典型煤矿区土壤中多环芳烃类化合物的污染特征

Abstract
Figure/Table
References
Related Citation (2)

Download: PDF (1553 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract The sources of polycyclic aromatic compounds (PACs) and carcinogenic risk in soils from three typical coal mining areas were analyzed with positive matrix factorization analysis (PMF) and Monte-Carlo simulation. The results showed that the soil in Shizuishan coal mine, Qipanjing coal mine and Shitanjing coal mine ΣPACs were 21862, 6226 and 2278μg/kg, respectively. PACs species were abundant and dominated by low rings, which was significantly affected by the coal mining area. Meanwhile, the concentration of alkyl polycyclic aromatic hydrocarbons (aPAHs) was significantly higher than that of parent polycyclic aromatic hydrocarbons (16PAHs). The results of PMF showed that coal and gangue particles were the primary pollution sources in the coal mine areas, followed by traffic sources. Monte-Carlo simulation showed that the three coal mining areas have potential carcinogenic risks to local residents. Although the study area was significantly affected by coal pollution sources, coal combustion was the main contributor to carcinogenic risks. In addition, Monte-Carlo simulation was more accurate than incremental lifetime cancer risk (ILCR), and the traditional risk assessment used ILCR significantly underestimates the actual cancer risk of adults.

Key words： coal mine areas alkyl polycyclic aromatic hydrocarbons (aPAHs) positive matrix factorization (PMF) Monte-Carlo simulation incremental lifetime cancer risk (ILCR)

Received: 28 November 2022

PACS:

X53

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	XU Zhen-peng
	YUAN Ke-yue
	QIAN Ya-hui
	LIANG Han-dong

Cite this article:

XU Zhen-peng,YUAN Ke-yue,QIAN Ya-hui等. Contamination characteristics of polycyclic aromatic compounds in soils of typical coal mining areas[J]. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(7): 3582-3591.

URL:

