静电油烟净化器对餐饮油烟中醛酮类VOCs的去除

穆桂珍, 卢清, 钟志强, 苏燕花, 陆海涛, 梁小明, 蔡立梅, 何秋生, 陈来国, 刘明

中国环境科学 ›› 2020, Vol. 40 ›› Issue (11) : 4697-4702.

PDF(412 KB)
PDF(412 KB)
中国环境科学 ›› 2020, Vol. 40 ›› Issue (11) : 4697-4702.
大气污染与控制

静电油烟净化器对餐饮油烟中醛酮类VOCs的去除

  • 穆桂珍1,2, 卢清2, 钟志强2, 苏燕花2, 陆海涛2, 梁小明2, 蔡立梅1, 何秋生3, 陈来国2, 刘明2
作者信息 +

Removal of electrostatic fume purifiers on aldehydes and ketones compounds from cooking oil fume

  • MU Gui-zhen1,2, LU Qing2, ZHONG Zhi-qiang2, SU Yan-hua2, LU Hai-tao2, LIANG Xiao-ming2, CAI Li-mei1, HE Qiu-sheng3, CHEN Lai-guo2, LIU Ming2
Author information +
文章历史 +

摘要

利用2,4-二硝基苯肼(DNPH)硅胶管采集了9家餐饮企业静电油烟净化装置处理前后的醛酮类VOCs样品,并采用高效液相色谱(HPLC)进行分析.结果表明,9家餐饮企业处理前后的油烟中醛酮类VOCs浓度范围分别为419.5~3372,415.8~2934μg/m3,经过基准风量折算后的浓度分别为783.4~3761和541.7~2997μg/m3,VOCs排放浓度与烹饪方式、实际使用灶头数和排风量有关.从排放的醛酮类VOCs的种类来看,C1~C3化合物的浓度占检测到的总羰基的66%以上,且甲醛占比最高,其次是乙醛;C4~C8化合物的含量相对较低.静电式油烟净化器对醛酮类VOCs的平均净化效率为31.82%,最高可达69.14%,其中对甲醛的净化效果最佳,平均为35.21%,最高达80.10%.复合式静电油烟净化器的净化效果要稍好于单一静电油烟净化器.

Abstract

Aldehydes and ketones compounds before and after electrostatic fume purifiers were sampled using 2,4-dinitrophenylhydrazine (DNPH) silica tube at nine restaurants, and then high performance liquid chromatography (HPLC) was used for quantitative measurement. Total concentrations of aldehydes and ketones compounds in the exhaust from nine restaurants ranged from 419.5 to 3372μg/m3 before the purifiers, while they varied from 415.8 to 2934μg/m3 after the purifiers. the concentrations of reference volume condition corresponded to 783.4~3761 and 541.7~2997μg/m3, respectively. It suggested that their concentrations were related to different cooking processes, the number of working stoves and the exhaust air volume. The concentration of C1~C3compounds accounted for more than 66% of the total detected carbonyl groups. formaldehyde was the highest detected compound, followed by acetaldehyde. The content of C4~C8compounds was relatively low. The average purification efficiency of electrostatic fume purifier on aldehydes and ketones compounds was 31.82%, with the highest efficiency reached to 69.14%. Formaldehyde has the highest purification efficiency with an average of 35.21% and a maximum of 80.10%. The composite electrostatic fume purifier can achieve a better purification effect than the normal electrostatic fume purifier.

关键词

餐饮油烟 / 静电油烟净化器 / 去除效率 / 醛酮类VOCs

Key words

aldehydes and ketones compounds / cooking oil fume / electrostatic fume purifiers / removal efficiency

引用本文

导出引用
穆桂珍, 卢清, 钟志强, 苏燕花, 陆海涛, 梁小明, 蔡立梅, 何秋生, 陈来国, 刘明. 静电油烟净化器对餐饮油烟中醛酮类VOCs的去除[J]. 中国环境科学. 2020, 40(11): 4697-4702
MU Gui-zhen, LU Qing, ZHONG Zhi-qiang, SU Yan-hua, LU Hai-tao, LIANG Xiao-ming, CAI Li-mei, HE Qiu-sheng, CHEN Lai-guo, LIU Ming. Removal of electrostatic fume purifiers on aldehydes and ketones compounds from cooking oil fume[J]. China Environmental Science. 2020, 40(11): 4697-4702
中图分类号: X701   

