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| Advances in carbocatalytic ozonation for water purification |
| KONG Yi-lian, HOU Zhi-ang, WANG Jin-nan |
| School of Environment, Nanjing University, Nanjing 210023, China |
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Abstract Heterogeneous catalytic ozonation (HCO) was used to degrade organic pollutants in water via both direct oxidation and reactive oxygen species (ROS) converted from ozonation. In general, the physicochemical catalysts properties were considered as an important factor that influenced the wastewater purification efficiency. Being attributed to stable chemical properties, easily regulated surface properties and pore structures, carbon-based materials for HCO arose much attention in wastewater treatment. Herein, the research progress and application of carbon-based catalysts for HCO in wastewater treatment were systematically discussed, which helped reader make a complete view. Furthermore, the functionalization and regulation methods of commonly used carbon-based catalysts were introduced in details, and the relationship between carbon-based materials structure and ROS generation was deeply discussed. Meanwhile, organic pollutants degradation mechanisms via radical and non-radical reaction under different reaction conditions such as water quality were expounded. Finally, the prospection and development of carbon-based materials for HCO in wastewater treatment was proposed. The results showed that carbon-based materials for HCO have broad application prospects in wastewater treatment. Future research should focus on the optimization of catalysts and the in-depth exploration of practical applications.
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Received: 09 July 2024
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[1] Dai L, Xue Y, Qu L, et al. Metal-free catalysts for oxygen reduction reaction [J]. Chemical Reviews, 2015,115(11):4823-4892.
[2] Wang Y, Duan X, Xie Y, et al. Nanocarbon-based catalytic ozonation for aqueous oxidation: engineering defects for active sites and tunable reaction pathways [J]. ACS Catalysis, 2020,10(22):13383-13414.
[3] Zou Q, Wang B, Gao B, et al. Roles and mechanisms of carbonaceous materials in advanced oxidation coupling processes for degradation organic pollutants in wastewater: A review [J]. Biochar, 2023,5(1):86.
[4] Wang J, Chen H. Catalytic ozonation for water and wastewater treatment: Recent advances and perspective [J]. Science of the Total Environment, 2020,704:135249.
[5] Jans U, Hoigné J. Activated carbon and carbon black catalyzed transformation of aqueous ozone into OH-radicals [J]. Ozone: Science & Engineering, 1998,20(1):67-90.
[6] Faria P C C, Órfão J J M, Pereira M F R. Activated carbon catalytic ozonation of oxamic and oxalic acids [J]. Applied Catalysis B: Environmental, 2008,79(3):237-243.
[7] Gonçalves A, Órfão J J M, Pereira M F R. Ozonation of bezafibrate promoted by carbon materials [J]. Applied Catalysis B: Environmental, 2013,140-141:82-91.
[8] Chen T, Gu W, Li G, et al. Significant enhancement in catalytic ozonation efficacy: From granular to super-fine powdered activated carbon [J]. Frontiers of Environmental Science & Engineering, 2017, 12(1):6.
[9] Biswal B K, Balasubramanian R. Use of biochar as a low-cost adsorbent for removal of heavy metals from water and wastewater: A review [J]. Journal of Environmental Chemical Engineering, 2023, 11(5):110986.
[10] Zhang F, Wu K, Zhou H, et al. Ozonation of aqueous phenol catalyzed by biochar produced from sludge obtained in the treatment of coking wastewater [J]. Journal of Environmental Management, 2018,224: 376-386.
[11] Li H, Liu S, Qiu S, et al. Catalytic ozonation oxidation of ketoprofen by peanut shell-based biochar: effects of the pyrolysis temperatures [J]. Environmental Technology, 2022,43(6):848-860.
[12] Yang J, Pignatello J J, Yang K, et al. Adsorption of organic compounds by biomass chars: Direct role of aromatic condensation (ring cluster size) revealed by experimental and theoretical studies [J]. Environmental Science & Technology, 2021,55(3):1594-1603.
[13] Dalla Bernardina S, Paineau E, Brubach J B, et al. Water in carbon nanotubes: The peculiar hydrogen bond network revealed by infrared spectroscopy [J]. Journal of the American Chemical Society, 2016, 138(33):10437-10443.
[14] Gonçalves A G, Órfão J J M, Pereira M F R. Catalytic ozonation of sulphamethoxazole in the presence of carbon materials: Catalytic performance and reaction pathways [J]. Journal of Hazardous Materials, 2012,239-240:167-174.
