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Distribution, assessment and sources analysis of persistent organic toxic chemicals in sediments of Dongting Lake |
YANG Hai-jun1, ZHANG Hai-tao1, LIU Ya-bin1, XU Yun-hai1, HUANG Zhong-ting2 |
1. College of Plant Protection, Hunan Agricultural University, Changsha 410128, China;
2. Environmental Monitoring Station of Hunan Province, Changsha 410014, China |
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Abstract In order to reveal the distribution characteristics and the sources of HCHs, DDTs and PAHs in sediments of Dongting lake, and assess their ecological risk, this study investigated the contents of HCHs, DDTs and PAHs in sediments (0~20cm) from 31sample sites of Dongting Lake (Nanzui Town, Yuanjiang city) in Dec, 2015. The results showed that the ∑HCHs and ∑PAHs content variation in South Dongting Lake was the highest, and the highest content variation of ∑DDTs and ∑OCPs was in West Dongting Lake. Based on the spatial distribution, the content of HCHs in East Dongting Lake was the highest, the next was on the border between East Dongting Lake and South Dongting Lake, and the other areas were low. The contents of DDTs in other areas were relatively high except the north part of West Dongting Lake, and some high value areas were found. The maximum content value of PAHs was found on the border between East Dongting Lake and South Dongting Lake, the second was the north and the central part of West Dongting Lake. Pollution sources analysis found that those 23kinds of compounds clustering in sediments of Dongting Lake could be classified into three categories, and 31monitoring points could be classified into four categories. Since the α-HCH/γ-HCH in all samples was 0.66, with the finding of lindane, it could be inferred that HCHs in the sediments of Dongting Lake mainly came from agricultural production. While, according to the p,p'-DDE/p,p'-DDT, new DDTs input had been found in the sediments. The study also suggested that the major sources of PAHs in sediments were coal and petroleum combustion and petroleum leakage. At last, by the risk assessment, Acy had caused slight pollution in the Dongting Lake, while other PAH had no effect. However, the residues of o,p'-DDT, p,p'-DDT and ∑DDTs would pose ecological risk. Furthermore, the detection of the residues of BbF, BkF, B ghi P, Incd P, α-C6H6Cl6, β-C6H6Cl6, δ-C6H6Cl6 and ∑HCHs should be seriously considered as well.
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Received: 24 August 2016
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[1] |
Jose M, Alex J. Assessment of sediment and porewater after one year of subaqueous capping of contaminated sediments in Hamilton harbour, Canada[J]. Water Science&Technology, 1998,37(6):323-329.
|
[2] |
陈燕燕,尹 颖,王晓蓉,等.太湖沉积物中PAHs和PCBs的分布及风险评价[J]. 中国环境科学, 2009,29(2):118-124.
|
[3] |
张 明,唐访良,吴志旭,等.千岛湖表层沉积物中多环芳烃污染特征及生态风险评价[J]. 中国环境科学, 2014,34(1):253-258.
|
[4] |
杜芳芳,杨 毅,刘 敏,等.上海市表层土壤中多环芳烃的分布特征与源解析[J]. 中国环境科学, 2014,34(4):989-995.
|
[5] |
Hartmann P C, Quinn J G, Cairns R W, et al. The distribution and sources of polycyclic aromatic hydrocarbons in Narragansett Bay surface sediments[J]. Marine pollution bulletin, 2004,48(3):351- 358.
|
[6] |
黄国培,陈颖军,林 田,等.渤海湾潮间带沉积物中多环芳烃的含量分布和生态风险[J]. 中国环境科学, 2011,31(11):1856- 1863.
|
[7] |
Liu L Y, Wang J Z, Wei G L, et a1. Polycyclic aromatic hydrocarbons (PAHs) in continental shelf sediment of China:Implications for anthropogenic influences on coastal marine envmonment[J]. Environmental Pollution, 2012,16(7):155-162.
|
[8] |
周俊丽,李 霏,刘征涛.长江河口沉积物柱状样中多环芳烃沉积记录分析[J]. 环境化学, 2013,32(6):30-35.
