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Concentration and source of polychlorinated naphthalenes in surface soils from the South of Jiangsu |
XUE Ling-nan1,2, ZHANG Lin-li1,2, ZHANG Li-fei2, SHI Shuang-xin2, DONG Liang2, LI Xiao-xiu1 |
1. College of Resource Environment and Tourism, Capital Normal University, Beijing 100048, China; 2. State Environmental Protection Key Laboratory of Dioxin Pollution Control, National Research Center for Environmental Analysis and Measurement, Beijing 100029, China |
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Abstract The concentrations, profiles and source apportionment of polychlorinated naphthalenes (PCNs) in 34surface soil samples from the South of Jiangsu were analyzed by gas chromatograph coupled with a triple quadrupole mass spectrometer. Total concentrations of PCNs in all samples ranged from 0.263 to 2.48ng/g dw with an average of 0.464ng/g dw except sampling point 16, which had the highest concentration of 2.48ng/g dw, the TEQs of PCNs ranged from 0.045 to 0.157pg/g dw, indicating a low concentration level. MonoCNs and DiCNs were the most predominant homologues in all the samples, accounting for 39.3%~91.4%. The congeners CN-66/67, CN-69 and CN-73 were the predominant contributors to the TEQs, accounting for 25.6%, 29.1% and 28.7%, respectively. The ratio of ΣPCNCom/ΣPCNs could indicate that the high temperature combustion process made great influence to the PCNs pollution in the South of Jiangsu. Correlation analysis and principal component analysis showed that the use of old electrical equipment and traffic emissions might be also the possible sources to the PCNs pollution in this study area. However, the sources of PCNs pollution are more complex, which need a further study to determine the source of PCNs in surface soil samples from the South of Jiangsu accurately.
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Received: 06 June 2016
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[1] |
Falandysz J. Polychlorinated naphthalenes:An environmental update[J]. Environmental Pollution, 1998,101(1):77-90.
|
[2] |
郭丽,巴特,郑明辉.多氯萘的研究[J]. 化学进展, 2009, 21(0203):377-388.
|
[3] |
Nie Z, Zheng M, Liu W, et al. Estimation and characterization of PCDD/Fs, dl-PCBs, PCNs, HxCBz and PeCBz emissions from magnesium metallurgy facilities in China[J]. Chemosphere, 2011,85(11):1707-1712.
|
[4] |
Imagawa T, Lee C W. Correlation of polychlorinated naphthalenes with polychlorinated dibenzofurans formed from waste incineration[J]. Chemosphere, 2001,44(6):1511-1520.
|
[5] |
Kannan K, Imagawa T, Blankenship A L, et al. Isomer-specific analysis and toxic evaluation of polychlorinated naphthalenes in soil, sediment, and biota collected near the site of a former chlor-alkali plant[J]. Environmental Science and Technology, 1998,32(17):2507-2514.
|
[6] |
Park H, Kang J H, Baek S Y, et al. Relative importance of polychlorinated naphthalenes compared to dioxins, and polychlorinated biphenyls in human serum from Korea:Contribution to TEQs and potential sources[J]. Environmental Pollution, 2010,158(5):1420-1427.
|
[7] |
Meijer S N, Harner T, Helm P A, et al. Polychlorinated naphthalenes in U. K. soils:time trends, markers of source, and equilibrium status[J]. Environmental Science and Technology, 2001,35(21):4205-4213.
|
[8] |
Wyrzykowska B, Hanari N, Orlikowska A, et al. Polychlorinated biphenyls and-naphthalenes in pine needles and soil from Poland-Concentrations and patterns in view of long-term environmental monitoring[J]. Chemphere, 2007,67:1877-1886.
|
[9] |
Pan J, Yang Y, Zhu X, et al. Altitudinal distributions of PCDD/Fs, dioxin-like PCBs and PCNs in soil and yak samples from Wolong high mountain area, eastern Tibet-Qinghai Plateau, China[J]. Science of the Total Environment, 2013,444(2):102-109.
|
[10] |
Xu Y, Li J, Zheng Q, et al. Polychlorinated naphthalenes (PCNs) in Chinese forest soil:Will combustion become a major source[J]. Environmental Pollution, 2015,204:124-132.
