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Research progress on spatiotemporal distribution of carbonaceous aerosols in China |
QI Shao-feng1,2, ZHAO Su-ping1,3, YIN Dai-ying4, YU Ye1,3, HE Jian-jun5 |
1. Key Laboratory of Land Surface Processes and Climate Change in Cold and Arid Regions, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, China; 2. University of Chinese Academy of Sciences, Beijing 100049, China; 3. Pingliang Land Surface Process and Disaster Weather Observation and Research Station, Chinese Academy of Sciences, Pingliang 744015, China; 4. Key Laboratory of Desert and Desertification, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, China; 5. State Key Laboratory of Severe Weather, Chinese Academy of Meteorological Aciences, Beijing 100081, China |
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Abstract By sorting out the research results related to carbonaceous aerosols in recent years in China, the spatiotemporal distribution and climate effect of carbonaceous aerosols in China were systematically summarized. Through the collection of existing offline observation data, it is found that the organic carbon (OC) and elemental carbon (EC) in PM2.5 in field observation points were less than 5μg/m3 and 1μg/m3 respectively, and the OC concentration in urban ranges from 3.78 to 30μg/m3 (the average value was 11.98 μg/m3), the mass concentration range of EC was 0.69~10μg/m3 (the average value was 3.93μg/m3),and the high value are mainly distributed in the Hu Huanyong Line (Heihe-Tengchong Line) and the north regions, such as the northeast region, the Fenwei Plain region, the Beijing-Tianjin-Hebei region, Lanzhou Basin and Sichuan Basin. At the same time, OC/EC and SOC/OC in PM2.5 had similar trends with altitude. Carbonaceous aerosols in the different heights within boundary layer had varying effects. Carbonaceous aerosol at upper layer of the boundary layer could inhibit the development of the boundary layer through the radiation effect, while those near the surface can promote the development of the boundary layer.
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Received: 18 April 2023
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[1] Jimenez J L, Canagaratna M R, Donahue N M, et al. Evolution of organic aerosols in the atmosphere [J].Science, 2009,326(5959): 1525-1529. [2] 李杏茹,王英锋,郭雪清,等.2008年奥运期间北京不同粒径大气颗粒物中元素碳和有机碳的变化特征[J].环境科学, 2011,32(2):313-318. Li X R, Wang Y F, Guo X Q, et al. Size distribution and characterization of EC and OC in aerosols during the Olympics of Beijing, China [J].Environmental Science, 2011,32(2):313-318. [3] Li M R, Hu M, Walker J, et al. Source apportionment of carbonaceous aerosols in diverse atmospheric environments of China by dual-carbon isotope method [J].Science of the Total Environment, 2022,806. [4] Niu Z C, Wang S, Chen J S, et al. Source contributions to carbonaceous species in PM2.5 and their uncertainty analysis at typical urban, peri-urban and background sites in southeast China [J].Environmental Pollution, 2013,181:107-114. [5] Liu D, Vonwiller M, Li J, et al. Fossil and non-fossil fuel sources of organic and elemental carbonaceous aerosol in Beijing, Shanghai, and Guangzhou: Seasonal carbon source variation [J].Aerosol and Air Quality Research, 2020,20(11):2495-2506. [6] 谢添,曹芳,章炎麟,等.2015~2019年南京北郊碳质气溶胶组成变化[J].