http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2023/V43/I7/3582

[1]	张娟,吴建芝,刘燕.北京市绿地土壤多环芳烃分布及健康风险评价 [J]. 中国环境科学, 2017,37(3):1146-1153. Zhang J, Wu J Z, Liu Y. Polycyclic aromatic hydrocarbons in urban green space of Beijing: distribution and potential risk [J]. China Environmental Science, 2017,37(3):1146-1153.
[2]	Xie Z Y, Zhang P, Wu Z L, et al. Legacy and emerging organic contaminants in the polar regions [J]. Science of the Total Environment, 2022,835.doi:10.1016/j.scitotenv.2022.155376.
[3]	李爽,刘殷佐,刘入瑜,等.浑河沈抚段多环芳烃的污染特征及风险评价 [J]. 中国环境科学, 2019,39(4):1551-1559. Li S, Liu Y Z, Liu R Y, et al. The pollution characteristics and risk assessment of polycyclic aromatic hydrocarbons of Shen-Fu section of the Hun River Basin [J]. China Environmental Science, 2019,39(4): 1551-1559.
[4]	孙焰,祁士华,李绘,等.福建闽江沿岸土壤中多环芳烃含量、来源及健康风险评价 [J]. 中国环境科学, 2016,36(6):1821-1829. Sun Y, Qi S H, Li H, et al. Concentrations, sources and health risk assessment of polycyclic aromatic hydrocarbons in soils collected along the banks of Minjiang River, Fujian, China [J]. China Environmental Science, 2016,36(6):1821-1829.
[5]	康欣媛,王国文,丁小璘,等.莱州湾大气颗粒相中多环芳烃及其衍生物的赋存特征 [J]. 海洋环境科学, 2022,41(1):113-121. Kang X Y, Wang G W, Ding X L, et al. Occurrence of different type polycyclic aromatic hydrocarbon (PAHs) in particle atmosphere of Laizhou Bay [J]. Marine Environmental Science, 2022,41(1):113-121.
[6]	Yin F, Gao C, Song Z B, et al. Chemical signatures of polycyclic aromatic hydrocarbons in the emissions from in situ oil burns [J]. Marine Pollution Bulletin, 2022,184.doi:10.1016/j.marpolbul.2022.114194.
[7]	Goto Y, Nakamuta K, Nakata H. Parent and alkylated PAHs profiles in 11petroleum fuels and lubricants: Application for oil spill accidents in the environment [J]. Ecotoxicology and Environmental Safety, 2021, 224.doi:10.1016/j.ecoenv.2021.112644.
[8]	乔秋菊,杭莉,张艳秋.2019年泰州市某区PM2.5中多环芳烃的污染特征及健康风险评价 [J]. 化学研究, 2021,32(5):417-423. Qiao Q J, Hang L, Zhang Y Q. Pollution characteristic and health risk assessment of polycyclic aromatic hydrocarbons in PM2.5 from a certain district of Taizhou city in 2019 [J]. Chemical Research, 2021, 32(5):417-423.
[9]	孙翔,王锋文,郭天锋,等.重庆废弃煤矿区表层土壤多环芳烃污染特征及风险评价 [J]. 地球与环境, 2019,47(4):502-509. Sun X, Wang F W, Guo T F, et al. Occurrence and risk assessment of polycyclic aromatic hydrocarbons in topsoil of an abandoned coal mine area in Chongqing [J]. Earth and Environment, 2019,47(4):502-509.
[10]	王飞,赵颖.太原市污灌区农田土壤中多环芳烃污染特征及生态风险评价 [J]. 生态环境学报, 2022,31(1):160-169. Wang F, Zhao Y. Pollution characteristics and risk assessment of PAHs in agricultural soil from sewage irrigation area of Taiyuan City, Shanxi Province [J]. Ecology and Environmental Sciences, 31(1):160-169.
[11]	徐振鹏,钱雅慧,洪秀萍,等.淮北孙疃矿区地表尘中多环芳烃类化合物的污染特征及致癌风险评价 [J/OL]. 环境科学, 2022,doi:10. 13227/j.hjkx.202209062. Xu Z P, Qian Y H, Hong X P, et al. Contamination characteristics and risk assessment of polycyclic aromatic compounds in surface dust of Suntuan mining area in Huaibei [J/OL]. Environmental Science, 2022.doi:10.13227/j.hjkx.202209062.
[12]	Wang Y H, Hu L F, Lu G H. Health risk analysis of atmospheric polycyclic aromatic hydrocarbons in big cities of China [J]. Ecotoxicology, 2014,23(4):584-588.
[13]	Wu J J, Bian J M, Wan H L, et al. Probabilistic human health-risk assessment and influencing factors of aromatic hydrocarbon in groundwater near urban industrial complexes in Northeast China [J]. Science of the Total Environment, 2021,800.doi:10.1016/j.scitotenv. 2021.149484.
[14]	Tarafdar A, Sinha A. Health risk assessment and source study of PAHs from roadside soil dust of a heavy mining area in India [J]. Archives of Environmental & Occupational Health, 2019,74(5):252-262.
[15]	Roy D, Jung W, Kim J, et al. Cancer Risk Levels for Sediment-and Soil-Bound Polycyclic Aromatic Hydrocarbons in Coastal Areas of South Korea [J]. Frontiers in Environmental Science, 2021,9.doi: 10.3389/fenvs.2021.719243.
