纤铁矿与重金属的相互作用——从界面过程到环境行为的研究进展

范聪; 方君然; 李晓飞; 郭楚玲; 申渝; 卢桂宁; 梅远飞; 党志

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中国环境科学 ›› 2024, Vol. 44 ›› Issue (8) : 4484-4495.

土壤污染与控制

纤铁矿与重金属的相互作用——从界面过程到环境行为的研究进展

范聪¹, 方君然¹, 李晓飞², 郭楚玲³, 申渝¹, 卢桂宁³, 梅远飞⁴, 党志³

作者信息 +

Interactions between lepidocrocite and heavy metals: Research progress from interfacial processes to environmental behaviors

FAN Cong¹, FANG Jun-ran¹, LI Xiao-fei², GUO Chu-ling³, SHEN Yu¹, LU Gui-ning³, MEI Yuan-fei⁴, DANG Zhi³

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摘要

铁的生物地球化学循环在土壤物质迁移转化过程尤其是重金属环境行为影响方面扮演着关键角色.纤铁矿是一种常见的亚稳态铁(羟基)氧化物,通常存在于季节性氧化还原交替的土壤环境中,具有较大的比表面积和高表面活性,驱动着土壤物质循环等重要过程.本文以纤铁矿稳定性为纽带,阐述了纤铁矿在不同晶相重组路径中作为起始物种、前驱体(中间产物)和最终产物三种不同定位角色的演化规律.从生物地球化学循环角度对纤铁矿形成和晶相重组过程与重金属的相互作用机制进行了系统论述.重点讨论了典型环境因子(如pH值、含氧阴离子、有机质和微生物等)对纤铁矿稳定性及重金属赋存形态的影响.展望了未来研究发展趋势,包括多过程耦合下铁氧化物相转化机制、重金属在矿物-水界面的微观反应机制、以及重金属归趋的环境因子调控等,以期为基于铁循环调控重金属赋存状态的污染修复及铁矿物作用下重金属环境行为预测等提供参考.

Abstract

The biogeochemical cycle of iron plays a key role in the migration and transformation processes of soil materials, especially in the environmental behavior of heavy metals. Lepidocrocite is a common metastable iron (hydroxyl) oxide that typically found in soils with seasonal redox alternations. It has a large specific surface area and high surface activity, and can drive soil material circulation. This article takes the stability of lepidocrocite as a link, to explain the evolutionary patterns of its three different roles of as an original mineral, precursor (intermediate product) and final product in different transformation pathways. The interaction mechanism between formation/transformation of lepidocrocite and fate of heavy metals was systematically discussed from the perspective of biogeochemical cycles. The impact of typical environmental factors (such as pH, oxyanions, dissolved organic matter and microorganisms) on the stability of lepidocrocite and the occurrence forms of heavy metals was focused on. Future research trends include the transformation mechanism of iron minerals in complex environments, the microscopic reaction mechanism of heavy metals at the mineral-water interface, and the regulation of environmental factors on the fate of heavy metals. These studies aim to provide solutions for pollution remediation by regulating the iron cycle and understanding the occurrence status of heavy metals. Additionally, they offer insights for predicting the environmental behavior of heavy metals under the influence of iron minerals.

导出引用

范聪, 方君然, 李晓飞, 郭楚玲, 申渝, 卢桂宁, 梅远飞, 党志. 纤铁矿与重金属的相互作用——从界面过程到环境行为的研究进展[J]. 中国环境科学. 2024, 44(8): 4484-4495

FAN Cong, FANG Jun-ran, LI Xiao-fei, GUO Chu-ling, SHEN Yu, LU Gui-ning, MEI Yuan-fei, DANG Zhi. Interactions between lepidocrocite and heavy metals: Research progress from interfacial processes to environmental behaviors[J]. China Environmental Science. 2024, 44(8): 4484-4495

中图分类号： X13

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