|
[11] |
Tian Z, Li H, Xie H, et al. Concentration and distribution of PCNs in ambient soil of a municipal solid waste incinerator[J]. Science of the Total Environment, 2014,491-492(1):75-79.
|
[12] |
张利飞,张秀蓝,张辉,等.加速溶剂萃取-多层硅胶柱净化-气相色谱串联三重四极杆质谱法测定土壤和沉积物中的多氯萘[J]. 分析化学, 2014,42(2):258-266.
|
[13] |
Shi S, Huang Y, Zhou L, et al. Changes of polybrominated diphenyl ethers and polychlorinated biphenyls in surface soils from urban agglomeration of the Yangtze River Delta, in China between 2003 and 2012[J]. Environmental Science and Pollution Research, 2015,22(13):9766-9774.
|
[14] |
刘芷彤,刘国瑞,郑明辉,等.多氯萘的来源及环境污染特征研究[J]. 中国科学:化学, 2013,43(3):279-290.
|
[15] |
Liu G, Zheng M, Du B, et al. Atmospheric emission of polychlorinated naphthalenes from iron ore sintering processes[J]. Chemosphere, 2012,89(4):467-472.
|
[16] |
Wang Y, Cheng Z, Li J, et al. Polychlorinated naphthalenes (PCNs) in the surface soils of the Pearl River Delta, South China:Distribution, sources, and air-soil exchange[J]. Environmental Pollution, 2012,170(8):1-7.
|
[17] |
Cetin B. Investigation of PAHs, PCBs and PCNs in soils around a heavily industrialized area in Kocaeli, Turkey:Concentrations, distributions, sources and toxicological effects[J]. Science of the Total Environment, 2016,560-561:160-169.
|
[18] |
Ali U, Sanchez-García L, Rehman M Y A, et al. Tracking the fingerprints and combined TOC-black carbon mediated soil-air partitioning of polychlorinated naphthalenes (PCNs) in the Indus River Basin of Pakistan[J]. Environmental Pollution, 2016,208:850-858.
|
[19] |
Li F, Jin J, Gao Y, et al. Occurrence, distribution and source apportionment of polychlorinated naphthalenes (PCNs) in sediments and soils from the Liaohe River Basin, China[J]. Environmental Pollution, 2016,211:226-232.
|
[20] |
Noma Y, Yamamoto T, Sakai S I. Congener-specific composition of polychlorinated naphthalenes, coplanar PCBs, dibenzo-pdioxins, and dibenzofurans in the halowax series[J]. Environmental Science and Technology, 2004,38(6):1675-1680.
|
[21] |
秦小军,陈群利.电子垃圾拆解场周边环境多氯萘污染检测[J]. 华侨大学学报, 2015,36(4):467-471.
|
[22] |
Mari M, Schuhmacher M, Feliubadalo J, et al. Air concentrations of PCDD/Fs, PCBs and PCNs using active and passive air samplers[J]. Chemphere, 2008,70(9):1637-1643.
|
[23] |
Gulan M P, Bills D D, Putnam T B. Analysis of polychlorinated naphthalenes by gas chromatography and ultraviolet irradiation[J]. Environment Contamination and Toxicology, 1974,11(5):438-441.
|
[24] |
Odabasi M, Bayram A, Elbir T, et al. Investigation of soil concentrations of persistent organic pollutants, trace elements, and anions due to iron-steel plant emissions in an industrial region in Turkey[J]. Water Air and Soil Pollution, 2010,213(1):375-388.
|
[25] |
Lee S C, Harner T, Pozo K, et al. Polychlorinated naphthalenes in the global atmospheric passive sampling (GAPS) study[J]. Environmental Science and Technology, 2007,41(8):2680-2687.
|
[26] |
Liu G, Cai Z, Zheng M. Sources of unintentionally produced polychlorinated naphthalenes[J]. Chemphere, 2014,94(1):1-12.
|
[27] |
Zhou Z, Zhao B, Qi L, et al. Distribution of polychlorinated dibenzo-p-dioxins and dibenzofurans in the atmosphere of Beijing, China[J]. Aerosol and Air Quality Research, 2014,14(4):1269-1278.
|
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