[15] Liu J N, Chen Z, Wu Q Y, et al. Ozone/graphene oxide catalytic oxidation: a novel method to degrade emerging organic contaminant N, N-diethyl-m-toluamide (DEET) [J]. Scientific Reports, 2016,6(1): 31405.
[16] Eigler S, Hirsch A. Chemistry with graphene and graphene oxide—challenges for synthetic chemists [J]. Angewandte Chemie International Edition, 2014,53(30):7720-7738.
[17] Xue Y, Ding Y, Niu J, et al. Rationally designed graphene-nanotube 3D architectures with a seamless nodal junction for efficient energy conversion and storage [J]. Science Advances, 2015,1(8):e1400198.
[18] Wang Y, Xi J, Duan X, et al. The duet of surface and radical-based carbocatalysis for oxidative destructions of aqueous contaminants over built-in nanotubes of graphite [J]. Journal of Hazardous Materials, 2020,384:121486.
[19] Yuan X, Xie R, Zhang Q, et al. Oxygen functionalized graphitic carbon nitride as an efficient metal-free ozonation catalyst for atrazine removal: Performance and mechanism [J]. Separation and Purification Technology, 2019,211:823-831.
[20] Deng S, Yuan P, Ji X, et al. Carbon nitride nanosheet-supported porphyrin: A new biomimetic catalyst for highly efficient bioanalysis [J]. ACS Applied Materials & Interfaces, 2015,7(1):543-552.
[21] Xie Y, Peng S, Feng Y, et al. Enhanced mineralization of oxalate by highly active and Stable Ce(III)-Doped g-C3N4 catalyzed ozonation [J]. Chemosphere, 2020,239:124612.
[22] Cao H, Xing L, Wu G, et al. Promoting effect of nitration modification on activated carbon in the catalytic ozonation of oxalic acid [J]. Applied Catalysis B: Environmental, 2014,146:169-176.
[23] Feng J, Xing B, Chen H. Catalytic ozonation of humic acid in water with modified activated carbon: Enhancement and restoration of the activity of an activated carbon catalyst [J]. Journal of Environmental Management, 2019,237:114-118.
[24] Dong S, Shen X, Guo Q, et al. Valorization of soybean plant wastes in preparation of N-doped biochar for catalytic ozonation of organic contaminants: Atrazine degradation performance and mechanistic considerations [J]. Chemical Engineering Journal, 2023,472:145153.
[25] 柴 铖,许 路,金 鑫,等.氮掺杂生物炭催化臭氧对于布洛芬的降解特性与机制 [J]. 环境科学, 2022,43(2):896-906.Chai C, Xu L, Jin X, et al. Degradation characteristics and mechanism of ibuprofen by ozone catalyzed by nitrogen-doped biochar [J]. Environmental Science, 2022,43(2):896-906.
[26] Wang D, Dong S, Fu S, et al. Catalytic ozonation for imazapic degradation over kelp-derived biochar: Promotional role of N-and S-based active sites [J]. Science of The Total Environment, 2023,860: 160473.
[27] Wei X, Zhang H, Wang J, et al. Nanocarbon shells with self-inherent N, P derived from chlorella pyrenoidosa for aqueous catalytic ozonation: nonradical-dominated mechanisms [J]. Chemical Engineering Journal, 2023,459:140873.
[28] Zhang S, Quan X, Zheng J F, et al. Probing the interphase “HO zone” originated by carbon nanotube during catalytic ozonation [J]. Water Research, 2017,122:86-95.
[29] Oulton R, Haase J P, Kaalberg S, et al. Hydroxyl radical formation during ozonation of multiwalled carbon nanotubes: Performance optimization and demonstration of a reactive CNT filter [J]. Environmental Science & Technology, 2015,49(6):3687-3697.
[30] Liu Z Q, Ma J, Cui Y H, et al. Influence of different heat treatments on the surface properties and catalytic performance of carbon nanotube in ozonation [J]. Applied Catalysis B: Environmental, 2010,101(1/2): 74-80.
[31] Wang Y, Xie Y, Sun H, et al. Efficient catalytic ozonation over reduced graphene oxide for p-Hydroxylbenzoic acid (PHBA) destruction: Active site and mechanism [J]. ACS Applied Materials & Interfaces, 2016,8(15):9710-9720.
[32] Wang Y, Cao H, Chen C, et al. Metal-free catalytic ozonation on surface-engineered graphene: Microwave reduction and heteroatom doping [J]. Chemical Engineering Journal, 2019,355:118-129.
