福建泉州湾有机氯农药的多介质迁移与归趋

Abstract
Figure/Table
References (33)
Related Citation (8)

Download: PDF (664 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract

A multimedia fugacity model (Level Ⅲ) was applied to simulate the concentrations distribution, fugacity reserves distribution and transfer flux of α-HCH and p,p'-DDT in Jinjiang River basin and Quanzhou Bay. Meanwhile, the key input parameters were identified using sensitivity analysis method. The reliability of the fugacity model is verified by the agreement between calculated and measured concentrations in soil, water and sediment. The capacities of the four environmental compartments to hold α-HCH and p,p'-DDT in the following orders: sediment, soil, water and air. The mass of α-HCH and p,p'-DDT in soil and sediment were 97.42% and 99.89%, which is the major sink for α-HCH and p,p'-DDT. The water advection outflow were the major routes for α-HCH and p,p'-DDT disappear in the study area. The main transfer processes of α-HCH and p,p'-DDT is diffusion from water to air and deposition from water to sediment. The results of sensitivity analysis in this study indicated that the logK_ow had significant influence on α-HCH and p,p'-DDT concentrationsin various media.

Key words： α-HCH p,p'-DDT Quanzhou Bay Jinjiang River basin multimedia fugacity model

Received: 16 December 2015

X131

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHANG Xiao-tao
	LU Yu-shi
	YANG Dan

Cite this article:

ZHANG Xiao-tao,LU Yu-shi,YANG Dan. Simulating the transfer and fate of OCPs in Quanzhou Bay[J]. CHINA ENVIRONMENTAL SCIENCECE, 2016, 36(7): 2146-2153.

URL:

http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2016/V36/I7/2146

[1]	Mishra K, Sharma R. C, Kumar S. Contamination profile of DDT and HCH in surface sediments and their spatial distribution from North-East India [J]. Ecotoxicology and Environmental Safety, 2013,95:113-122.
[2]	崔嵩,付强,李天霄.污灌区有机氯农药的土-气交换行为与影响因素分析 [J]. 农业机械学报, 2015,(5):122-130.
[3]	Jones K C, Voogt P D. Persistent organic pollutants (POPs):state of the science [J]. Environ Pollut, 1999,100(1/2/3):209-221.
[4]	冉聃,鲁建江,姚晓瑞,等.新疆典型农业地区土壤中有机氯农药(OCPs)分布特征及风险评价 [J]. 农业工程学报, 2012,(3): 225-229.
[5]	Li Y F, Cai D J, Singh A. Technical hexachlorocyclohexane use trends in China and their impact on environment [J]. Archives of Environment Contamination and Toxicology, 1998,35:688-697.
[6]	Xin J, Liu X, Liu W, et al. Production and use of DDT containing antifouling paint resulted in high DDTs residue in three paint factory sites and two shipyard sites, China [J]. Chemosphere, 2011,84(3):342-347.
[7]	孙洪欣,杨阳,王倩倩,等.府河流域污灌状况及农户对污灌与人体健康关系的认知调查分析 [J]. 中国农学通报, 2015,31(2): 197-200.
[8]	刘鹏宇,夏传,常青,等.聚合硫酸铁混凝消除水中有机氯的研究 [J]. 中国环境科学, 2015,35(8):2382-2392.
[9]	胡英,祁士华,袁林喜.洪湖湿地水鸟肝脏中有机氯农药的分布 [J]. 中国环境科学, 2014,34(8):2140-2147.
[10]	刘彬,李爱民,张强,等.有机氯农药在湖北省菜地土壤中的污染研究 [J]. 中国环境监测, 2016,(3):68-72.
[11]	Hong H, Xu L, Zhang L, et al. Environmental fate and chemistry of organic pollutants in the sediment of Xiamen and Victoria Harbors [J]. Marine Pollution Bulletin, 1995,31(4-12):229-236.
[12]	中国海湾志编纂委员会.中国海湾志(第八分册)(福建省南部海湾) [M]. 北京:海洋出版社, 1993.
[13]	张家泉,祁士华,谭凌智,等.晋江流域表层土壤中有机氯农药分布特征及污染评价 [J]. 环境科学学报, 2011,32(9):2008-2013.
[14]	Qiu X G., Zhu T, Yao B, et al. Contribution of dicofol to the current DDT pollution in China [J]. Environmental Science & Technology, 2005,39(12):4385-4390.
[15]	Meijer S N, Halsall C J, Harner T, et al. Organochlorine pesticide residues in archived UK soil [J]. Environmental Science & Technology, 2001,35(10):1989-1995.
[16]	田崇国.中国α-HCH-六六六土壤残留分布特征及源汇解析的数值模拟研究 [D]. 哈尔滨.哈尔滨工业大学, 2009.
[17]	齐丽,周志广,许鹏军,等.北京地区二噁英类的环境多介质迁移和归趋模拟 [J]. 环境科学研究, 2012,25(5):543-548.
[18]	MACKAY D.环境多介质模型:逸度方法 [M]. 黄国兰,陈春江,孔庆宁等译.北京:化学工业出版, 2007.
[19]	任智辉,裴国霞,修海峰,等.黄河包头段环境中α-HCH的迁移与残留的动态模拟 [J]. 中国环境监测, 2012,(2):77-81.
[20]	叶常明.多介质环境污染研究 [M]. 北京:科学出版社, 1997.
[21]	Mackay D, Shiu W Y, Ma K C. Illustrated handbook of physical chemical properties and environmental fate for organic chemicals, Volume V, pesticide chemicals [M]. Boca. Raton., FL: Lewis Pub2lishers, 1997.
[22]	孙清芳,冯玉杰,武晓威,等.松花江流域萘的多介质环境迁移与归趋模拟 [J]. 哈尔滨工业大学学报, 2013,(4):64-68.
[23]	董继元,王金玉,张本忠,等.兰州城区多环芳烃的多介质归趋模拟研究 [J]. 环境科学学报, 2013,34(2):570-578.
[24]	田慧,郭强,毛潇萱,等.广州地区典型多溴联苯醚迁移和归趋行为模拟 [J]. 中国环境科学, 2014,34(3):758-765.
[25]	Mackay D, Paterson S, Shiu W Y, et al. Generic models for evaluating the regional fate of chemical [J]. Chemosphere, 1992, 24(6):695-717.
[26]	韩珍,裴国霞,张琦,等.黄河头道拐冰封期a-HCH逸度模型的建立与验证 [J]. 干旱区资源与环境, 2014,(12):184-189.
[27]	汪祖丞,刘敏,杨毅,等.菲在长江口的多介质归趋模拟 [J]. 环境科学, 2011,31(8):2444-2449.
[28]	Feng Y Z, Sun Q F, Gao P, et al. Polycyclic aromatic hydrocarbons in surface water from the Songhua River of China [J]. Fresenius Environmental Bulletin, 2009,18(12):2388-2395.
[29]	刘华英,邓莎,李强,等.昆明地区双酚A的多介质环境归趋研究 [J]. 安全与环境学报, 2014,(5):257-260.
[30]	Yao Z W, Jiang G B, Xu HZ, et al. Distribution of organochlorine pesticides in seawater of the Bering and Chukchi Sea [J]. Environmental Pollution, 2002,116:49-56.
[31]	曹红英,梁涛,陶澍.北京地区50多年来有机氯农药迁移与残留的动态模拟与预测 [J]. 中国科学(D辑:地球科学), 2005, (10):76-84.
[32]	叶常明,雷志芳,王宏,等.有机污染物多介质环境的稳态非平衡模型 [J]. 环境科学学报, 1995,15(2):192-197.
[33]	隆兴兴,牛军峰,史姝琼.邻苯二甲酸酯类化合物正辛醇-水分配系数的QSPR研究 [J]. 环境科学, 2006,26(11):2318-2322.