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Characteristics and formation mechanism of a heavy winter air pollution event in Beijing |
YANG Xiao-wen, ZHOU Ying, CHENG Shui-yuan, WANG Gang, WANG Xiao-qi |
Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing 100124, China |
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Abstract In order to study the characteristics and formation mechanism during a heavy air pollution episode in Beijing during 9~15January in 2013, the weather conditions, chemical characteristics of particulate matter and atmospheric environmental background were analyzed. The results showed that the average daily mass concentrations of PM10 and PM2.5 were 347.7μg/m3and 222.4μg/m3, respectively, exceeding the corresponding ambient air quality standards (GB3095-2012) of China. During the pollution episode, NH4+, NO3- and SO42- made a combined contribution of 44.0% to PM2.5 concentration. The average ratios of OC/EC were 5.44. This indicates a large contribution from secondary ions and organic matters to PM2.5. The atmosphere was relatively stable during the study period in Beijing because of the stable atmosphere circulation, the adverse near-ground meteorological conditions of high humidity and low wind speed as well as the lower and deeper inversion layer. The stable atmospheric condition and the land structure surrounded by mountains on three sides in Beijing restrained the dispersion of pollutants, and these were the main causes of this heavy pollution process.
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Received: 26 June 2015
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[1] |
Ji D, Li L, Wang Y, et al. The heaviest particulate air-pollution episodes occurred in northern China in January, 2013: Insights gained from observation[J]. Atmospheric Environment, 2014,92: 546-556.
|
[2] |
王占山,李云婷,孙 峰,等.2014年10月上旬北京市大气重污染分析[J]. 中国环境科学, 2015,35(6):1654-1663.
|
[3] |
李令军,王 英,李金香,等.2000~2010北京大气重污染研究[J]. 中国环境科学, 2012,32(1):23-30.
|
[4] |
Molina M J, Molina L T. Megacities and atmospheric pollution[J]. Journal of the Air & Waste Management Association, 2004,54(6): 644-680.
|
[5] |
Fann N, Risley D. The public health context for PM2.5 and ozone air quality trends[J]. Air Quality, Atmosphere & Health, 2013, 6(1):1-11.
|
[6] |
Li Z, Li C, Chen H, et al. East asian studies of tropospheric aerosols and their impact on regional climate (EAST-AIRC): An overview[J]. Journal of Geophysical Research: Atmospheres (1984~2012), 2011,116(D7).
|
[7] |
王晴晴,马永亮,谭吉华,等.北京市冬季PM2.5中水溶性重金属污染特征[J]. 中国环境科学, 2014,34(9):2204-2210.
|
[8] |
杨素英,赵秀勇,刘宁微.北京秋季一次重污染天气过程的成因分析[J]. 气象与环境学报, 2010,26(5):13-16.
|
[9] |
Chow J C, Bachmann J D, Wierman S S G, et al. Visibility: science and regulation[J]. Journal of the Air & Waste Management Association, 2002,52(6):628-713.
|
[10] |
Huang K, Zhuang G, Lin Y, et al. Typical types and formation mechanisms of haze in an Eastern Asia megacity, Shanghai[J]. Atmospheric Chemistry and Physics, 2012,12(1):105-124.
|
[11] |
周 敏,陈长虹,乔利平,等.2013年1月中国中东部大气重污染期间上海颗粒物的污染特征[J]. 环境科学学报, 2013,33(11): 3118-3126.
|
[12] |
Ma J, Shi A, Tong M. Special Report: Big bang measures to fight air pollution[R]. Hongkong: Deutsche Bank AG. 7, 2013.
|
[13] |
杨 欣,陈义珍,刘厚风,等.北京2013年1月连续强霾过程的污染特征及成因分析[J]. 中国环境科学, 2014,34(2):282-288.
|
[14] |
王志娟,韩力慧,陈旭锋,等.北京典型污染过程PM2.5的特性和来源[J]. 安全与环境学报, 2012,12(5):122-126.
|
[15] |
Chow J C, Watson J G, Chen L W, et al. Equivalence of elemental carbon by thermal/optical reflectance and transmittance with different temperature protocols[J]. Environmental Science & Technology, 2004,38(16):4414-4422.
|
[16] |
GB/3095-2012 环境空气质量标准[S].