[33] Sun Z, Zhao L, Liu C, et al. Catalytic ozonation of ketoprofen with in situ N-doped carbon: A novel synergetic mechanism of hydroxyl radical oxidation and an intra-electron-transfer nonradical reaction [J]. Environmental Science & Technology, 2019,53(17):10342-10351.
[34] Chen S, Ren T, Zhang X, et al. Efficient catalytic ozonation via Mn-loaded C-SiO2Framework for advanced wastewater treatment: Reactive oxygen species evolution and catalytic mechanism [J]. Science of The Total Environment, 2023,858:159447.
[35] Tian S Q, Qi J Y, Wang Y P, et al. Heterogeneous catalytic ozonation of atrazine with Mn-loaded and Fe-loaded biochar [J]. Water Research, 2021,193:116860.
[36] Yuan X, Qin W, Lei X, et al. Efficient enhancement of ozonation performance via ZVZ immobilized g-C3N4 towards superior oxidation of micropollutants [J]. Chemosphere, 2018,205:369-379.
[37] Wang Y, Xie Y, Sun H, et al. 2D/2D nano-hybrids of γ-MnO2 on reduced graphene oxide for catalytic ozonation and coupling peroxymonosulfate activation [J]. Journal of Hazardous Materials, 2016,301:56-64.
[38] Ren T, Yin M, Chen S, et al. Single-atom Fe-N4sites for catalytic ozonation to selectively induce a nonradical pathway toward wastewater purification [J]. Environmental Science & Technology, 2023,57(9):3623-3633.
[39] 卢思颖,孙中恩,封 莉,等.T-FMSAC制备及其催化臭氧氧化去除p-CBA效能研究 [J]. 中国环境科学, 2017,37(6):2139-2144.Lu S Y, Sun Z E, Feng L. Preparation of T-FMSAC and its catalytic ozonation performance on the removal of p-CBA in water [J] China Environmental Science, 2017,37(6):2139-2144.
[40] Wang J, Xie Y, Yu G, et al. Manipulating selectivity of hydroxyl radical generation by single-atom catalysts in catalytic ozonation: Surface or solution [J]. Environmental Science & Technology, 2022, 56(24):17753-17762.
[41] Ren M, Wang F, Xu Z, et al. Composite material derived from ZIF-67and biochar promotes ozonation of 4-nitrophenol [J]. Chemosphere, 2023,338:139495.
[42] Xu L, He Z, Wei X, et al. Facile-prepared Fe/Mn co-doped biochar is an efficient catalyst for mediating the degradation of aqueous ibuprofen via catalytic ozonation [J]. Chemical Engineering Journal, 2023,461.
[43] 吴天翔,张翼飞,林 原,等.CNT-Fe/Zn催化剂的制备及其催化臭氧氧化降解DBP [J]. 中国环境科学, 2024,44(2):814-824.Wu T X, Zhang Y F, Lin Y. Preparation of CNT-Fe/Zn catalyst and its catalytic ozonation for DBP degradation [J] China Environmental Science, 2024,44(2):814-824.
[44] Wang J, Quan X, Chen S, et al. Enhanced catalytic ozonation by highly dispersed CeO2 on carbon nanotubes for mineralization of organic pollutants [J]. Journal of Hazardous Materials, 2019,368: 621-629.
[45] Buxton G V, Greenstock C L, Helman W P, et al. Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (•OH/•O−) in Aqueous Solution [J]. Journal of Physical and Chemical Reference Data, 1988,17(2):513-886.
[46] Černoch I, Fránek M, Diblíková I, et al. Determination of atrazine in surface waters by combination of POCIS passive sampling and ELISA detection [J]. Journal of Environmental Monitoring, 2011,13(9): 2582-2587.
[47] Gao L, Guo Y, Zhan J, et al. Assessment of the validity of the quenching method for evaluating the role of reactive species in pollutant abatement during the persulfate-based process [J]. Water Research, 2022,221:118730.
[48] Andini S, Bolognese A, Formisano D, et al. Mechanochemistry of ibuprofen pharmaceutical [J]. Chemosphere, 2012,88(5):548-553.
[49] Yang L, Hu C, Nie Y, et al. Catalytic ozonation of selected pharmaceuticals over mesoporous alumina-supported manganese oxide [J]. Environmental Science & Technology, 2009,43(7):2525-2529.
[50] Zhang S, Wang D, Quan X, et al. Multi-walled carbon nanotubes immobilized on zero-valent iron plates (Fe0-CNTs) for catalytic ozonation of methylene blue as model compound in a bubbling reactor [J]. Separation and Purification Technology, 2013,116:351-359.