[16]	杜川,梁汉东,李展平.内蒙古乌达煤火海绵体的硫酸盐表征 [J]. 环境化学, 2020,39(1):264-270. Du C, Liang H D, Li Z P. Characterization of sulfate salts in the coal fire sponge in Wuda coalfield, Inner Mongolia of China [J]. Environmental Chemistry, 2020,39(1):264-270.
[17]	梁言慈.内蒙古乌达煤火典型污染物排放特征研究 [D]. 北京:中国矿业大学(北京), 2018. Liang Y C. Emission Characteristics of Typical Pollutants of Coal Fire in Wuda, Inner Mongolia [D]. Beijing: China University of Mining and Technology, Beijing, 2018.
[18]	Xu Z P, Qian Y H, Yuan K Y, et al. Contamination characteristics and risk assessment of polycyclic aromatic compounds in soil from industrial park of Wuda District, Inner Mongolia, China [J]. International Journal of Environmental Analytical Chemistry, 2022, doi:10.1080/03067319.2022.2140411.
[19]	徐友宁,李玉武,张江华,等.宁夏石嘴山采煤塌陷区地质环境治理模式研究 [J]. 西北地质, 2015,48(4):183-189. Xu Y N, Li Y W, Zhang J H, et al. Treatment model on Geo-Environment in the coal mine collapse area of Shizuishan city, Ningxia [J]. Northwestern Geology, 2015,48(4):183-189.
[20]	袁珂月,钱雅慧,许丹丹,等.内蒙古乌达矿区土壤多环芳烃空间分布特征及分析 [J]. 地球与环境, 2022,50(5):698-707. Yuan K Y, Qian Y H, Xu D D, et al. Distribution characteristics of soil PAHs in Wuda mining area, Inner Mongolia [J]. Earth and Environment, 2022,50(5):698-707.
[21]	钱雅慧,汪婷,洪秀萍,等.煤矿区地表土中烷基多环芳烃的定量方法研究 [J]. 质谱学报, 2022,43(2):168-177. Qian Y H, Wang T, Hong X P, et al. Quantitative method of alkyl polycyclic aromatic hydrocarbons in surface soils of coal mines [J]. Journal of Chinese Mass Spectrometry Society, 2022,43(2):168-177.
[22]	梁明.华北地区农村环境介质多环芳烃污染特征研究 [D]. 北京:中国矿业大学(北京), 2021. Liang M. Pollution characteristics of polycyclic aromatic hydrocarbons in rural environmental multimedia in North China [D]. Beijing: China University of Mining and Technology, Beijing, 2021.
[23]	Yang W, Carmichael S L, Roberts E M, et al. Residential Agricultural Pesticide Exposures and Risk of Neural Tube Defects and Orofacial Clefts among Offspring in the San Joaquin Valley of California [J]. American Journal of Epidemiology, 2014,179:740-748.
[24]	Kelishadi R, Motlagh M E, Bahreynian M, et al. Methodology and early findings of the assessment of determinants of weight disorders among Iranian children and adolescents: The childhood and adolescence surveillance and prevention of adult noncommunicable disease-IV study [J]. International Journal of Preventive Medicine, 2015,6:77-84.
[25]	Qishlaqi A, Beiramali F. Potential sources and health risk assessment of polycyclic aromatic hydrocarbons in street dusts of Karaj urban area, northern Iran [J]. Journal of Environmental Health Science and Engineering. 2020,17(2):1029-1044.
[26]	Maliszewska-Kordybach B. Polycyclic aromatic hydrocarbons in agroecosystems-example of Poland [J]. Polycyclic Aromatic Compounds, 2000,21(1-4):287-295.
[27]	Golzadeh N, Barst B D, Baker J M, et al. Alkylated polycyclic aromatic hydrocarbons are the largest contributor to polycyclic aromatic compound concentrations in traditional foods of the Bigstone Cree Nation in Alberta, Canada [J]. Environmental Pollution, 2021, 275.doi:10.1016/j.envpol.2021.116625.
[28]	Abdel-Shafy H I, Mansour M S M. A review on polycyclic aromatic hydrocarbons: Source, environmental impact, effect on human health and remediation [J]. Egyptian Journal of Petroleum, 2016,25(1): 107-123.
[29]	Hindersmann B, Achten C. Urban soils impacted by tailings from coal mining: PAH source identification by 59PAHs, BPCA and alkylated PAHs [J]. Environmental Pollution, 2018,242:1217-1225.
[30]	Hindersmann B, Forster A, Achten C. Novel and specific source identification of PAH in urban soils: Alk-PAH-BPCA index and “V”-shape distribution pattern [J]. Environmental Pollution, 2020,257.doi:10.1016/j.envpol.2019.113594.
[31]	Fabianska M J, Kurkiewicz S. Biomarkers, aromatic hydrocarbons and polar compounds in the Neogene lignites and gangue sediments of the Konin and Turoszów Brown Coal Basins (Poland) [J]. International Journal of Coal Geology, 2013,107:24-44.