|
[17] |
李贵玲,周 敏,陈长虹,等.2011年春季沙尘天气影响下上海大气颗粒物及其化学组分的变化特征[J]. 环境科学, 2014,35(5): 1644-1653.
|
[18] |
程念亮,李云婷,张大伟,等.2014年10月北京市4次典型空气重污染过程成因分析[J]. 环境科学研究, 2015,28(2):163-170.
|
[19] |
Fu Q, Zhuang G, Wang J, et al. Mechanism of formation of the heaviest pollution episode ever recorded in the Yangtze River Delta, China[J]. Atmospheric Environment, 2008,42(9):2023-2036.
|
[20] |
李德平,程兴宏,于永涛,等.北京地区三级以上污染日的气象影响因子初步分析[J]. 气象与环境学报, 2010,26(3):7-13.
|
[21] |
邓利群,钱 骏,廖瑞雪,等.2009年8~9月成都市颗粒物污染及其与气象条件的关系[J]. 中国环境科学, 2012,32(8):1433-1438.
|
[22] |
刘庆阳,刘艳菊,杨 峥,等.北京城郊冬季一次大气重污染过程颗粒物的污染特征[J]. 环境科学学报, 2014,34(1):12.
|
[23] |
Hou B, Zhuang G S, Zhang R, et al. The implication of carbonaceous aerosol to the formation of haze: Revealed from the characteristics and sources of OC/EC over a mega-city in China[J]. Journal of Hazardous Materials, 2011,190:529-536.
|
[24] |
徐晓峰,李青春,张小玲.北京一次局地重污染过程气象条件分析[J]. 气象科技, 2006,33(6):543-547.
|
[25] |
http://www.nmc.cn/publish/observations.html
|
[26] |
Wang H, Xu J, Zhang M, et al. A study of the meteorological causes of a prolonged and severe haze episode in January 2013 over central-eastern China[J]. Atmospheric Environment, 2014, 98:146-157.
|
[27] |
http://web.kma.go.kr/chn/weather/images/analysischart.jsp
|
[28] |
http://weather.uwyo.edu/upperair/sounding.html
|
[29] |
Zhang R, Li Q, Zhang R. Meteorological conditions for the persistent severe fog and haze event over eastern China in January 2013[J]. Science China Earth Sciences, 2014,57(1):26-35.
|
[30] |
Tao M, Chen L, Xiong X, et al. Formation process of the widespread extreme haze pollution over northern China in January 2013: Implications for regional air quality and climate[J]. Atmospheric Environment, 2014,98:417-425.
|
[31] |
Wang Y, Zhuang G, Tang A, et al. The ion chemistry and the source of PM2.5 aerosol in Beijing[J]. Atmospheric Environment, 2005,39(21):3771-3784.
|
[32] |
Lin J J. Characterization of water-soluble ion species in urban ambient particles[J]. Environment International, 2002,28(1):55-61.
|
[33] |
Sun Y, Zhuang G, Tang A, et al. Chemical characteristics of PM2.5 and PM10in haze-fog episodes in Beijing[J]. Environmental science & technology, 2006,40(10):148-3155.
|
[34] |
Truex T J, Pierson W R, McKee D E. Sulfate in diesel exhaust[J]. Environmental Science & Technology, 1980,14(9):118-1121.
|
[35] |
Ohta S, Okita T. A chemical characterization of atmospheric aerosol in Sapporo[J]. Atmospheric Environment. Part A. General Topics, 1990,24(4):815-822.
|
[36] |
Yao X, Chan C K, Fang M, et al. The water-soluble ionic composition of PM2.5 in Shanghai and Beijing, China[J]. Atmospheric Environment, 2002,36(26):4223-4234.
|
[37] |
宋 燕,徐殿斗,柴之芳.北京大气颗粒物PM10和PM2.5中水溶性阴离子的组成及特征[J]. 分析试验室, 2006,25(2):80-85.
|
[38] |
Huebert B J, Wang M X, Lü W X. Atmospheric nitrate, sulfate, ammonium and calcium concentrations in China[J]. Tellus Series B-chemical & Physical Meteorology, 2010,40B(4):260-269.
|
[39] |
Wang Y, Zhuang G, Tang A, et al. The ion chemistry and the source of PM2.5 aerosol in Beijing[J]. Atmospheric Environment, 2005,39(21):3771-3784.
|
|
|
|