[51] Akhtar J, Amin N S, Aris A. Combined adsorption and catalytic ozonation for removal of sulfamethoxazole using Fe2O3/CeO2 loaded activated carbon [J]. Chemical Engineering Journal, 2011,170(1):136-144.
[52] Song Z, Sun J, Wang Z, et al. Two-dimensional layered carbon-based catalytic ozonation for water purification: Rational design of catalysts and an in-depth understanding of the interfacial reaction mechanism [J]. Science of The Total Environment, 2022,832:155071.
[53] Duan X, Sun H, Ao Z, et al. Unveiling the active sites of graphene-catalyzed peroxymonosulfate activation [J]. Carbon, 2016,107:371-378.
[54] Song Z, Zhang Y, Liu C, et al. Insight into ×OH and ×O2- formation in heterogeneous catalytic ozonation by delocalized electrons and surface oxygen-containing functional groups in layered-structure nanocarbons [J]. Chemical Engineering Journal, 2019,357:655-666.
[55] Bernat-Quesada F, Espinosa J C, Barbera V, et al. Catalytic ozonation using edge-hydroxylated graphite-based materials [J]. ACS Sustainable Chemistry & Engineering, 2019,7(20):17443-17452.
[56] Qu R, Xu B, Meng L, et al. Ozonation of indigo enhanced by carboxylated carbon nanotubes: Performance optimization, degradation products, reaction mechanism and toxicity evaluation [J]. Water Research, 2015,68:316-327.
[57] Zhang L, Lin C-Y, Zhang D, et al. Guiding principles for designing highly efficient metal-free carbon catalysts [J]. Advanced Materials, 2019,31(13):1805252.
[58] Long J, Xie X, Xu J, et al. Nitrogen-doped graphene nanosheets as metal-free catalysts for aerobic selective oxidation of benzylic alcohols [J]. ACS Catalysis, 2012,2(4):622-631.
[59] Wan K, Long G F, Liu M Y, et al. Nitrogen-doped ordered mesoporous carbon: synthesis and active sites for electrocatalysis of oxygen reduction reaction [J]. Applied Catalysis B: Environmental, 2015,165:566-571.
[60] Song Z, Wang M, Wang Z, et al. Insights into heteroatom-doped graphene for catalytic ozonation: active centers, reactive oxygen species evolution, and catalytic mechanism [J]. Environmental Science & Technology, 2019,53(9):5337-5348.
[61] Ma X, Ning G, Wang Y, et al. S-doped mesoporous graphene microspheres: A high performance reservoir material for LiS batteries [J]. Electrochimica Acta, 2018,269:83-92.
[62] Chen X, Ye P, Wang H, et al. Discriminating active B-N sites in coralloidal B, N dual-doped carbon nano-bundles for boosted Zn-Ion storage capability [J]. Advanced Functional Materials, 2023,33(12): 2212915.
[63] Wang Y, Fang Y, Wang Y, et al. Plasma-enhanced chemical-vapor-deposition synthesis of photoredox-active nitrogen-doped carbon from NH3 and CH4 gases [J]. Angewandte Chemie International Edition, 2023,62(33):e202307236.
[64] Zhang J, Zhang J, He F, et al. Defect and doping Co-engineered non-metal nanocarbon ORR electrocatalyst [J]. Nano-Micro Letters, 2021,13(1):65.
[65] Terrones H, Lv R, Terrones M, et al. The role of defects and doping in 2D graphene sheets and 1D nanoribbons [J]. Reports on Progress in Physics, 2012,75(6):062501.
[66] Wang Y, Cao H, Chen L, et al. Tailored synthesis of active reduced graphene oxides from waste graphite: Structural defects and pollutant-dependent reactive radicals in aqueous organics decontamination [J]. Applied Catalysis B: Environmental, 2018,229:71-80.
[67] Yuan W, Zhou Y, Li Y, et al. The edge-and basal-plane-specific electrochemistry of a single-layer graphene sheet [J]. Scientific Reports, 2013,3(1):2248.
[68] Zhu S, Huang X, Ma F, et al. Catalytic removal of aqueous contaminants on N-doped graphitic biochars: inherent roles of adsorption and nonradical mechanisms [J]. Environmental Science & Technology, 2018,52(15):8649-8658.