环境科学, 2022,43(6):2858-2866. Xie T, Cao F, Zhang Y L, et al. Changes in carbonaceous aerosol in the northern suburbs of Nanjing from 2015 to 2019[J].Environmental Science, 2022,43(6):2858-2866. [7] Ding J J, Huang W, Zhao J, et al. Characteristics and source origins of carbonaceous aerosol in fine particulate matter in a megacity, Sichuan Basin, Southwestern China [J].Atmospheric Pollution Research, 2022,13(1). [8] Wang Z, Wang T, Guo J, et al. Formation of secondary organic carbon and cloud impact on carbonaceous aerosols at Mount Tai, North China [J].Atmospheric Environment, 2012,46:516-527. [9] Li P H, Wang Y, Li T, et al. Characterization of carbonaceous aerosols at Mount Lu in South China: implication for secondary organic carbon formation and long-range transport [J].Environmental Science and Pollution Research, 2015,22(18):14189-14199. [10] Zhao S P, Yu Y, Du Z H, et al. Size-resolved carbonaceous aerosols at near surface level and the hilltop in a typical valley city, China [J].Atmospheric Pollution Research, 2020,11(1):129-140. [11] Yin D Y, Zhao S P, Qu J J, et al. The vertical profiles of carbonaceous aerosols and key influencing factors during wintertime over western Sichuan Basin, China [J].Atmospheric Environment, 2020,223: 117269. [12] Zheng N, Song S J, Jin X L, et al. Assessment of carbonaceous aerosols at mount Tai, North China: Secondary formation and regional source analysis [J].Aerosol and Air Quality Research, 2019,19(8): 1708-1720. [13] Cui H, Mao P, Zhao Y, et al. Patterns in atmospheric carbonaceous aerosols in China: emission estimates and observed concentrations [J].Atmospheric Chemistry and Physics, 2015,15(15):8657-8678. [14] Zhang X, Li Z Q, Wang F T, et al. Carbonaceous aerosols in PM1, PM2.5, and PM10 size fractions over the Lanzhou city, Northwest China [J].Atmosphere, 2020,11(12). [15] Zhi G R, Chen Y J, Sun J Y, et al. Harmonizing aerosol carbon measurements between two conventional thermal/optical analysis methods [J].Environment Science Technology, 2011,45(7):2902-2908. [16] Zhang L, Guo X M, Zhao T L, et al. Effect of large topography on atmospheric environment in Sichuan Basin: A climate analysis based on changes in atmospheric visibility [J].Frontiers in Earth Science (Lausanne), 2022,10. [17] Han J Y, Miao C Y, Duan Q Y, et al. Changes in unevenness of wet-day precipitation over China during 1961~2020[J].Journal of Geophysical Research: Atmospheres, 2021,126(19):e2020JD034483. [18] Tang J, Chen S, Li Z, et al. Mapping the distribution of Summer precipitation types over China based on radar observations [J].Remote Sensing, 2022,14(14):3437. [19] Zhang X Y, Cong Z T. Trends of precipitation intensity and frequency in hydrological regions of China from 1956 to 2005[J].Global and Planetary Change, 2014,117:40-51. [20] 高丹,孔庚,麻林巍,等.我国区域能源现状及中长期发展战略重点研究[J].中国工程科学, 2021,23(1):7-14. Gao D, Kun G, Ma L W, et al. Energy development status and developing focus of varied regions in China [J].Strategic Study of CAE, 2021,23(1):7-14. [21] Niu Y W, Li X L, Qi B, et al. Variation in the concentrations of atmospheric PM2.5 and its main chemical components in an eastern China city (Hangzhou) since the release of the air pollution prevention and control action plan in 2013[J].Air Quality, Atmosphere & Health, 2022,15(2):321-337. [22] Wang Q, Fang J L, Shi W Y, et al. Distribution characteristics and policy-related improvements of PM2.5 and its components in six Chinese cities [J].Environment Pollution, 2020,266(3):115299. [23] Zhou S Z, Yang L X, Gao R, et al. A comparison study of carbonaceous aerosols in a typical North China Plain urban atmosphere: Seasonal variability, sources and implications to haze formation [J].Atmospheric Environment, 2017,149:95-103. [24] Huang F, Zhou J B, Chen N, et al. Chemical characteristics and source apportionment of PM2.5 in Wuhan, China [J].Journal of Atmospheric Chemistry, 2019,76(3):245-262. [25] Shi J W, Zhao C Y, Wang Z J, et al. Chemical composition and source apportionment of PM2.5 in a border city in Southwest China [J].Atmosphere, 2022,13(1):7. [26] Shi J W, Feng Y C, Ren L, et al. Mass concentration, chemical composition, and source characteristics of PM2.5 in a plateau slope city in Southwest China [J].Atmosphere, 2021,12(5):611. [27] 赵冰.