Role of surface secondary mineral on tylosin degradation mediated by the pyrite oxidation process
SHU Xiao-hua1,2,3, QIN Zi-qi1, NIE Chang-da1, ZHOU Jin-wen4, ZHANG Teng-fei1, ZHANG Qian4
1. College of Environmental Science and Engineering, Guilin University of Technology, Guilin 541006, China; 2. The Guangxi Key Laboratory of Theory and Technology for Environmental Pollution Control, Guilin University of Technology, Guilin 541006, China; 3. Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guilin University of Technology, Guilin 541006, China; 4. School of Life and Environmental Science, Guilin University of Electronic Technology, Guilin 541004, China
Abstract：This study investigated the photodegradation performance and mechanisms of pyrite, with varying degrees of oxidation, on the macrolide antibiotic tylosin (TYL), which is extensively used in animal husbandry. The results indicated that oxidized pyrite significantly enhanced its photocatalytic degradation efficiency towards TYL. The surface roughness of the oxidized pyrite samples increased, leading to a larger specific surface area and a greater number of active sites for surface reactions, which improved the adsorption capacity for TYL. Moreover, the surface electron transfer process of oxidized pyrite was significantly enhanced, which accelerated the production rate of hydroxyl radicals (·OH) and improved the photodegradation efficiency of TYL. Additionally, the interaction between pyrite (FeS2) and the newly formed Fe2O3 on the surface created a heterojunction that effectively inhibited the recombination of photogenerated electrons and holes within the material, thereby augmenting the photodegradation performance.
舒小华, 覃紫其, 聂昌达, 周进文, 张腾飞, 张倩. 表面次生氧化矿物对FeS2降解抗生素的影响及作用机制[J]. 中国环境科学, 2024, 44(10): 5539-5546.
SHU Xiao-hua, QIN Zi-qi, NIE Chang-da, ZHOU Jin-wen, ZHANG Teng-fei, ZHANG Qian. Role of surface secondary mineral on tylosin degradation mediated by the pyrite oxidation process. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(10): 5539-5546.
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