[69] Yan D, Li Y, Huo J, et al. Defect chemistry of nonprecious-metal electrocatalysts for oxygen reactions [J]. Advanced Materials, 2017, 29(48):1606459.
[70] Zhang C, Cao M, Ma H, et al. Morphology-control strategy of the superhydrophobic poly(methyl methacrylate) surface for efficient bubble adhesion and wastewater remediation [J]. Advanced Functional Materials, 2017,27(43):1702020.
[71] Orge C A, Sousa J P S, Gonçalves F, et al. Development of novel mesoporous carbon materials for the catalytic ozonation of organic pollutants [J]. Catalysis Letters, 2009,132(1):1-9.
[72] Liu Y, Chen C, Duan X, et al. Carbocatalytic ozonation toward advanced water purification [J]. Journal of Materials Chemistry A, 2021,9(35):18994-19024.
[73] Lakhi K S, Park D H, Al-Bahily K, et al. Mesoporous carbon nitrides: Synthesis, functionalization, and applications [J]. Chemical Society Reviews, 2017,46(1):72-101.
[74] Inagaki M, Toyoda M, Soneda Y, et al. Templated mesoporous carbons: Synthesis and applications [J]. Carbon, 2016,107:448-473.
[75] Li C, Hu Z, Jiang G, et al. 3D carbon microspheres with a maze-like structure and large mesopore tunnels built from rapid aerosol-confined coherent salt/surfactant templating [J]. Small, 2024,20(5):2305316.
[76] Tian W, Zhang H, Duan X, et al. Porous carbons: structure-oriented design and versatile applications [J]. Advanced Functional Materials, 2020,30(17):1909265.
[77] Li K, Tian S, Jiang J, et al. Pine cone shell-based activated carbon used for CO2 adsorption [J]. Journal of Materials Chemistry A, 2016, 4(14):5223-5234.
[78] Chen B, Qi Z, Chen B, et al. Room-temperature salt template synthesis of nitrogen-doped 3D porous carbon for fast metal-ion storage [J]. Angewandte Chemie International Edition, 2024,63(1): e202316116.
[79] Pacchioni G, Freund H-J. Controlling the charge state of supported nanoparticles in catalysis: Lessons from model systems [J]. Chemical Society Reviews, 2018,47(22):8474-8502.
[80] Wang D, He Y, Chen Y, et al. Electron transfer enhancing the Mn(II)/ Mn(III) cycle in MnO/CN towards catalytic ozonation of atrazine via a synergistic effect between MnO and CN [J]. Water Research, 2023, 230:119574.
[81] Li X, Huang X, Xi S, et al. Single cobalt atoms anchored on porous N-Doped graphene with dual reaction sites for efficient fenton-like catalysis [J]. Journal of the American Chemical Society, 2018,140(39): 12469-12475.
[82] Von Gunten U. Ozonation of drinking water: Part I. Oxidation kinetics and product formation [J]. Water Research, 2003,37(7):1443-1467.
[83] Yu G, Wang Y, Cao H, et al. Reactive oxygen species and catalytic active sites in heterogeneous catalytic ozonation for water purification [J]. Environmental Science & Technology, 2020,54(10):5931-5946.
[84] Nawrocki J, Kasprzyk-Hordern B. The efficiency and mechanisms of catalytic ozonation [J]. Applied Catalysis B: Environmental, 2010, 99(1):27-42.
[85] Bing J, Hu C, Zhang L. Enhanced mineralization of pharmaceuticals by surface oxidation over mesoporous γ-Ti-Al2O3 suspension with ozone [J]. Applied Catalysis B: Environmental, 2017,202:118-126.
[86] Wang Y, Chen L, Chen C, et al. Occurrence of both hydroxyl radical and surface oxidation pathways in N-doped layered nanocarbons for aqueous catalytic ozonation [J]. Applied Catalysis B: Environmental, 2019,254:283-291.
[87] Santos A S G G, Orge C A, Soares O S G P, et al. 4-Nitrobenzaldehyde removal by catalytic ozonation in the presence of CNT [J]. Journal of Water Process Engineering, 2020,38:101573.
[88] Lee J, von Gunten U, Kim J H. Persulfate-based advanced oxidation: Critical assessment of opportunities and roadblocks [J]. Environmental Science & Technology, 2020,54(6):3064-3081.
[89] Wang Y, Ren N, Xi J, et al. Mechanistic investigations of the pyridinic N-Co structures in Co embedded N-Doped carbon nanotubes for catalytic ozonation [J]. ACS ES&T Engineering, 2021,1(1):32-45.