[32]	叶凯,孙玉川,朱琳跃,等.典型岩溶槽谷区不同地表覆被土壤中多环芳烃的运移特征和来源解析 [J]. 环境科学学报, 2021,41(12): 5127-5136. Ye K, Sun Y C, Zhu L Y, et al. Migration characteristic and source analysis of PAHs in soils with different surface cover in typical Karst trough Valley Area [J]. Acta Scientiae Circumstantiae, 2021,41(12): 5127-5136.
[33]	Zheng H, Qu C K, Zhang J Q, et al. Polycyclic aromatic hydrocarbons (PAHs) in agricultural soils from Ningde, China: levels, sources, and human health risk assessment [J]. Environmental Geochemistry and Health, 2019,41(2):907-919.
[34]	Moradi M, Hung H, Li J, et al. Assessment of Alkylated and Unsubstituted Polycyclic Aromatic Hydrocarbons in Air in Urban and Semi-Urban Areas in Toronto, Canada [J]. Environmental Science & Technology, 2022,56(5):2959-2967.
[35]	Qu Y J, Gong Y W, Ma J, et al. Potential sources, influencing factors, and health risks of polycyclic aromatic hydrocarbons (PAHs) in the surface soil of urban parks in Beijing, China [J]. Environmental Pollution, 2020,260.doi:10.1016/j.envpol.2020.114016.
[36]	Qian Y H, Xu Z P, Hong X P, et al. Alkylated Polycyclic Aromatic Hydrocarbons Are the Largest Contributor to Polycyclic Aromatic Compound Concentrations in the Topsoil of Huaibei Coalfield, China [J]. International Journal of Environmental Research and Public Health, 2022,19(19).doi:10.3390/ijerph191912733.
[37]	Qian Y H, Yuan K Y, Hong X P, et al. Contamination characteristics of alkyl polycyclic aromatic hydrocarbons in dust and topsoil collected from Huaibei Coalfeld, China [J]. Environmental Geochemistry and Health, 2022.doi:10.1007/s10653-022-01365-y.
[38]	Ambade B, Sethi S S, Chintalacheruvu M R. Distribution, risk assessment, and source apportionment of polycyclic aromatic hydrocarbons (PAHs) using positive matrix factorization (PMF) in urban soils of East India [J]. Environmental Geochemistry and Health, 2022.doi:10.1007/s10653-022-01223-x.
[39]	Wang Y M, Qi A A, Wang P C, et al. Temporal profiles, source analysis, and health risk assessments of parent polycyclic aromatic hydrocarbons (PPAHs) and their derivatives (NPAHs, OPAHs, ClPAHs, and BrPAHs) in PM2.5 and PM1.0 from the eastern coastal region of China: Urban coastal area versus coastal background area [J]. Chemosphere, 2022,292.doi:10.1016/j.chemosphere.2021.133341.
[40]	Ma C L, Ye S Y, Lin T, et al. Source apportionment of polycyclic aromatic hydrocarbons in soils of wetlands in the Liao River Delta, Northeast China [J]. Marine Pollution Bulletin, 2014,80(1/2):160-167.
[41]	Zuo Q, Duan Y H, Yang Y, et al. Source apportionment of polycyclic aromatic hydrocarbons in surface soil in Tianjin, China [J]. Environmental Pollution, 2007,147(2):303-310.
[42]	Jiang H H, Wang Q, Zhao N N, et al. Distributions and Sources of Polycyclic Aromatic Hydrocarbons (PAHs) in Soils around a Chemical Plant in Shanxi, China [J]. International Journal of Environmental Research and Public Health, 2017,14(10).doi:10.3390/ijerph14101198.
[43]	Liang M, Liang H D, Rao Z, et al. Characterization of polycyclic aromatic hydrocarbons in urban-rural integration area soil, North China: Spatial distribution, sources and potential human health risk assessment [J]. Chemosphere, 2019,234:875-884.
[44]	Lin Q Y, Zhao W H, Ma J, et al. Spatial clustering and source-specific risk of combined pollutants in soils from an industrial area in Shanxi Province, China [J]. Environmental Pollution, 2022,299.doi:10.1016/ j.envpol.2022.118925.
[45]	Lim H, Sadiktsis I, Galvo M F D, et al. Polycyclic aromatic compounds in particulate matter and indoor dust at preschools in Stockholm, Sweden: Occurrence, sources and genotoxic potential in vitro [J]. Science of the Total Environment, 2020,755(Pt 1).doi:10. 1016/j.scitotenv.2020.142709.
[46]	Yan D H, Wu S H, Zhou S L, et al. Characteristics, sources and health risk assessment of airborne particulate PAHs in Chinese cities: A review [J]. Environmental Pollution, 2019,248:804-814.