Redox zonation in the process of river water infiltration in the Huangjia riverside well field, Shenyang City
SU Dong1,2, SU Xiao-si1,2, ZHANG Li-hua3, YUAN Wen-zhen1,2, LU Shuai1,2, ZUO En-de1,2, GAO Rui-min1,2
1. Key Laboratory of Groundwater Resources and Environment Ministry of Education, Jilin University, Changchun 130021, China;
2. Institute of Water Resources and Environment, Jilin University, Changchun 130021, China;
3. 904 Environment Surveying and Designing Academy of Heilongjiang Province, Harbin 150027, China
Based on the analysis of hydrogeological conditions and geological formations in the Huangjia riverside well field, Shenyang City, the redox zonation during water infiltration process was integrally studied on the basis of in-situ monitoring together with indoor experiments. Our study reveal that regular patterns of the redox zonation along the river water infiltration do exist in the riverbed sediments of Liaohe River.Successive arrangements of O2-NO3- mixed reduction zone, mangne-oxide reduction zone and iron-oxide reduction zone are found embedded in the depth of 0~20cm, 20~80cm, 80~90cm in the riverbed. It is implied that dissolved organic carbon (DOC) from the river water could not provide enough electrons as the reduction oxidants. DOC in river and the dissolved sedimentary organic carbon (SOC) involve in the redox reaction as carbon sources together.
苏东, 苏小四, 张丽华, 袁文真, 鹿帅, 左恩德, 高睿敏. 沈阳黄家傍河水源地河水入渗过程中氧化还原分带规律[J]. 中国环境科学, 2016, 36(7): 2043-2050.
SU Dong, SU Xiao-si, ZHANG Li-hua, YUAN Wen-zhen, LU Shuai, ZUO En-de, GAO Rui-min. Redox zonation in the process of river water infiltration in the Huangjia riverside well field, Shenyang City. CHINA ENVIRONMENTAL SCIENCECE, 2016, 36(7): 2043-2050.
Sophocleous M. Interactions between groundwater and surface water: the state of the science [J]. Hydrogeology Journal, 2002, 10(1):52-67.
[2]
Kuehn W, Mueller U. Riverbank filtration: An overview [J]. Journal-American Water Works Association, 2000,92(12):60-69.
[3]
Tufenkji N, Ryan J N, Elimelech M. Peer reviewed: The promise of bank filtration [J]. Environmental Science & Technology, 2002,36(21):422A-428A.
[4]
Hiscock K M, Grischek T. Attenuation of groundwater pollution by bank filtration [J]. Journal of Hydrology, 2002,266(3):139- 144.
[5]
Massmann G, Greskowiak J, Dunnbier U. The impact of variable temperatures on the redox conditions and the behaviour of pharmaceutical residues during artificial recharge [J]. Journal of Hydrology, 2006,328:141-156.
Champ D R, Gulens J, Jackson R E. Oxidation-reduction sequences in ground water flow systems [J]. Canadian Journal of Earth Sciences, 1979,16(1):12-23.
Guerra G, Jinno K, Hiroshiro Y, et al. The Multi-component Solute Transport Model with Cation Exchange under Redox environment and its Application for Designing the Slow Infiltration setup [J]. Memoirs of Eng Kyushu Uni, 2004,64(1): 79-100.
[10]
Hancock P J. Human impacts on the stream-groundwater exchange zone [J]. Environmental Management, 2002,29(6):763- 781.
[11]
Petrunic B M, MacQuarrie K T B, Al T A. Reductive dissolution of Mn oxides in river-recharged aquifers: a laboratory column study [J]. Journal of Hydrology, 2005,301(1):163-181.
[12]
Lovley D R. Dissimilatory Fe (III) and Mn (IV) reduction [J]. Microbiological Reviews, 1991,55(2):259-287.
[13]
Corstjens P L, De Vrind J P, Westbroek P, et al. Enzymatic iron oxidation by Leptothrix discophora: identification of an iron- oxidizing protein [J]. Applied and Environmental Microbiology, 1992,58(2):450-454.
[14]
Lloyd J R. Microbial reduction of metals and radionuclides [J]. FEMS Microbiology Reviews, 2003,27(2/3):411-425.
[15]
Tebo B M, Bargar J R, Clement B G, et al. Biogenic manganese oxides: properties and mechanisms of formation [J]. Annu. Rev. Earth Planet. Sci., 2004,32:287-328.
[16]
Doussan C, Poitevin G, Ledoux E, et al. River bank filtration: modelling of the changes in water chemistry with emphasis on nitrogen species [J]. Journal of Contaminant Hydrology, 1997, 25(1):129-156.
[17]
Kedziorek M A M, Geoffriau S, Bourg A C M. Organic matter and modeling redox reactions during river bank filtration in an alluvial aquifer of the Lot River, France [J]. Environmental Science & Technology, 2008,42(8):2793-2798.
[18]
Massmann G, Nogeitzig A, Taute T, et al. Seasonal and spatial distribution of redox zones during lake bank filtration in Berlin, Germany [J]. Environmental Geology, 2008,54(1):53-65.
[19]
Kim D M, Yun S T, Kwon M J, et al. Assessing redox zones and seawater intrusion in a coastal aquifer in South Korea using hydrogeological, chemical and isotopic approaches [J]. Chemical Geology, 2014,390:119-134.
[20]
Hansen A L, Christensen B S B, Ernstsen V, et al. A concept for estimating depth of the redox interface for catchment-scale nitrate modelling in a till area in Denmark [J]. Hydrogeology Journal, 2014,22(7):1639-1655.
Appelo C A J, Postma D. Geochemistry, groundwater and pollution [M]. CRC Press, 2005:438-442.
[30]
Burke V, Greskowiak J, Asmuß T, et al. Temperature dependent redox zonation and attenuation of wastewater-derived organic micropollutants in the hyporheic zone [J]. Science of the Total Environment, 2014,482:53-61.
[31]
Lensing H J, Vogt M, Herrling B. Modeling of biologically mediated redox processes in the subsurface [J]. Journal of Hydrology, 1994,159(1):125-143.
[32]
Massmann G, Pekdeger A, Merz C. Redox processes in the Oderbruch polder groundwater flow system in Germany [J]. Applied Geochemistry, 2004,19(6):863-886.
[33]
Richters L, Eckert P, Teermann I, et al. Untersuchungen zur Entwicklung des pH-Wertes bei der Uferpassage in einem Wasserwerk am Rhein [J]. Gas-und Wasserfach. Wasser, Abwasser, 2004,145(9):640-645.
[34]
Von Rohr M R, Hering J G, Kohler H P E, et al. Column studies to assess the effects of climate variables on redox processes during riverbank filtration [J]. Water Research, 2014,61:263-275.
[35]
Eljamal O, Jinno K, Hosokawa T. Modeling of solute transport with bioremediation processes using sawdust as a matrix [J]. Water, Air, and Soil Pollution, 2008,195(1-4):115-127.