沈阳市大气PM2.5污染规律及其化学组分分布特征研究[D].沈阳:辽宁大学, 2017. Zhao B. The research of PM2.5 pollution rules and distribution characteristics of chemical components in Shenyang’s atmosphere [D].Shenyang: Liaoning University, 2017. [28] Hong Y H, Cao F, Fan M Y, et al. Impacts of chemical degradation of levoglucosan on quantifying biomass burning contribution to carbonaceous aerosols: A case study in Northeast China [J].Science of The Total Environment, 2022,819. [29] 王幸,张青梅,刘湛,等.张家界市大气PM2.5碳组分污染特征及来源分析[J].湘潭大学学报(自然科学版), 2021,43(6):117-126. Wang X, Zhang Q M, Liu Z, et al. Characteristics and sources of carbonaceous species in atmospheric PM2.5 in Zhangjiajie [J].Journal of Xiangtan University (Natural Science Edition), 2021,43(6):117-126. [30] 唐军婷.焦作市PM2.5污染特征及其煤源分析[D].焦作:河南理工大学, 2016. Tang J T. Pollution characteristics and coal source analysis of PM2.5 in Jiaozuo [D].Jiaozuo: Henan Polytechnic University, 2016. [31] Hu X F, Yin Y Z, Duan L, et al. Temporal and spatial variation of PM2.5 in Xining, northeast of the Qinghai-Xizang (Tibet) Plateau [J].Atmosphere, 2020,11(9):953. [32] 尹寒梅,陈军辉,冯小琼,等.宜宾市PM2.5中碳组分的污染特性及来源分析[J].环境化学, 2019,38(4):738-745. Yin H M, Chen J H, Feng X Q, et al. Pollution characteristics and source analysis of carbonaceous aerosol in PM2.5 in Yibin, China [J].Environmental Chemistry, 2019,38(4):738-745. [33] 曹佳阳,樊晋,罗彬,等.川南四座城市PM2.5化学组分污染特征及其源解析[J].环境化学, 2021,40(2):559-570. Cao J Y, Fan J, Luo B, et al. Pollution characteristics and source apportionment of PM2.5 in four urban environment of Southern Sichuan [J].Environmental Chemistry, 2021,40(2):559-570. [34] Zhao H Y Z, Niu Z C, Zhou W J, et al. Measurement report: Source apportionment of carbonaceous aerosol using dual-carbon isotopes (C-13 and C-14) and levoglucosan in three northern Chinese cities during 2018~2019[J].Atmospheric Chemistry and Physics, 2022, 22(9):6255-6274. [35] Xue F L, Niu H Y, Hu S H, et al. Seasonal variations and source apportionment of carbonaceous aerosol in PM2.5 from a coal mining city in the North China Plain [J].Energy Exploration & Exploration, 2022,40(2):834-851. [36] 罗达通,张敬巧,刘湛,等.郴州市大气PM2.5碳组分污染特征及其来源分析[J].环境科学研究, 2018,31(11):1858-1866. Luo D T, Zhang J Q, Liu Z, et al. Characteristics and sources of carbonaceous species in atmospheric PM2.5 in Chenzhou city. Research of Environmental Sciences, 2018,31(11):1858-1866. [37] Li D P, Wu C, Zhang S, et al. Significant coal combustion contribution to water-soluble brown carbon during winter in Xingtai, China: Optical properties and sources [J].Journal of Environmental Sciences, 2023,124:892-900. [38] 张丹,楚宝临,赵丽,等.拉萨市大气颗粒物碳组分污染特征及来源分析[J].环境影响评价, 2018,40(3):65-70. Zhang D, Chu B L, Zhao L, et al. Characteristics and source of carbonaceous species in PM of Lhasa city [J].Environmental Impact Assessment, 2018,40(3):65-70. [39] 郑晓伍,陈家灯,刘子龙,等.石河子市PM2.5中有机碳和元素碳的变化特征与来源解析[J].环境化学, 2018,37(1):115-122. Zheng X W, Cheng J D, Liu Z L, et al. Characteristics and source apportionment of organic carbon and elemental carbon in PM2.5 in Shihezi, Xinjiang, China [J].Environmental Chemistry, 2018,37(1): 115-122. [40] 李曾曾.三亚市PM2.5化学特征、源解析和健康评价的研究[D].