J]. Atmospheric Measurement Techniques, 2014,7:65–79. |
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