[90] Issaka E, AMU-Darko J N O, Yakubu S, et al. Advanced catalytic ozonation for degradation of pharmaceutical pollutants―A review [J]. Chemosphere, 2022,289:133208.
[91] Shang Y, Xu X, Gao B, et al. Single-atom catalysis in advanced oxidation processes for environmental remediation [J]. Chemical Society Reviews, 2021,50(8):5281-5322.
[92] Chen Y Z, Zhou Y X, Wang H, et al. Multifunctional PdAg@MIL-101for one-pot cascade reactions: combination of host-guest cooperation and bimetallic synergy in catalysis [J]. ACS Catalysis, 2015,5(4):2062-2069.
[93] Wei K, Cao X, Gu W, et al. Ni-induced C-Al2O3-Framework (NiCAF) supported core-multishell catalysts for efficient catalytic ozonation: A structure-to-performance study [J]. Environmental Science & Technology, 2019,53(12):6917-6926.
[94] Asgari G, Seidmohammadi A, Faradmal J, et al. Optimization of synthesis a new composite of nano-MgO, CNT and Graphite as a catalyst in heterogeneous catalytic ozonation for the treatment of pesticide-laden wastewater [J]. Journal of Water Process Engineering, 2020,33:101082.
[95] Liang L, Cao P, Bai H, et al. N-coordinated single cobalt atoms catalyst triggering concerted radical-nonradical process in catalytic ozonation for efficient water decontamination [J]. Applied Catalysis B: Environment and Energy, 2024,354:124149.
[96] Tu Y, Zhang T, Ren C, et al. Superoxide radical-induced rapid valence cycling of Mn(II/III/IV) for efficient degradation of organic pollutants [J]. Chemical Engineering Journal, 2024,489:151201.
[97] Tu Y, Shao G, Liu F, et al. Efficient treatment of salty organic wastewater by α-MnO-N/C synergistic catalytic ozonation: Effect and mechanism [J]. AIChE Journal, 2023,69(10):e18160.
[98] 王利平,沈肖龙,倪 可,等.非均相催化臭氧氧化深度处理炼油废水 [J]. 环境工程学报, 2015,9(5):2297-2302.Wang L P, Shen X L, Ni K, et al. Treatment of oil-refinery wastewater by heterogeneous catalytic ozonation process [J]. Chinese Journal of Environmental Engineering, 2015,9(5):2297-2302.
[99] Li C, Jiang F, Sun D, et al. Catalytic ozonation for advanced treatment of incineration leachate using (MnO2-Co3O4)/AC as a catalyst [J]. Chemical Engineering Journal, 2017,325:624-631.
[100] 庄海峰,黄海丽,徐科龙,等.非均相催化臭氧氧化深度处理造纸废水的性能 [J]. 工业水处理, 2017,37(6):30-34.Zhuang H F, Huang H L, Xu K L, et al. Advanced treatment of paper-making wastewater by heterogeneous catalytic ozonation [J]. Industrial Water Treatment, 2017,37(6):30-34.
[101] Hu E, Shang S, Tao X, et al. Regeneration and reuse of highly polluting textile dyeing effluents through catalytic ozonation with carbon aerogel catalysts [J]. Journal of Cleaner Production, 2016,137: 1055-1065.
[102] Grebel J E, Pignatello J J, Mitch W A. Effect of halide ions and carbonates on organic contaminant degradation by hydroxyl radical-based advanced oxidation processes in saline waters [J]. Environmental Science & Technology, 2010,44(17):6822-6828.
[103] Lu K, Ren T, Yan N, et al. Revisit the role of salinity in heterogeneous catalytic ozonation: the trade-off between reaction inhibition and mass transfer enhancement [J/OL]. Environmental Science & Technology, 2023[2023-09-17].
[104] Zuo Z, Cai Z, Katsumura Y, et al. Reinvestigation of the acid-base equilibrium of the (bi)carbonate radical and pH dependence of its reactivity with inorganic reactants [J]. Radiation Physics and Chemistry, 1999,55(1):15-23.
[105] Wang H, Guo W, Liu B, et al. Edge-nitrogenated biochar for efficient peroxydisulfate activation: An electron transfer mechanism [J]. Water Research, 2019,160:405-414.
[106] Yuan X, Duan S, Wu G, et al. Enhanced catalytic ozonation performance of highly stabilized mesoporous ZnO doped g-C3N4 composite for efficient water decontamination [J]. Applied Catalysis A: General, 2018,551:129-138. |
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