三亚:海南热带海洋学院, 2022. Li Z Z. Study on chemical characteristics, source analysis and health evaluation of PM2.5 in Sanya city [D].Sanya: Hainan Tropical Ocean University, 2022. [41] Duan J, Chen Y, Wang W L, et al. Cable-car measurements of vertical aerosol profiles impacted by mountain-valley breezes in Lushan Mountain, East China [J].Science of The Total Environment, 2021, 768:144198. [42] Yi Y N, Meng J J, Hou Z F, et al. Contrasting compositions and sources of organic aerosol markers in summertime PM2.5 from urban and mountainous regions in the North China Plain [J].Science of The Total Environment, 2021,766:144187. [43] Zhao S P, Qi S F, Yu Y, et al. Measurement report: Contrasting elevation-dependent light absorption by black and brown carbon: lessons from in situ measurements from the highly polluted Sichuan Basin to the pristine Tibetan Plateau [J].Atmospheric Chemistry and Physics, 2022,22(22):14693-14708. [44] Zhao Z Z, Cao J J, Shen Z X, et al. Chemical composition of PM2.5 at a high-altitude regional background site over Northeast of Tibet Plateau [J].Atmospheric Pollution Research, 2015,6(5):815-823. [45] Li C L, Yan F P, Kang S C, et al. Light absorption characteristics of carbonaceous aerosols in two remote stations of the southern fringe of the Tibetan Plateau, China [J].Atmospheric Environment, 2016,143: 79-85. [46] Hu J X, Gong W W, Yin P, et al. Central heating and winter mortality in China: A national study based on 364 Chinese locations [J].Urban Climate, 2022,41:101045. [47] 姜晓彤,杜林.环境因素影响二次有机气溶胶生成的研究进展[J].大气与环境光学学报, 2022,17(1):1-15. Jiang X T, Du L. Research process of influence of environmental factors on secondary organic aerosol formation [J].Journal of Atmospheric and Environmental Optics, 2022,17(1):1-15. [48] Wang D F, Zhou B, Fu Q Y, et al. Intense secondary aerosol formation due to strong atmospheric photochemical reactions in summer: Observations at a rural site in eastern Yangtze River Delta of China [J].The Science of the total environment, 2016,571:1454-1466. [49] Wang L P, Zhou X H, Ma Y J, et al. Carbonaceous aerosols over China-review of observations, emissions, and climate forcing [J].Environmental Science and Pollution Research, 2016,23(2):1671-1680. [50] Zhang H Y, Cheng S Y, Li J B, et al. Investigating the aerosol mass and chemical components characteristics and feedback effects on the meteorological factors in the Beijing-Tianjin-Hebei region, China [J].Environmental Pollution, 2019,244:495-502. [51] Hu T F, Cao J J, Lee S C, et al. Physiochemical characteristics of indoor PM2.5 with combustion of dried yak dung as biofuel in Tibetan Plateau, China [J].Indoor and Built Environment, 2016,25(5):737-747. [52] Sang X F, Zhang Z S, Chan C Y, et al. Source categories and contribution of biomass smoke to organic aerosol over the southeastern Tibetan Plateau [J].Atmospheric Environment, 2013, 78:113-123. [53] Ping X G, Li C W, Jiang Z G. Household energy consumption patterns in agricultural zone, pastoral zone and agro-pastoral transitional zone in eastern part of Qinghai-Tibet Plateau [J].Biomass and Bioenergy, 2013,58:1-9. [54] 关东杰,沈振兴,陈庆彩.棕碳气溶胶的生消机制研究进展[J].环境化学, 2020,39(10):2812-2822. Guan D J, Shen Z X, Chen Q C. Formation and elimination of brown carbon aerosol: A review [J].Environmental Chemistry, 2020,39(10): 2812-2822. [55] Lee S H, Lee S, Kim D B, et al. Concentrations of carbonaceous compounds and quantitation of secondary organic carbon in PM2.5 at Taehwa Research Forest [J].Journal of forest and environmental science, 2018,34:53-56. [56] Wu X F, Vu T V, Shi Z B, et al. Characterization and source apportionment of carbonaceous PM2.5 particles in China—A review [J].Atmospheric Environment, 2018,189:187-212. [57] Wang J D, Zhao B, Wang S X, et al. Particulate matter pollution over China and the effects of control policies [J].Science of The Total Environment, 2017,584-585:426-447. [58] Ma Z W, Liu R Y, Liu Y, et al. Effects of air pollution control policies on PM2.5 pollution improvement in China from 2005 to 2017: A satellite-based perspective [J].Atmospheric Chemistry and Physics, 2019,19(10):6861-6877. [59] Cai S Y, Wang Y J, Zhao B, et al. The impact of the “Air Pollution Prevention and Control Action Plan” on PM2.5 concentrations in Jing-Jin-Ji region during 2012~2020[J].Science of The Total Environment, 2017,580:197-209. [60] Yang F, He K, Ye B, et al. One-year record of organic and elemental carbon in fine particles in downtown Beijing and Shanghai [J].Atmospheric Chemistry and Physics, 2005,5(6):1449-1457. [61] 徐敬.