|
[9] |
张光贵,田 琪,郭 晶.洞庭湖沉积物重金属生态风险及其变化趋势研究[J]. 生态毒理学报, 2015,10(3):184-191.
|
[10] |
方 群,李 飞,祝慧娜,等.东洞庭湖沉积物中重金属的分布特征、污染评价与来源分析[J]. 环境科学研究, 2011,24(12):1378-1384.
|
[11] |
祝云龙,姜加虎,孙占东,等.洞庭湖沉积物中重金属污染特征与评价[J]. 湖泊科学, 2008,20(4):477-485.
|
[12] |
湖南省政协经济科技委员会编.三峡工程与洞庭湖关系研究[M]. 长沙:湖南科学技术出版社, 2002:179-182.
|
[13] |
姚志刚,鲍征宇,高 璞.洞庭湖沉积物重金属环境地球化学[J]. 地球化学, 2006,25(6):629-638.
|
[14] |
基于GIS和多元变量模型的洞庭湖沉积物中重金属的空间风险评价和来源解析[D]. 长沙:湖南大学, 2013.
|
[15] |
李国傲.水、土壤、气体样品中挥发性有机物分析方法研究[D]. 北京:北京师范大学, 2013.
|
[16] |
宋守鑫.哈尔滨周边地区土壤中27种挥发性有机物的测定[D]. 长春:吉林大学, 2013.
|
[17] |
Long E R, Macdonald D D, Smith S L, et al. Incidence of adversebiological effects with range of chemical concentrations in marineand estuarine sediments[J]. Environmental Management, 1995,19(1):81-97.
|
[18] |
Macdonald D D, Ingersoll C G, Berger T A. Development and evaluation of consensus-based sediment quality guidelines for freshwater ecosystems[J]. Arch Environmental Contamination, 2000,39(1):20-31.
|
[19] |
李海燕,段丹丹,黄 文,等.珠江三角洲表层水中多环芳烃的季节分布、来源和原位分配[J]. 环境科学学报, 2014,34(12):2963-2972.
|
[20] |
万 群,李 飞,祝慧娜,等.东洞庭湖沉积物中重金属的分布特征、污染评价与来源辨析[J]. 环境科学研究, 2011,24(12):1378-1384.
|
[21] |
Du Yun, Cai Shuming, Zhang Xiaoyang, et al. Interpretation of the environmental change of Dongting Lake, middle reach of Yangtze River, China, by 210Pb measurement and satellite image analysis[J]. Geomorphology, 2001,41(23):171-181.
|
[22] |
秦迪岚,黄 哲,罗岳平,等.洞庭湖区污染控制区划与控制对策[J]. 环境科学研究, 2011,24(7):748-755.
|
[23] |
田泽斌,王丽婧,李小宝,等.洞庭湖出入湖污染物通量特征[J]. 环境科学研究, 2014,27(9):1008-1015.
|
[24] |
程荣进,张思冲,周晓聪,等.大庆城郊湿地沉积物重金属污染及聚类分析[J]. 中国农学通报, 2009,25(2):240-245.
|
[25] |
Law S A, Diamond M L, Helm P A, et al. Factors affecting theoccurrence and enantiomeric degradation of hexachlorocyclohexaneisomers in northern and temperate aquatic systems[J]. Environmental Toxicology and Chemistry, 2001, 20(12):2690-2698.
|
[26] |
Zheng X, Liu X, Liu W, et al. Concentrations and source identification of organochlorine pesticides (OCPs) in soils from Wolong Natural Reserve[J]. Chinese Science Bulletin, 2009, 54(5):743-751.
|
[27] |
张 明,唐访良,吴志旭,等.千岛湖沉积物中多环芳烃污染特征及生态风险评价[J]. 中国环境科学, 2014,34(1):253-258.
|
[28] |
冯精兰,刘书卉,申君慧,等.新乡市地表水沉积物中HCHs和DDTs的分布特征及生态风险[J]. 农业环境科学学报, 2013,32(6):1219-1225.
|
|
|
|