参考文献

[1] 程婧晨,崔彤,何万清,等.北京市典型餐饮企业油烟中醛酮类化合物污染特征[J]. 环境科学, 2015,36(8):2743-2749. Cheng J C, Cui T, He W T, et al. Pollution characteristics of aldehydes and ketones compounds in the exhaust of Beijing typical restaurants[J]. Environmental Science, 2015,36(8):274-2749.
[2] 张鑫,李红,张成龙,等.环境空气中醛酮类化合物检测方法优化与初步应用[J]. 环境科学研究, 2019,32(5):821-829. Zhang X, Li H, Zhang C L, et al. Optimization and preliminary of the detection method of carbonyl compounds in the ambient air[J]. Research of Environmental Science, 2019,32(5):821-829.
[3] Kumar A, Singh D, Kumar K, et al. Distribution of VOCs in urban and rural atmospheres of subtropical India:Temporal variation, source attribution, ratios, OFP and risk assessment[J]. Science of the Total Environment, 2018,613-614:492-501.
[4] Zheng J, Shao M, Che W, et al. Speciated VOC Emission Inventory and Spatial Patterns of Ozone Formation Potential in the Pearl River Delta, China[J]. Environmental Science & Technology, 2009,43(22):8580-8586.
[5] 舒木水,淡默,纪晓慧,等.油烟净化设备对餐饮排放物的净化效率[J]. 环境工程, 2018,36(11):86-89. Shu S S, Dan M, Ji X H, et al. Purification efficiency of cooking fume control equipment to cooking emission[J]. Environmental Engineering, 2018,36(11):86-89.
[6] GB18483-2001饮食业油烟排放标准[S]. GB18483-2001 Emission standard of cooking fume[S].
[7] Abdullahi, DelgadoSaborit, J M, et al. Emissions and indoor concentrations of particulate matter and its specific chemical components from cooking:A review[J]. Atmospheric Environment, 2013,71(2):260-294.
[8] Cheng S Y, Wang G, Lang J L, et al. Characterization of volatile organic compounds from different cooking emissions[J]. Atmospheric Environment, 2016,145:299-307.
[9] 张宝勇,杨玉柱.烹调油烟的组成与危害及防治方法探讨[J]. 四川食品与发酵, 2006,2:14-18. Zhang B Y, Yang Y Z. Discussion of the composition, harm and preventing and controlling methods of the cooking oil fumes[J]. Sichuan Food and Fermentation, 2006,2:14-18.
[10] Takeoka G, Perrino C Jr, Buttery R. Volatile constituents of used frying oils[J]. Journal of Agricultural and Food Chemistry, 1996,44(3):654-660.
[11] Schauer J J, Kleeman M J, Cass G R, et al. Measurement of emissions from air pollution sources.4. C1-C27 organic compounds from cooking with seed oils[J]. Environmental Science & Technology, 2002,36:567-575.
[12] 冯艳丽,黄娟,文晟,等.餐馆排放油烟气中羰基化合物浓度及分布特征[J]. 环境科学与技术, 2008,31(2):66-68. Feng Y L, Huang J, Wen S, et al. Concentration and Pattern of carbonyl compounds from oil smoke in restaurant[J]. Environmental Science & Technology, 2008,31(2):66-68.
[13] Xiang Z Y, Wang H L, Svetlana S, et al. Assessing impacts of factors on carbonyl compounds emissions produced from several typical Chinese cooking[J]. Building and Environment, 2017,125:348-355.
[14] 史纯珍,姜锡,姚志良,等.烹饪油烟羰基化合物排放特征[J]. 环境工程学报, 2015,9(3):1376-1380. Shi C Z, Jiang X, Yao Z L, et al. Carbonyl compounds emission characteristics in cooking fumes[J]. Chinese Journal of Environmental Engineering, 2015,9(3):1376-1380.
[15] 仝晓波.醇基燃料发展亟待统一认识[N]. 中国能源报, 2017-06-12(004). Tong X B. The development of alcohol-based fuels urgently needs a unified understanding[N]. China Energy News, 2017-06-12(004).
[16] HJ683-2014环境空气醛酮类化合物的测定高效液相色谱法[S]. HJ683-2014 Ambient air Determination of aldehydes and ketones compounds-High performance liquid chromatography[S].
[17] 张春洋,马永亮.中式餐饮业油烟中非甲烷碳氢化合物排放特征研究[J]. 环境科学学报, 2011,31(8):202-209. Zhang C Y, Ma Y L. Characterization of non-methane hydrocarbons emitted from Chinese cooking[J]. Acta Scientiae Circumstantiae, 2011,31(8):202-209.
[18] Cheng J H, Lee Y S, Chen K S. Carbonyl compounds in dining areas, kitchens and exhaust streams in restaurants with varying cooking methods in Kaohsiung, Taiwan[J]. Journal of Environmental Sciences, 2016,41:218-226.
[19] Zhang Y, Mu Y, Liu J. Levels, sources and health risks of carbonyls and BTEX in the ambient air of Beijing, China[J]. Environment Science, 2012,24:124-130.
[20] 贝雷.油脂化学与工艺学(上册)[M]. 北京:轻工业出版社, 1959. Bei Lei. Oil Chemistry and Technology, (Volume 1)[M]. Beijing:Light Industry Press, 1959.
[21] Zhang J F, Smith K R. Hydrocarbon emissions and health risks from cookstoves in developing countries[J]. Journal of exposure analysis & environmental epidemiology, 1996,6(2):147.
[22] Ho S S H, Yu J Z, Chu K W, et al. Carbonyl emissions from commercial cooking sources in Hong Kong[J]. Journal of the Air & Waste Management Association, 2006,56(8):1091-1098.
[23] 黄丽萍.电晕放电与光催化协同净化室内空气研究[D]. 大连:大连海事大学, 2010. Huang L P. Research on synergistic purification of indoor air by corona discharge and photocatalysis[D]. Dalian:Dalian Maritime University, 2010.
[24] 何红勤,袁建平,张杰,等.烹饪油烟污染与净化技术[J]. 排灌机械, 2007,25(1):68-70. He H Q, Yuan J P, Zhang J, et al. Cooking oil fume pollution and purification technology[J]. Drainage and Irrigation Machinery, 2007, 25(1):68-70.

基金

国家重点研发计划项目(2017YFC0212606);国家自然科学基金资助项目(41773130,41573123);中央公益性科研院所基本科研业务专项(PM-zx703-201904-081)


PDF(412 KB)

Accesses

Citation

Detail

段落导航
相关文章

/