北京城区单点气溶胶细粒子(PM2.5)观测分析与研究[D].北京:中国气象科学研究院, 2003. Xu J. Observation, analysis, and study of fine aerosol particles(PM2.5) at single locations in Beijing urban area [D].Beijing: Chinese Academy of Meteorological Sciences, 2003. [62] 周家茂,曹军骥,张仁健.北京大气中PM2.5及其碳组分季节变化特征与来源[J].过程工程学报, 2009,9(S2):248-252. Zhou J M, Cao J J, Zhang R J. Variations and sources of PM2.5 and its carbonaceous components in Beijing [J].Chinese Journal of Process Engineering, 2009,9(S2):248-252. [63] Zhao P S, Dong F, Yang Y D, et al. Characteristics of carbonaceous aerosol in the region of Beijing, Tianjin, and Hebei, China [J].Atmospheric Environment, 2013,71:389-398. [64] Wang G, Cheng S Y, Li J B, et al. Source apportionment and seasonal variation of PM2.5 carbonaceous aerosol in the Beijing-Tianjin-Hebei region of China [J].Environment Monitoring and Assessment, 2015, 187(3). [65] 樊啸辰,郎建垒,程水源,等.北京市大气环境PM2.5和PM1及其碳质组分季节变化特征及来源分析[J].环境科学, 2018,39(10):4430-4438. Fan X C, Lang J L, Cheng S Y, et al. Seasonal variation and source analysis for PM2.5, PM1 and their carbonaceous components in Beijing [J].Environmental Science, 2018,39(10):4430-4438. [66] Ding A J, Huang X, Nie W, et al. Enhanced haze pollution by black carbon in megacities in China [J].Geophysical Research Letters, 2016, 43(6):2873-2879. [67] Feichter J, Stier P. Assessment of black carbon radiative effects in climate models [J].Wiley interdisciplinary reviews, Climate change, 2012,3(4):359-370. [68] Ban-Weiss G A, Cao L, Bala G, et al. Dependence of climate forcing and response on the altitude of black carbon aerosols [J].Climate Dynamics, 2012,38(5/6):897-911. [69] 唐利琴,胡波,刘慧,等.近十年北京气溶胶光学特性及直接辐射强迫研究[J].气候与环境研究, 2021,26(2):155-168. Tang L Q, Hu B, Liu H, et al. Aerosol optical properties and direct radiative forcing in Beijing in the recent decade [J].Climatic and Environmental Research (in Chinese), 2021,26(2):155-168. [70] Zhao S P, Yu Y, Yin D Y, et al. PM1 carbonaceous aerosols during winter in a typical valley city of western China: Vertical profiles and the key influencing factors [J].Atmospheric Environment, 2019,202: 75-92. [71] Zhao S P, Yin D Y, Yu Y, et al. PM1 chemical composition and light absorption properties in urban and rural areas within Sichuan Basin, southwest China [J].Environmental Pollution, 2021,280:116970. [72] Zhao S P, Yu Y, Yin D Y, et al. Concentrations, optical and radiative properties of carbonaceous aerosols over urban Lanzhou, a typical valley city: Results from in-situ observations and numerical model [J].Atmospheric Environment, 2019,213:470-484. [73] 张靖,银燕.黑碳气溶胶对我国区域气候影响的数值模拟[J].南京气象学院学报, 2008,31(6):852-859. Zhang J, Yin Y. Numerical simulations of effect of black carbon aerosol on regional climate in China [J].Journal of Nanjing Institute of Meteorology, 2008,31(6):852-859. [74] 关攀博,师华定,高庆先,等.中国地区黑碳气溶胶的气候效应模拟[J].环境工程技术学报, 2017,7(4):418-423. Guan P B, Shi H D, Gao Q X, et al. Study on black carbon aerosol simulation of climate effect in China [J].Journal of Environmental Engineering Technology, 2017,7(4):418-423. [75] Wang X P, Gong P, Sheng J J, et al. Long-range atmospheric transport of particulate polycyclic aromatic hydrocarbons and the incursion of aerosols to the southeast Tibetan Plateau [J].Atmospheric Environment, 2015,115:124-131. |
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